Citation: ZHANG Chun-Li, QIN Ling, YANG Qing-Xiang, SHI Zhi-Qiang, ZHENG He-Gen. Synthesis,Crystal Structure and Magnetic Property of the 2D Mn(Ⅱ) Coordination Polymer Based on 4,4'-Bisimidazolylbiphenyl and m-Phthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2157-2161. doi: 10.3969/j.issn.1001-4861.2013.00.321 shu

Synthesis,Crystal Structure and Magnetic Property of the 2D Mn(Ⅱ) Coordination Polymer Based on 4,4'-Bisimidazolylbiphenyl and m-Phthalic Acid

1.
1 School of Chemistry and Life Science, Suzhou University, Suzhou 234000, China;

Received Date: 19 March 2013
Available Online: 5 June 2013
Fund Project: 国家自然科学基金(No.91022011) (No.91022011)国家重点基础研究发展计划(No.2010CB923303)资助项目 (No.2010CB923303)

A 2D complex {[Mn(4,4'-bibp)(MPA)]·4H₂O}_n (1), based on mixed-ligands bibp (bibp=4,4'-bisimidazol-ylbiphenyl) and H₂MPA (H₂MPA=m-phthalic acid), has been synthesized by hydrothermal method and charac-terized by elemental analysis, IRspectra, XRD, TGA, and the crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the triclinic system, space group Pl, and features 2Dbilayer structure. Magnetic susceptibility measurement of complex 1 indicates the presence of weak antiferromagnetic interactions between the neighboring Mn(Ⅱ) ions. CCDC: 928642.
- Mn(Ⅱ) coordination polymer; crystal structure; magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142