Citation: Han A-Li, Du Ping-Wu. Platinum-Cobalt Dinuclear Complex：Synthesis, Photophysical Properties and Visible Light-Driven Hydrogen Production from Water[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1703-1709. doi: 10.3969/j.issn.1001-4861.2013.00.309 shu

Platinum-Cobalt Dinuclear Complex：Synthesis, Photophysical Properties and Visible Light-Driven Hydrogen Production from Water

Han A-Li ,
Du Ping-Wu

1.
Key Laboratory of Materials for Energy Conversion of Chinese Academy of Sciences & Department of Materials Science and Engineering, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230026 China

Received Date: 28 February 2013
Available Online: 14 June 2013
Fund Project: 国家自然科学基金(No.21271166)资助项目。 (No.21271166)

A platinum sensitizer-cobalt dinuclear complex, [Pt(^tBu₃tpy)([C≡C-C₆H₄N])-Co(dmgH)₂PyCl, 5] (^tBu₃tpy=4,4',4"-tri(tert-butyl)-2,2':6',2"-terpyridine, C₆H₄N=4-pyridyl, dmgH=dimethylglyoxime, Py=pyridine), has been synthesized and characterized. The complex 5 shows absorption spectra in the visible region, which are assigned to mainly metal-to-ligand charge transfer (MLCT) character from the platinum sensitizer part. The cobalt moiety in complex 5 could quench the luminescence of the platinum part, indicating a possible process of intramolecular electron transfer. This dinuclear complex has been used for light-driven catalytic hydrogen production from water in the presence of triethanolamine (TEOA). The hydrogen production is affected by many factors, such as pH value and solvent. And the results show that this molecular catalyst could be decomposed to release the platinum based photosensitizer, as confirmed by absorption spectra and mass spectrometry.
- platinum;photosensitizer;cobalt;hydrogen production
1. [1]
  [1] Kalyanasundaram K, Kiwi J, Gratzel M. Helv. Chim. Acta, 1978,61:2720-2730
2. [2]
  [2] Esswein A J, Nocera D G. Chem. Rev., 2007,107:4022-4047
3. [3]
  [3] Goldsmith J I, Hudson W R, Lowry M S, et al. J. Am. Chem. Soc., 2005,127:7502-7510
4. [4]
  [4] Du P W, Schneider J, Jarosz P, et al. J. Am. Chem. Soc., 2006,128:7726-7727
5. [5]
  [5] Du P W, Schneider J, Jarosz P, et al. J. Phys. Chem. B, 2007, 111:6887-6894
6. [6]
  [6] Du P W, Eisenberg R. Energy Environ. Sci., 2012,5:6012-6021
7. [7]
  [7] Artero V, Chavarot-Kerlidou M, Fontecave M. Angew. Chem. Int. Ed., 2011,50:7238-7266
8. [8]
  [8] Razavet M, Artero V, Fontecave M. Inorg. Chem., 2005,44: 4786-4795
9. [9]
  [9] Baffert C, Artero V, Fontecave M. Inorg. Chem., 2007,46: 1817-1824
10. [10]
  [10] Du P W, Knowles K, Eisenberg R. J. Am. Chem. Soc., 2008, 130:12576-12577
11. [11]
  [11] Zhang P, Wang M, Dong J, et al. J. Phys. Chem. C, 2010, 114:15868-15874
12. [12]
  [12] Hu X, Brunschwig B S, Peters J C. J. Am. Chem. Soc., 2007, 129:8988-8998
13. [13]
  [13] Hu X, Cossairt B M, Brunschwig B S, et al. Chem. Commun., 2005,37:4723-4725
14. [14]
  [14] Dempsey J L, Brunschwig B S, Winkler J R, et al. Acc. Chem. Res., 2009,42:1995-2004
15. [15]
  [15] Ozawa H, Haga M A, Sakai K. J. Am. Chem. Soc., 2006, 128:4926-4927
16. [16]
  [16] Rau S, Schfer B, Gleich D, et al. Angew. Chem. Int. Ed., 2006,45:6215-6218
17. [17]
  [17] Elvington M, Brown J, Arachchige S M, et al. J. Am. Chem. Soc., 2007,129:10644-10645
18. [18]
  [18] Fihri A, Artero V, Pereira A, et al. Dalton Trans., 2008,41: 5567-5569
19. [19]
  [19] Fihri A, Artero V, Razavet M, et al. Angew. Chem. Int. Ed., 2008,47:564-567
20. [20]
  [20] Zhang P, Wang M, Li C, et al. Chem. Commun., 2010,46: 8806-8808
21. [21]
  [21] Artero V, Chavarot-Kerlidou M, Fontecave M. Angew. Chem. Int. Ed., 2011,50:7238-7266
22. [22]
  [22] Lai S W, Chan M C W, Cheung K K, et al. Inorg. Chem., 1999,38:4262-4267
23. [23]
  [23] Yam V W W, Tang R P L, Wong K M C, et al. Organometallics 2001,20:4476-4482.
24. [24]
  [24] Yang Q Z, Wu L Z, Wu Z X, et al. Inorg. Chem., 2002,41: 5653-5655.
25. [25]
  [25] Calvert J M, Caspar J V, Binstead R A, et al. J. Am. Chem. Soc., 1982,104:6620-6627
26. [26]
  [26] Chakraborty S, Wadas T J, Hester H, et al. Inorg. Chem., 2005,44:6284-6293
27. [27]
  [27] Chakraborty S, Wadas T J, Hester H, et al. Inorg. Chem., 2005,44:6865-6878
28. [28]
  [28] McCormick T M, Han Z, Weinberg D J, et al. Inorg. Chem., 2011,50:10660-10666
1. [1]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
2. [2]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
3. [3]
  Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
4. [4]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
7. [7]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
8. [8]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
10. [10]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
11. [11]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
12. [12]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
13. [13]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
14. [14]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
15. [15]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
18. [18]
  Congying Wen , Zhengkun Du , Yukun Lu , Zongting Wang , Hua He , Limin Yang , Jingbin Zeng . Teaching Reform and Practice of Modern Analytical Technology under the Integration of Science, Industry, and Education. University Chemistry, 2024, 39(8): 104-111. doi: 10.3866/PKU.DXHX202312089
19. [19]
  Hengwei Wei , Liqiu Zhao , Jiqiang Geng , Xuebo Xu , Yingpeng Ma , Yuhao Liu , Mingzhe Han , Huan Jiao , Lingling Wei . Research on Safety Management of Hazardous Chemicals and Talent Cultivation in Universities Driven by Production-Education Integration. University Chemistry, 2024, 39(10): 289-298. doi: 10.12461/PKU.DXHX202403022
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(182)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142