Citation: ZHANG Chun-Li, QIN Ling, YANG Qing-Xiang, SHI Zhi-Qiang, ZHENG He-Gen. Synthesis,Crystal Structure and Magnetic Property of the 2D Mn(Ⅱ) Coordination Polymer Based on 4,4'-Bisimidazolylbiphenyl and m-Phthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2157-2161. doi: 10.3969/j.issn.1001-4861.2013.00.321 shu

Synthesis,Crystal Structure and Magnetic Property of the 2D Mn(Ⅱ) Coordination Polymer Based on 4,4'-Bisimidazolylbiphenyl and m-Phthalic Acid

1.
1 School of Chemistry and Life Science, Suzhou University, Suzhou 234000, China;

Received Date: 19 March 2013
Available Online: 5 June 2013
Fund Project: 国家自然科学基金(No.91022011) (No.91022011)国家重点基础研究发展计划(No.2010CB923303)资助项目 (No.2010CB923303)

A 2D complex {[Mn(4,4'-bibp)(MPA)]·4H₂O}_n (1), based on mixed-ligands bibp (bibp=4,4'-bisimidazol-ylbiphenyl) and H₂MPA (H₂MPA=m-phthalic acid), has been synthesized by hydrothermal method and charac-terized by elemental analysis, IRspectra, XRD, TGA, and the crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the triclinic system, space group Pl, and features 2Dbilayer structure. Magnetic susceptibility measurement of complex 1 indicates the presence of weak antiferromagnetic interactions between the neighboring Mn(Ⅱ) ions. CCDC: 928642.
- Mn(Ⅱ) coordination polymer; crystal structure; magnetic property
1. [1]
  [1] Kurmoo M. Chem. Soc. Rev., 2009,38:1353-1379 [2] Chun H J, Wang X H, Gao S, et al. Inorg. Chem., 2009,48: 1301-1302 [3] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352 [4] Yang J, Yue Q, Li G D, et al. Inorg. Chem., 2006,45:2857- 2865 [5] Li J R, Ma Y, Sculley J, et al. Chem. Rev., 2011,255:1791- 1823 [6] Ma L, Abney C, Lin W. Chem. Soc. Rev., 2009,38:1248- 1256 [7] Barde T E. J. Am. Chem. Soc., 2006,128:898-904 [8] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352 [9] YANG Juan(杨娟), DAI Jun(戴俊), LI Fei-Fei(李飞飞). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(9): 1605-1611 [10]Nouar F, Eubank J F, Bousquet T, et al. J. Am. Chem. Soc., 2008,130:1833-1835 [11]Ono K, Yoshizawa M, Akita M, et al. J. Am. Chem. Soc., 2009,131:2782-2783 [12]LI Xiu-Mei(李秀梅), NIU Yan-Ling(牛艳玲), WANG Zhi- Tao(王志涛). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1659-1663 [13]Ryan P E, Lescop C, Laliberté D, et al. Inorg. Chem., 2009, 48:2793-2807 [14]LIU Tong-Fei(刘同飞), CUI Guang-Hua(崔广华), JIAO Cui- Huan(焦翠欢), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1417-1422 [15]DAI Jun(戴俊), YANG Juan(杨娟), CHEN Xi(陈曦). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1617- 1624 [16]SHI Zhi-Qiang(石智强), JI Ning-Ning(季宁宁), HE Guo- Fang(何国芳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1507-1512 [17]Wang X L, Qin C, Wang E B, et al. Chem. Commun., 2007, 34:4245-4247 [18]Kahn O. Molecular Magnetism. New York: VCH Publishers, 1993. [19](a)Chen Z L, Jiang C F, Yan W H, et al. Inorg. Chem., 2009, 48:4674-4675 (b)Pan Z R, Song Y, Jiao Y, et al. Inorg. Chem., 2008,47: 5162-5163 (c)Bouwman E, Huffman J C, et al. Inorg. Chem., 1992,31: 4436-4437
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沈阳化工大学材料科学与工程学院沈阳 110142