Citation: XIONG Ying, LOU Zhen-Ning, SHAN Wei-Jun, REN Fu-Qiang, LI Ye-Xia, ZANG Shu-Liang. Recovery of Mo(Ⅵ) from Re(Ⅶ)-Containing Wastewater by Chemically Modified Orange Waste：Competitiveness and Selectivity[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1717-1723. doi: 10.3969/j.issn.1001-4861.2013.00.317 shu

Recovery of Mo(Ⅵ) from Re(Ⅶ)-Containing Wastewater by Chemically Modified Orange Waste：Competitiveness and Selectivity

1.
Key Laboratory of Rare-scattered Elements of Liaoning Province, School of Chemistry, Liaoning University, Shenyang 110036, China

Received Date: 25 February 2013
Available Online: 4 July 2013
Fund Project: 国家自然科学基金(No.21171080,21201094) (No.21171080,21201094)国家科技支撑计划(No.2012BAF03B00) (No.2012BAF03B00)辽宁省高等学校优秀人才支持计划(LJQ2012001)资助项目。 (LJQ2012001)

New adsorption gel (OW-NH₂) was prepared by chemically immobilizing functional group of amine orange waste. For the system of Mo(Ⅵ) coexisted with Re(Ⅶ), Pb(Ⅱ), Fe(Ⅲ), Zn(Ⅱ), Mn(Ⅶ) Ca(Ⅱ) and Cu(Ⅱ), the gel exhibits selectivity only for Mo(Ⅵ). The maximum adsorption capacity for Mo(Ⅵ) is 1.71 mmol·g^-1, and the adsorption behavior obeys the Langmuir model. The adsorption mechanism of molybdenum anion could be explained as the anion exchange reactions. In addition, the excellent adsorption characteristics for Mo(Ⅵ) are confirmed by separation of Mo(Ⅵ) from Mo-Re containing industrial effluent.
- adsorption;biomass;molybdenum;rhenium
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沈阳化工大学材料科学与工程学院沈阳 110142