Citation: CHEN Gong-De, ZHANG Wei-Xin, YANG Ze-Heng, WANG Qiang, YAO Hong-Xu. Lithium Storage Performances of TiO₂ Nanotube Arrays on Copper Substrate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1759-1768. doi: 10.3969/j.issn.1001-4861.2013.00.308 shu

Lithium Storage Performances of TiO₂ Nanotube Arrays on Copper Substrate

1.
School of Chemical Engineering, Hefei University of Technology, Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei 230009, China

Received Date: 26 February 2013
Available Online: 10 June 2013
Fund Project: 国家自然科学基金(No.21271058, 21176054, 20871038) (No.21271058, 21176054, 20871038)安徽省教育厅创新团队项目(TD200702)资助项目。 (TD200702)

Lithium storage performances of TiO₂ nanotube arrays on copper substrate as electrodes in lithium-ion batteries were investigated. Amorphous TiO₂ nanotube arrays were prepared via a sacrificial template method from outward coating of TiO₂ and inward etching of Cu(OH)₂ nanorod array templates on copper substrate. Anatase TiO₂ nanotube arrays were obtained by post-heating the sample at 500 ℃ for 4 h. The samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). The electrochemical performances of amorphous and anatase TiO₂ nanotube arrays were investigated by galvanostatic charge-discharge measurements, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results indicate that compared with amorphous TiO₂ nanotube arrays, anatase TiO₂ nanotube arrays exhibit a superior rate capability and cycling performance due to their lower amounts of adsorbed water, higher crystallization, lower charge-transfer resistance, higher lithium-ion diffusion coefficient, and more stable one-dimensional tubular structure. They show an initial specific discharge capacity of 353 mAh·g^-1 and 243 mAh·g^-1 even after 40 cycles at 0.2C. At a high rate of 8C, their discharge capacity can reach 90 mAh·g^-1.
- TiO₂;nanotube arrays;templates;anode;lithium-ion batteries
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Lithium Storage Performances of TiO2 Nanotube Arrays on Copper Substrate

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通讯作者: 陈斌, bchen63@163.com

Lithium Storage Performances of TiO₂ Nanotube Arrays on Copper Substrate