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Citation: MIAO Bao-Xi, LI Guo-Ling, ZHAO Yun, NI Zhong-Hai. Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged FeⅢ-CuⅡ Complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2470-2474. doi: 10.3969/j.issn.1001-4861.2013.00.322 shu

Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged FeⅢ-CuⅡ Complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n

  • 1.

    School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

  • Received Date: 3 January 2013
    Available Online: 6 June 2013

    Fund Project: 江苏省创新团队和中央高校基本科研业务费专项资金(No.2013XK05)资助项目。 (No.2013XK05)

  • Anew one-dimensional cyanide-bridged FeⅢ-CuⅡ complex {[Fe(1-CH3im)(CN)4(μ-CN)Cu(cyclam)]·H2O}n (1-CH3im=1-methylimidazole, cyclam=1,4,8,11-tetraazacyclotetradecane) (1) has been synthesized by the reaction of [Cu(cyclam)](ClO4)2 and a pentacyanideferrite building blocks K2[Fe(1-CH3im)(CN)5]. Single crystal X-ray diffraction analysis reveals the structure of complex 1 is polymer type with two different metal centers which is alternated linked by cyanide group from the [Fe(1-CH3im)(CN)5]2- building blocks. Complex 1 (C19H32CuFeN11O, Mr=549.95) crystallizes in triclinic space group P1 with a=0.83256(17) nm, b=0.89938(18) nm, c=0.9983(2) nm, α=111.94(3)°, β=95.06(3)°, γ=116.90(3)°, V=0.5877(2) nm3, Z=1, Dc=1.554 g·cm-3, μ=1.558 mm-1, F(000)=286, the final R10.0519 and wR2=0.1353. Magnetic investigations show that complex 1 exhibits a weak ferromagnetic coupling between CuⅡ and low-spin FeⅢ through the cyanide bridge. CCDC: 908099.
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