Citation: WANG Shi, CUI Lin-Fang, LI Xing-Ao, WANG Lian-Hui, HUANG Wei. Synthesis, Crystal Structure and Magnetic Properties of a Tetragonally Compressed High-Spin Mn(Ⅲ) Schiff Base Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1733-1737. doi: 10.3969/j.issn.1001-4861.2013.00.313 shu

Synthesis, Crystal Structure and Magnetic Properties of a Tetragonally Compressed High-Spin Mn(Ⅲ) Schiff Base Complex

1.
Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210046, China

Received Date: 26 February 2013
Available Online: 24 June 2013
Fund Project: 国家自然科学基金(No.51173082) (No.51173082)

The synthesis, crystal structure and magnetic properties of a new six-coordinated high-spin (HS) Mn(Ⅲ) Schiff base complex, [Mn^Ⅲ(3-MeO-sal-N(1,5,9,13))]ClO₄H₂O (1) are described. The ligand 3-MeO-sal-N(1,5,9,13) is a hexadentate Schiff base obtained from N,N'-bis(3-aminopropyl)-1,3-propanediamine and 2-hydroxy-3-methoxy benzaldehyde. Compound 1 crystallizes in monoclinic space group P2₁/c, with a=0.806 43(2) nm, b=2.049 31(4) nm, c=1.709 74(3) nm, β=101.302 0(10)°, V=2.770 77(10) nm3, Z=4, R=0.055 4 and wR=0.136 0 (I >2σ(I)). Single crystal X-ray diffraction analysis reveals that the Mn site has a tetragonally compressed octahedral geometry. The magnetic susceptibilities measurements indicate the HS ground state in the temperature range 1.8~300 K. The magnetic data are well fitted by Zero-Field-Splitting (ZFS) Hamiltonian, showing a D >0 parameter, in line with the compressed octahedron pattern. CCDC: 926103.
- manganese(Ⅲ) complex;axial compression, magnetic anisotropy
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沈阳化工大学材料科学与工程学院沈阳 110142