Citation: ZHANG Xin, CHEN Lin, WANG Hai-Fang, CAO Ao-Neng. One-Step Microwaving Method to Synthesize Graphene-CdS Nanocomposite[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1675-1679. doi: 10.3969/j.issn.1001-4861.2013.00.312 shu

One-Step Microwaving Method to Synthesize Graphene-CdS Nanocomposite

1.
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received Date: 27 February 2013
Available Online: 19 June 2013
Fund Project: 国家自然科学基金(No.21073117和No.21071094)资助项目。 (No.21073117和No.21071094)

Graphene-CdS nanocomposite is a very promising optoelectronic material, and its optoelectronic properties are critically dependent on the distribution of CdS nanoparticles (NPs) on single sheets of graphene. Herein, we developed a facile one-step one-pot microwaving method to produce graphene-CdS nanocomposite, only involving of a few minutes' microwaving of the mixture of graphene oxide (GO), dihydrate acid cadmium and thioacetamide in 90% ethylene glycol solvent. The whole process is simple, efficient and environmental friendly. This method is an improvement of our previous dimethyl sulfoxide method (Adv. Mater., 2010,22:103-106). Using stoichiometric thioacetamide as the sulfur source, the current method avoided the byproduct of hazard hydrogen sulfide gas of the previous method. While using GO as the initial material, which was simultaneously reduced during the microwaving process as CdS NPs grew on graphene sheet, guaranteed that graphene was mainly single-layer sheets in the final nanocomposite. TEM and XRD results show that well-crystallized CdS NPs of a blende structure with an average diameter of about 5.7 nm nicely distributed on single graphene sheets with almost no aggregation.
- graphene;CdS;nanocomposite;microwave reaction
1. [1]
  [1] Abergel D S L, Russell A, Fal'ko V I. Appl. Phys. Lett., 2007,91(6):063125(3pp)
2. [2]
  [2] An S J, Zhu Y W, Lee S H, et al. J. Phys. Chem. Lett., 2010,1:1259-1263
3. [3]
  [3] Ansari S, Giannelis E P. J. Polym. Sci. Pol. Phys., 2009,47: 888-897
4. [4]
  [4] Artiles M S, Rout C S, Fisher T S, et al. Adv. Drug Deliv. Rev., 2011,63:1352-1360
5. [5]
  [5] Kuila T, Bose S, Khanra P, et al. Biosens. Bioelectron., 2011,26:4637-4648
6. [6]
  [6] Grande L, Chundi V T, Weib D, et al. Particuology, 2012, 10:1-8
7. [7]
  [7] Velten J, Mozer A J, Li D, et al. Nanotechnology, 2012,23 (8):0805201(6pp)
8. [8]
  [8] Xu G, Liu J, Wang Q, et al. Adv. Mater., 2012,24:OP71-OP76
9. [9]
  [9] Chen S, Chrzan D C. Phys. Rev. B. Condens. Matter. Mater. Phys., 2011,84:195409(4pp)
10. [10]
  [10] Zhang Y H, Tang Z R, Fu X Z, et al. ACS Nano, 2010,4: 7303-7314
11. [11]
  [11] Zhang H, Lü X J, Li Y M, et al. ACS Nano, 2010,4:380-386
12. [12]
  [12] Akhavan O, Ghaderi E. J. Phys. Chem. C, 2009,113:20214-20220
13. [13]
  [13] Chen C, Cai W M, Long M C, et al. ACS Nano, 2010,4: 6425-6432
14. [14]
  [14] Xu T G, Zhang L W, Cheng H Y, et al. Appl. Catal. B, 2011,101:382-387
15. [15]
  [15] CHEN Qi-Yuan(陈启元), LAN Ke(兰可), YI Zhou-Lan(尹周澜), et al. Mater. Rev.(Cailiao Daobao), 2005,19(1):20-23
16. [16]
  [16] Niemeyer C M. Angew. Chem. Int. Ed., 2003,42(47):5796-5800
17. [17]
  [17] Zhao H Y, Douglas E P, Harrison B S, et al. Langmuir, 2001,17(26):8428-8433
18. [18]
  [18] Li Q, Guo B D, Yu J G, et al. J. Am. Chem. Soc., 2011,133 (28):10878-10884
19. [19]
  [19] Zhao X M, Zhou S W, Jiang L P, et al. Chem. Eur. J., 2012, 18:4974-4981
20. [20]
  [20] Ye A H, Fan W Q, Zhang Q H, et al. Catal. Sci. Technol., 2012,2:969-978
21. [21]
  [21] Cao A N, Liu Z, Chu S S, et al. Adv. Mater., 2010,22:103-106
22. [22]
  [22] CHANG Yan-Li(常艳丽), CHEN Sheng(陈胜), CAO Ao-Neng(曹傲能). J. Shanghai Univ.: Nat. Sci. Ed.(Shanghai Daxue Xuebao: Ziran Kexueban), 2010,16(6):577-581
23. [23]
  [23] ZHOU Tian(周田), CHEN Bing-Di(陈炳地), YAO Ai-Hua (姚爱华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013,29(2):231-236
24. [24]
  [24] Tang L H, Wang Y, Li Y M, et al. Adv. Funct. Mater., 2009,19:2782-2789
25. [25]
  [25] Perebeinos V, Tersoff J, Avouris P. Phys. Rev. Lett., 2005, 94:086802(4pp)
26. [26]
  [26] MIN Shi-Xiong (敏世雄), LÜ Gong-Xuan (吕功煊). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(9):2178-2184
27. [27]
  [27] Xu Y, Bai H, Lu G, et al. J. Am. Chem. Soc., 2008,130(18): 5856-5857
28. [28]
  [28] HAN Zhi-Dong(韩志东), WANG Jian-Qi(王建祺). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(5):459-461
29. [29]
  [29] Zhao X, Zhou S, Shen Q, et al. Analyst, 2012,137:3697-3703
30. [30]
  [30] Li Y J, Ma M J, Yin G, et al. Chem. Eur. J., doi:10.1002/chem.201203521
31. [31]
  [31] Yang S T, Chang Y, Wang H, et al. J. Colloid Interface Sci., 2010,351(1):122-127
32. [32]
  [32] Wang C L, Zhang H, Lin Z, et al. Langmuir, 2009,25(17): 10237-10242
1. [1]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
2. [2]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
3. [3]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
6. [6]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
7. [7]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
8. [8]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
9. [9]
  Shiqian WEI , Xinyu TIAN , Hong LIU , Maoxia CHEN , Fan TANG , Qiang FAN , Weifeng FAN , Yu HU . Oxygen reduction reaction/oxygen evolution reaction catalytic performances of different active sites on nitrogen-doped graphene loaded with iron single atoms. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1776-1788. doi: 10.11862/CJIC.20250102
10. [10]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
11. [11]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
12. [12]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
13. [13]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
14. [14]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
15. [15]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
16. [16]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
17. [17]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
18. [18]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . Nanoscale Mechanism of Microstructure-Dependent Thermal Diffusivity in Thick Graphene Sheets. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-0. doi: 10.3866/PKU.WHXB202404024
19. [19]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . High-Precision and Reliable Thermal Conductivity Measurement for Graphene Films Based on an Improved Steady-State Electric Heating Method. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-0. doi: 10.1016/j.actphy.2025.100045
20. [20]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(450)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142