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Citation: PAN Hui, BAI Yan, AN Bing, DANG Dong-Bin. Crystal Structure and Spectral Properties of a One-Dimensional Coordination Polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (H2dpa=2,2’-biphenyldicarboxylate, dpdo=4,4’-bipyridine-N,N’-dioxide)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1710-1716. doi: 10.3969/j.issn.1001-4861.2013.00.307 shu

Crystal Structure and Spectral Properties of a One-Dimensional Coordination Polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (H2dpa=2,2’-biphenyldicarboxylate, dpdo=4,4’-bipyridine-N,N’-dioxide)

  • 1.

    Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

  • Received Date: 29 March 2013
    Available Online: 12 June 2013

    Fund Project: 国家自然科学基金(No.21071044)资助项目。 (No.21071044)

  • A new Co(Ⅱ) coordination polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (1) (H2dpa=2,2'-biphenyldicarboxy-late, dpdo=4,4'-bipyridine-N,N'-dioxide) has been synthesized and characterized by IR spectroscopy, UV-Vis spectroscopy, elemental analysis, XRPD, TGA and X-ray single-crystal structure analysis. The Co(Ⅱ) atom has a distorted octahedral coordination environment with a set of oxygen donors from two dpa2- ligands and four coordinated water molecules. Each dpa2- ligand is bounded to two cobalt centers and each cobalt atom is coordinated by two dpa2- ligands thereby generating a 21 helical chain. The helical chains further interact with each other and form a 2D network through multiform O-H…O hydrogen bonds with the help of the solvent water. In the solid state the adjacent layers are separated by dpdo units to form a 3D framework. Upon the excitation at 275 nm, the polymer 1 shows one emission peak at 430 nm in the solid state. CCDC: 922034.
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    1. [1]

      [1] Zhang Z J, Zhao Y G, Gong Q H, et al. Chem. Commun., 2013,49:653-661

    2. [2]

      [2] Carson F, Agrawal S, Gustafsson M, et al. Chem. Eur. J., 2012,18:15337-15344

    3. [3]

      [3] Wang K B, Geng Z R, Zheng M B, et al. Cryst. Growth Des., 2012,12:5606-5614

    4. [4]

      [4] Bai Z S, Qi Z P, Lu Y, et al. Cryst. Growth Des., 2008,8: 1924-1931

    5. [5]

      [5] Liu G X, Zhu K, Xu H M, et al. CrystEngComm, 2009,11: 2784-2796

    6. [6]

      [6] Selvakumar P M, Suresh E, Subramanian P S. Inorg. Chim. Acta, 2008,361:1503-1509

    7. [7]

      [7] Liu G X, Xu Y Y, Wang Y, et al. Inorg. Chim. Acta, 2010, 363:3932-3938

    8. [8]

      [8] Wang X L, Guo Z C, Liu G C, et al. CrystEngComm, 2013, 15:551-559

    9. [9]

      [9] Ding C X, Li X, Ding Y B, et al. Cryst. Growth Des., 2012, 12:3465-3473

    10. [10]

      [10] Stylianou K C, Rabone J, Chong S Y, et al. J. Am. Chem. Soc., 2012,134:20466-20478

    11. [11]

      [11] Zhou X Y, Guo Y L, Shi Z H, et al. Dalton Trans., 2012, 41:1765-1775

    12. [12]

      [12] Platero-Prats A E, Bernini M C, Medina M E, et al. CrystEngComm, 2011,13:4965-4972

    13. [13]

      [13] Wang R H, Hong M C, Luo J H, et al. Chem. Commun., 2003:1018-1019

    14. [14]

      [14] LI Zheng (李正), ZHAO Yue (赵越), WANG Peng (王鹏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 28(7):1469-1476

    15. [15]

      [15] Zhao Y, Luo L, Liu C, et al. Inorg. Chem. Commun., 2011, 14:1145-1148

    16. [16]

      [16] Dang D B, Gao H, Bai Y, et al. J. Chem. Crystallogr., 2010, 40:332-336

    17. [17]

      [17] Dang D B, Li M M, Bai Y, et al. Spectrochim. Acta, Part A, Mol. Biomol. Spectrosc., 2013,103:101-107

    18. [18]

      [18] Dang D B, Li M M, Bai Y, et al. Synth. Met., 2012,162: 2075-2080

    19. [19]

      [19] Bai Y, Wang J L, Dang D B, et al. Spectrochim. Acta, Part A, Mol. Biomol. Spectrosc., 2012,97:105-110

    20. [20]

      [20] ZHANG Zhong (张众), LIU Ji-Zhong (刘积中), GAO Pe(高 鹏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):195-200

    21. [21]

      [21] Wolfle I, Lodaya J, Sauerwein B, et al. J. Am. Chem. Soc., 1992,114:9304-9309

    22. [22]

      [22] Sheldrick G M. Acta Crystallogr., 1990,A46:467-473

    23. [23]

      [23] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122

    24. [24]

      [24] Rueff J M, Pillet S, Claiser N, et al. Eur. J. Inorg. Chem., 2002:895-900

    25. [25]

      [25] Yin P X, Zhang J, Li Z J, et al. Inorg. Chim. Acta, 2007, 360:3525-3532

    26. [26]

      [26] Aizawa S, Funahashi S. Inorg. Chem., 2002,41:4555-4559

    27. [27]

      [27] Chen Z Y, Luo D B, Kang M P, et al. Inorg. Chem., 2011, 50:4674-4676

    28. [28]

      [28] Dong D P, Sun Z G, Tong F, et al. CrystEngComm, 2011,13: 3317-3320

    29. [29]

      [29] Yin P X, Zhang J, Li Z J, et al. Cryst. Growth Des., 2009,9: 4884-4896

    30. [30]

      [30] Wang R H, Yuan D Q, Jiang F L, et al. Cryst. Growth Des., 2006,6:1351-1360

    31. [31]

      [31] Wu H, Dong Z W, Liu H Y, et al. Dalton Trans., 2008:5331-5341

    32. [32]

      [32] Ashiry K O, Zhao Y H, Shao K Z, et al. Solid State Sci., 2007,9:1006-1011

    33. [33]

      [33] Xiong K C, Jiang F L, Yang M, et al. Dalton Trans., 2012, 41:540-545

    34. [34]

      [34] Farnum G A, Lucas J S, Wang C Y, et al. Inorg. Chim. Acta, 2011,368:84-95

    35. [35]

      [35] Gai Y L, Jiang F L, Xiong K C, et al. Cryst. Growth Des., 2012,12:2079-2088

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