Citation:
CHEN Gong-De, ZHANG Wei-Xin, YANG Ze-Heng, WANG Qiang, YAO Hong-Xu. Lithium Storage Performances of TiO2 Nanotube Arrays on Copper Substrate[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(8): 1759-1768.
doi:
10.3969/j.issn.1001-4861.2013.00.308
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Lithium storage performances of TiO2 nanotube arrays on copper substrate as electrodes in lithium-ion batteries were investigated. Amorphous TiO2 nanotube arrays were prepared via a sacrificial template method from outward coating of TiO2 and inward etching of Cu(OH)2 nanorod array templates on copper substrate. Anatase TiO2 nanotube arrays were obtained by post-heating the sample at 500 ℃ for 4 h. The samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and thermogravimetric analysis (TGA). The electrochemical performances of amorphous and anatase TiO2 nanotube arrays were investigated by galvanostatic charge-discharge measurements, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results indicate that compared with amorphous TiO2 nanotube arrays, anatase TiO2 nanotube arrays exhibit a superior rate capability and cycling performance due to their lower amounts of adsorbed water, higher crystallization, lower charge-transfer resistance, higher lithium-ion diffusion coefficient, and more stable one-dimensional tubular structure. They show an initial specific discharge capacity of 353 mAh·g-1 and 243 mAh·g-1 even after 40 cycles at 0.2C. At a high rate of 8C, their discharge capacity can reach 90 mAh·g-1.
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-
[1]
[1] Wagemaker M, Kearley G J, Well A A, et al. J. Am. Chem. Soc., 2003,125:840-848
-
[2]
[2] Macklin W J, Neat R J. Solid State Ionics, 1992,53:694-700
-
[3]
[3] Chen J S, Lou X W. Electrochem. Commun., 2009,11:2332-2335
-
[4]
[4] Bao S J, Bao Q L, Li C M, et al. Electrochem. Commun., 2007, 9:1233-1238
-
[5]
[5] Xu J W, Jia C H, Cao B, et al. Electrochim. Acta, 2007,52: 8044-8047
-
[6]
[6] Chen J S, Tan Y L, Li C M, et al. J. Am. Chem. Soc., 2010, 132:6124-6130
-
[7]
[7] Wang D W, Fang H T, Li F, et al. Adv. Funct. Mater., 2008,18:3787-3793
-
[8]
[8] Jiang J, Liu J P, Ding R M, et al. J. Phys. Chem. C, 2010,114: 929-932
-
[9]
[9] Wang J, Lin Z Q. Chem. Mater., 2008,20:1257-1261
-
[10]
[10] Yoriya S, Paulose M, Varghese O K, et al. J. Phys. Chem. C, 2007,111:13770-13776
-
[11]
[11] Lakshmi B B, Dorhout P K, Martin C R. Chem. Mater., 1997, 9:857-862
-
[12]
[12] Li X H, Liu W M, Li H L. Appl. Phys. A, 2005,80:317-320
-
[13]
[13] Tian Z R, Voigt J A, Liu J, et al. J. Am. Chem. Soc., 2003, 125:12384-12385
-
[14]
[14] Ortiz G F, Hanzu I, Djenizian T, et al. Chem. Mater., 2009,21: 63-67
-
[15]
[15] Fang H T, Liu M, Wang D W, et al. Nanotechnol., 2009,20:1-7
-
[16]
[16] Zhang W X, Chen G D, Yang Z H, et al. AIChE J., 2013,59: 2134-2144
-
[17]
[17] Zhang W X, Xu J, Yang Z H, et al. Chem. Phys. Lett., 2007, 434:256-259
-
[18]
[18] Xu J, Zhang W X, Yang Z H, et al. Inorg. Chem., 2008,47: 699-704
-
[19]
[19] Ortiz G F, Hanzu I, Knauth P, et al. Electrochim. Acta, 2009, 54:4262-4268
-
[20]
[20] Lou X W, Archer L A, Yang Z C. Adv. Mater., 2008,20:3987-4019
-
[21]
[21] Li H Q, Martha S K, Unocic R R, et al. J. Power Sources, 2012,218:88-92
-
[22]
[22] Pei B, Yao H X, Zhang W X, et al. J. Power Sources, 2012, 220:317-323
-
[23]
[23] Bard A J, Faulkner L R. Electrochemical Methods; Fundamentals and Applications. New York: John Wiley & Sons, Inc., 1980:378-387
-
[24]
[24] Krol R, Goossens A, Schoonman J. J. Phys. Chem. B, 1999, 103:7151-7159
-
[25]
[25] Wang J, Polleux J, Lim J, et al. J. Phys. Chem. C, 2007,111: 14925-14931.
-
[26]
[26] Cava R J, Murphy D W, Zahurak S. J. Solid State Chem., 1984,53:64-75
-
[27]
[27] Nuspl G, Yoshizawa K, Yamabe T. J. Mater. Chem., 1997,7: 2529-2536
-
[28]
[28] Shin J Y, Samuelis D, Maier J. Adv. Funct. Mater., 2011,21: 3464-347
-
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