Citation: YUAN Guo-Zan, RONG Lu-Lu, QIAO Xue-Long, XIA Yin-Pan, GUO Ting, WEI Xian-Wen. Synthesis, Crystal Structures and Properties of One Binuclear Zinc Complex from a Novel 2-Substituted-8-Hydroxyquinoline Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1769-1776. doi: 10.3969/j.issn.1001-4861.2013.00.310 shu

Synthesis, Crystal Structures and Properties of One Binuclear Zinc Complex from a Novel 2-Substituted-8-Hydroxyquinoline Ligand

1.
School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Received Date: 27 February 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.21201002和21271006) (No.21201002和21271006)安徽省自然科学基金(1308085QB22) (1308085QB22)安徽工业大学SRTP(2013027Y) 资助项目。 (2013027Y)

A 2-substituted-8-hydroxyquinoline ligand (E)-2-[2-(4-Methoxyphenyl)ethenyl]-8-hydroxyquinoline (HL) was synthesized in two steps from the readily available and cheap 8-hydroxyquinaldine and characterized by LC-MS, NMR spectroscopy, elemental analysis and X-ray crystallography. Using solvothermal method, a crystalline complex Zn₂L₄(1) was obtained by reacting Zn(Ⅱ) ions with ligand HL. X-ray structural analysis shows that 1 exhibits a binuclear core, which is bridged by two 8-hydroxyquinoline rings. The supramolecular structure of 1 features a 3D supramolecular structure constructed by π…π aromatic stacking interactions, nonclassical C-H…O hydrogen bonds and C-H…π interactions. The aggregation behavior of zinc salts and HL in solutions was investigated with UV-vis and PL spectra. Additionally, we also studied the photophysical properties of compound 1 by PL. The results showed that complex 1 exhibits a red shift compared with free ligand HL and emits yellow luminescence. CCDC:923979,HL;923980,1.
- 2-substituted-8-hydroxyquinoline;binuclear complex;crystal structure;photophysical properties
1. [1]
  [1] Tang C W, VanSlyke S A. Appl. Phys. Lett., 1987,51:913-915
2. [2]
  [2] Chen C H, Shi J. Coord. Chem. Rev., 1998,171:161-174
3. [3]
  [3] Brinkmann M, Gadret G, Muccini M, et al. J. Am. Chem. Soc., 2000,122:5147-5157
4. [4]
  [4] Kulkarni A P, Tonzola C J, Babel A, et al. Chem. Mater., 2004,16:4556-4573
5. [5]
  [5] Hopkins T A, Meerholz K, Shaheen S, et al. Chem. Mater., 1996,8:344-351
6. [6]
  [6] Kunkely H, Vogler A. Chem. Phys. Lett., 2003,376:226-229
7. [7]
  [7] Miozzo L, Papagni A, Casalbore-Miceli G, et al. Chem. Mater., 2004,16:5124-5132
8. [8]
  [8] Albrecht M, Fiege M, Osetska O. Coord. Chem. Rev., 2008, 252:812-824
9. [9]
  [9] Li S, Lu J, Xu J, et al. J. Mater. Chem., 2010,20:9718-9725
10. [10]
  [10] Zheng Y, Shi C, Liang Y, et al. Synth. Met., 2000,114(03): 321-323
11. [11]
  [11] Farinola G M, Ragni R. Chem. Soc. Rev., 2011,40:3467-3482
12. [12]
  [12] Huang Q L, Li J F, Marks T J. J. Appl. Phys., 2007,101(09): 093101-093113
13. [13]
  [13] Sapochak L S, Benincasa F E, Schofield R S, et al. J. Am. Chem. Soc., 2002,124(21):6119-6125
14. [14]
  [14] Pohl R, Jr. Anzenbacher P. Org. Lett., 2003,5(16):2769-2772
15. [15]
  [15] Sokoowski K, Justyniak I, liwiński W, et al. Chem. Eur. J., 2012,18:5637-5645
16. [16]
  [16] Yuan G Z, Huo Y P, Rong L L, et al. Inorg. Chem. Commun., 2012,23:90-94
17. [17]
  [17] Yuan G Z, Huo Y P, Nie X L, et al. Dalton Trans., 2013,42: 2921-2929
18. [18]
  [18] Chen C H, Shi J. Coord. Chem. Rev., 1998,171:161-174
19. [19]
  [19] Sheldrick G M. SHELXS 97, Program for Crystal Structure Solution, University of Göttingen: Göttingen, Germany, 1997.
20. [20]
  [20] Sheldrick G M. SHELXS 97, Program for Crystal Structure Solution, University of Götingen: Göttingen, Germany, 1997.
21. [21]
  [21] Wu Q, Esteghamatian M, Hu N X, et al. Chem. Mater., 2000,12:79-83
22. [22]
  [22] CHEN Shu-Yang (陈书阳), ZHAO Wei (赵伟),GUO Ying-Chen (郭应臣). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013,29(6):1165-1170
23. [23]
  [23] TIAN Jing(田婧), DONG Li-Na(董丽娜), ZHAO Kai(赵凯), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28(1):113-118
24. [24]
  [24] Perkovic M W. Inorg. Chem., 2000,39(21):4962-4968
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沈阳化工大学材料科学与工程学院沈阳 110142