Citation: YUAN Guo-Zan, RONG Lu-Lu, QIAO Xue-Long, XIA Yin-Pan, GUO Ting, WEI Xian-Wen. Synthesis, Crystal Structures and Properties of One Binuclear Zinc Complex from a Novel 2-Substituted-8-Hydroxyquinoline Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1769-1776. doi: 10.3969/j.issn.1001-4861.2013.00.310 shu

Synthesis, Crystal Structures and Properties of One Binuclear Zinc Complex from a Novel 2-Substituted-8-Hydroxyquinoline Ligand

1.
School of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan, Anhui 243002, China

Received Date: 27 February 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.21201002和21271006) (No.21201002和21271006)安徽省自然科学基金(1308085QB22) (1308085QB22)安徽工业大学SRTP(2013027Y) 资助项目。 (2013027Y)

A 2-substituted-8-hydroxyquinoline ligand (E)-2-[2-(4-Methoxyphenyl)ethenyl]-8-hydroxyquinoline (HL) was synthesized in two steps from the readily available and cheap 8-hydroxyquinaldine and characterized by LC-MS, NMR spectroscopy, elemental analysis and X-ray crystallography. Using solvothermal method, a crystalline complex Zn₂L₄(1) was obtained by reacting Zn(Ⅱ) ions with ligand HL. X-ray structural analysis shows that 1 exhibits a binuclear core, which is bridged by two 8-hydroxyquinoline rings. The supramolecular structure of 1 features a 3D supramolecular structure constructed by π…π aromatic stacking interactions, nonclassical C-H…O hydrogen bonds and C-H…π interactions. The aggregation behavior of zinc salts and HL in solutions was investigated with UV-vis and PL spectra. Additionally, we also studied the photophysical properties of compound 1 by PL. The results showed that complex 1 exhibits a red shift compared with free ligand HL and emits yellow luminescence. CCDC:923979,HL;923980,1.
- 2-substituted-8-hydroxyquinoline;binuclear complex;crystal structure;photophysical properties
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沈阳化工大学材料科学与工程学院沈阳 110142