Advanced Search

Citation: MIAO Bao-Xi, LI Guo-Ling, ZHAO Yun, NI Zhong-Hai. Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged FeⅢ-CuⅡ Complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2470-2474. doi: 10.3969/j.issn.1001-4861.2013.00.322 shu

Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged FeⅢ-CuⅡ Complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n

  • 1.

    School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

  • Received Date: 3 January 2013
    Available Online: 6 June 2013

    Fund Project: 江苏省创新团队和中央高校基本科研业务费专项资金(No.2013XK05)资助项目。 (No.2013XK05)

  • Anew one-dimensional cyanide-bridged FeⅢ-CuⅡ complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n (1-CH3im=1-methylimidazole, cyclam=1,4,8,11-tetraazacyclotetradecane) (1) has been synthesized by the reaction of [Cu(cyclam)](ClO4)2 and a pentacyanideferrite building blocks K2[Fe(1-CH3im)(CN)5]. Single crystal X-ray diffraction analysis reveals the structure of complex 1 is polymer type with two different metal centers which is alternated linked by cyanide group from the [Fe(1-CH3im)(CN)5]2- building blocks. Complex 1 (C19H32CuFeN11O, Mr=549.95) crystallizes in triclinic space group P1 with a=0.83256(17) nm, b=0.89938(18) nm, c=0.9983(2) nm, α=111.94(3)°, β=95.06(3)°, γ=116.90(3)°, V=0.5877(2) nm3, Z=1, Dc=1.554 g·cm-3, μ=1.558 mm-1, F(000)=286, the final R10.0519 and wR2=0.1353. Magnetic investigations show that complex 1 exhibits a weak ferromagnetic coupling between CuⅡ and low-spin FeⅢ through the cyanide bridge. CCDC: 908099.
  • 加载中
    1. [1]

      [1] Ma Y S, Li Y Z, Zheng L M, et al. Inorg. Chem., 2008,47: 4536-4544

    2. [2]

      [2] Li B, Chen L Q, Wei R J, et al. Inorg. Chem., 2011,50:424-426

    3. [3]

      [3] You Y S, Yoon J H, Lim J H, et al. Inorg. Chim. Acta, 2007,360:2523-2531

    4. [4]

      [4] YAO Jing (姚景), XING Yan-Yan (邢燕燕), XU Yan-Yan (徐艳燕), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1636-1642

    5. [5]

      [5] Colacio E, Dominguez-Vera J M, Ghazi M, et al. Chem. Commun., 1998:1071-1072

    6. [6]

      [6] Shen Z, Zuo J L, Gao S, et al. Angew. Chem. Int. Ed., 2000, 39:3633-3635

    7. [7]

      [7] Cha M J, Shin J W, Lee Y H, et al. Inorg. Chem. Commun., 2009,12:520-522

    8. [8]

      [8] Dong D P, Liu T, Zheng H, et al. Inorg. Chem. Commun., 2012,24:153-156

    9. [9]

      [9] NI Zhong-Hai(倪中海), NIE Jing(聂景), LI Guo-Ling(李国 玲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,2:411-416

    10. [10]

      [10]Wang S, Ding X H, Li Y H, et al. Coord. Chem. Res., 2012, 256:439-464

    11. [11]

      [11]Yao M X, Zheng Q, Gao F, et al. Sci. China Chem., 2012, 55:1022-1030

    12. [12]

      [12]Palii A, Tsukerblat B, Klokishner S, et al. Chem. Soc. Rev., 2011,40:3130-3156

    13. [13]

      [13]Trávncek Z, Herchel R, Mikulík J, et al. J. Solid State Chem., 2010,183:1046-1054

    14. [14]

      [14]Beltran L M C, Long J R. Acc. Chem. Res., 2005,38:325-334

    15. [15]

      [15]Kou H Z, Liao D Z, Cheng P, el al. J. Chem. Soc., Dalton Trans., 1997:1503-1506

    16. [16]

      [16]Ni Z H, Kou H Z, Zhao Y H, et al. Inorg. Chem., 2005,44: 2050-2059

    17. [17]

      [17]Ge C H, Kou H Z, Ni Z H, et al. Chem. Lett., 2005,34:1280-1281

    18. [18]

      [18]Li G L, Nie J, Chen H, et al. Inorg. Chem. Commun., 2012, 19:66-69

    19. [19]

      [19]Kamaluddin, Mala N, Sushama W D. Bull. Chem. Soc. Jpn., 1989,62:3291-3297

    20. [20]

      [20]Kolinski R A, Korybut-Daszkiewicz B. Inorg. Chim. Acta, 1975,14:237-245

    21. [21]

      [21]Sheldrick G M. Acta Crystallogr., 2008,A64:112-122

    22. [22]

      [22]Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structure, University of Gottingen, Germany, 1997.

    23. [23]

      [23]Fischer M E. Am. J. Phys., 1964,32:343-346

    24. [24]

      [24]Nie J, Li G L, Miao B X, et al. Chinese J. Struct. Chem., 2012,31:1129-1134

    25. [25]

      [25]Bieńko A, Suracka K, Mroziński J, et al. Polyhedron, 2010, 29:2546-2552

    26. [26]

      [26]Colacio E, Domínguez-Vera J M, Ghazi M, et al. J. Chem. Soc., Dalton Trans., 2000:505-509

    27. [27]

      [27]Zhang B, Ni Z H, Cui A L, et al. New J. Chem., 2006,30: 1327-1332

    28. [28]

      [28]Parker R J, Lu K D, Batten S R, et al. J. Chem. Soc., Dalton Trans., 2002:3723-3730

    29. [29]

      [29]Kou H Z, Zhou B C, Wang R J, et al. Inorg. Chem., 2003, 42:7658-7665

    30. [30]

      [30]Lu T B, Shi H X, Chen S, el at. J. Inorg. Organomet. Polym., 1999,9:165-178

  • 加载中
    1. [1]

      Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

    2. [2]

      Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278

    3. [3]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    4. [4]

      Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064

    5. [5]

      Yan Liu ,  Yuexiang Zhu ,  Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

    6. [6]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    7. [7]

      Weina Wang ,  Fengyi Liu ,  Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

    8. [8]

      Junqiao Zhuo ,  Xinchen Huang ,  Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100

    9. [9]

      Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    10. [10]

      Wenyan Dan ,  Weijie Li ,  Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

    11. [11]

      Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207

    12. [12]

      Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    13. [13]

      Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307

    14. [14]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    15. [15]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    16. [16]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    17. [17]

      Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

    18. [18]

      Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269

    19. [19]

      Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251

    20. [20]

      Jinfeng Chu ,  Lan Jin ,  Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(284)
  • HTML views(5)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return