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Citation: XIE Feng-Xia, ZHANG Dan, ZHANG Xin-Xin, HUA Min. Synthesis, Characterization, Structure and Thermal Decomposition of a Zn(Ⅱ) Complex Derived from Glycine Acid Cation and1, 10-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2162-2168. doi: 10.3969/j.issn.1001-4861.2013.00.320 shu

Synthesis, Characterization, Structure and Thermal Decomposition of a Zn(Ⅱ) Complex Derived from Glycine Acid Cation and1, 10-Phenanthroline

  • 1.

    School of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, China

  • Received Date: 16 February 2013
    Available Online: 30 May 2013

    Fund Project: 西安工程大学博士基金(No.BS0902)资助项目 (No.BS0902)

  • The new complex [Zn(gly)(phen)(H2O)2]2·2OH·SO4·4H2O(gly=Glycine acid cation, phen=1, 10-phenanthroline) has been synthesized and structurally characterized by X-ray single crystal diffraction, elemental analysis, infrared spectroscopy, thermogravimetric analysis and fluorescence spectrum. The complex crystal data: triclinic, space group Pl, a=1.17163(9) nm, b=1.28022(10) nm, c=1.34849(10) nm, α=74.4800°, β=85.4240(10) °, γ=69.8070°, V=1.8289(2) nm3, Z=2. The TG-DTGof the complex was analyzed, and the E and lnA were figured out by Coasts-Redfem method and Achar method. Fluorescence spectrum showed that the complex has very strong luminescence at 370 nm. CCDC: 876328.
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