Citation: ZHANG Xin, CHEN Lin, WANG Hai-Fang, CAO Ao-Neng. One-Step Microwaving Method to Synthesize Graphene-CdS Nanocomposite[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1675-1679. doi: 10.3969/j.issn.1001-4861.2013.00.312 shu

One-Step Microwaving Method to Synthesize Graphene-CdS Nanocomposite

1.
Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received Date: 27 February 2013
Available Online: 19 June 2013
Fund Project: 国家自然科学基金(No.21073117和No.21071094)资助项目。 (No.21073117和No.21071094)

Graphene-CdS nanocomposite is a very promising optoelectronic material, and its optoelectronic properties are critically dependent on the distribution of CdS nanoparticles (NPs) on single sheets of graphene. Herein, we developed a facile one-step one-pot microwaving method to produce graphene-CdS nanocomposite, only involving of a few minutes' microwaving of the mixture of graphene oxide (GO), dihydrate acid cadmium and thioacetamide in 90% ethylene glycol solvent. The whole process is simple, efficient and environmental friendly. This method is an improvement of our previous dimethyl sulfoxide method (Adv. Mater., 2010,22:103-106). Using stoichiometric thioacetamide as the sulfur source, the current method avoided the byproduct of hazard hydrogen sulfide gas of the previous method. While using GO as the initial material, which was simultaneously reduced during the microwaving process as CdS NPs grew on graphene sheet, guaranteed that graphene was mainly single-layer sheets in the final nanocomposite. TEM and XRD results show that well-crystallized CdS NPs of a blende structure with an average diameter of about 5.7 nm nicely distributed on single graphene sheets with almost no aggregation.
- graphene;CdS;nanocomposite;microwave reaction
1. [1]
  [1] Abergel D S L, Russell A, Fal'ko V I. Appl. Phys. Lett., 2007,91(6):063125(3pp)
2. [2]
  [2] An S J, Zhu Y W, Lee S H, et al. J. Phys. Chem. Lett., 2010,1:1259-1263
3. [3]
  [3] Ansari S, Giannelis E P. J. Polym. Sci. Pol. Phys., 2009,47: 888-897
4. [4]
  [4] Artiles M S, Rout C S, Fisher T S, et al. Adv. Drug Deliv. Rev., 2011,63:1352-1360
5. [5]
  [5] Kuila T, Bose S, Khanra P, et al. Biosens. Bioelectron., 2011,26:4637-4648
6. [6]
  [6] Grande L, Chundi V T, Weib D, et al. Particuology, 2012, 10:1-8
7. [7]
  [7] Velten J, Mozer A J, Li D, et al. Nanotechnology, 2012,23 (8):0805201(6pp)
8. [8]
  [8] Xu G, Liu J, Wang Q, et al. Adv. Mater., 2012,24:OP71-OP76
9. [9]
  [9] Chen S, Chrzan D C. Phys. Rev. B. Condens. Matter. Mater. Phys., 2011,84:195409(4pp)
10. [10]
  [10] Zhang Y H, Tang Z R, Fu X Z, et al. ACS Nano, 2010,4: 7303-7314
11. [11]
  [11] Zhang H, Lü X J, Li Y M, et al. ACS Nano, 2010,4:380-386
12. [12]
  [12] Akhavan O, Ghaderi E. J. Phys. Chem. C, 2009,113:20214-20220
13. [13]
  [13] Chen C, Cai W M, Long M C, et al. ACS Nano, 2010,4: 6425-6432
14. [14]
  [14] Xu T G, Zhang L W, Cheng H Y, et al. Appl. Catal. B, 2011,101:382-387
15. [15]
  [15] CHEN Qi-Yuan(陈启元), LAN Ke(兰可), YI Zhou-Lan(尹周澜), et al. Mater. Rev.(Cailiao Daobao), 2005,19(1):20-23
16. [16]
  [16] Niemeyer C M. Angew. Chem. Int. Ed., 2003,42(47):5796-5800
17. [17]
  [17] Zhao H Y, Douglas E P, Harrison B S, et al. Langmuir, 2001,17(26):8428-8433
18. [18]
  [18] Li Q, Guo B D, Yu J G, et al. J. Am. Chem. Soc., 2011,133 (28):10878-10884
19. [19]
  [19] Zhao X M, Zhou S W, Jiang L P, et al. Chem. Eur. J., 2012, 18:4974-4981
20. [20]
  [20] Ye A H, Fan W Q, Zhang Q H, et al. Catal. Sci. Technol., 2012,2:969-978
21. [21]
  [21] Cao A N, Liu Z, Chu S S, et al. Adv. Mater., 2010,22:103-106
22. [22]
  [22] CHANG Yan-Li(常艳丽), CHEN Sheng(陈胜), CAO Ao-Neng(曹傲能). J. Shanghai Univ.: Nat. Sci. Ed.(Shanghai Daxue Xuebao: Ziran Kexueban), 2010,16(6):577-581
23. [23]
  [23] ZHOU Tian(周田), CHEN Bing-Di(陈炳地), YAO Ai-Hua (姚爱华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013,29(2):231-236
24. [24]
  [24] Tang L H, Wang Y, Li Y M, et al. Adv. Funct. Mater., 2009,19:2782-2789
25. [25]
  [25] Perebeinos V, Tersoff J, Avouris P. Phys. Rev. Lett., 2005, 94:086802(4pp)
26. [26]
  [26] MIN Shi-Xiong (敏世雄), LÜ Gong-Xuan (吕功煊). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(9):2178-2184
27. [27]
  [27] Xu Y, Bai H, Lu G, et al. J. Am. Chem. Soc., 2008,130(18): 5856-5857
28. [28]
  [28] HAN Zhi-Dong(韩志东), WANG Jian-Qi(王建祺). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(5):459-461
29. [29]
  [29] Zhao X, Zhou S, Shen Q, et al. Analyst, 2012,137:3697-3703
30. [30]
  [30] Li Y J, Ma M J, Yin G, et al. Chem. Eur. J., doi:10.1002/chem.201203521
31. [31]
  [31] Yang S T, Chang Y, Wang H, et al. J. Colloid Interface Sci., 2010,351(1):122-127
32. [32]
  [32] Wang C L, Zhang H, Lin Z, et al. Langmuir, 2009,25(17): 10237-10242
1. [1]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
3. [3]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
4. [4]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
5. [5]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
8. [8]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
9. [9]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
10. [10]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
15. [15]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
16. [16]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
17. [17]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
18. [18]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
19. [19]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
20. [20]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(293)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142