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Citation: PAN Hui, BAI Yan, AN Bing, DANG Dong-Bin. Crystal Structure and Spectral Properties of a One-Dimensional Coordination Polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (H2dpa=2,2’-biphenyldicarboxylate, dpdo=4,4’-bipyridine-N,N’-dioxide)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1710-1716. doi: 10.3969/j.issn.1001-4861.2013.00.307 shu

Crystal Structure and Spectral Properties of a One-Dimensional Coordination Polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (H2dpa=2,2’-biphenyldicarboxylate, dpdo=4,4’-bipyridine-N,N’-dioxide)

  • 1.

    Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

  • Received Date: 29 March 2013
    Available Online: 12 June 2013

    Fund Project: 国家自然科学基金(No.21071044)资助项目。 (No.21071044)

  • A new Co(Ⅱ) coordination polymer {[Co(dpa)(H2O)4]·(dpdo)·(H2O)}n (1) (H2dpa=2,2'-biphenyldicarboxy-late, dpdo=4,4'-bipyridine-N,N'-dioxide) has been synthesized and characterized by IR spectroscopy, UV-Vis spectroscopy, elemental analysis, XRPD, TGA and X-ray single-crystal structure analysis. The Co(Ⅱ) atom has a distorted octahedral coordination environment with a set of oxygen donors from two dpa2- ligands and four coordinated water molecules. Each dpa2- ligand is bounded to two cobalt centers and each cobalt atom is coordinated by two dpa2- ligands thereby generating a 21 helical chain. The helical chains further interact with each other and form a 2D network through multiform O-H…O hydrogen bonds with the help of the solvent water. In the solid state the adjacent layers are separated by dpdo units to form a 3D framework. Upon the excitation at 275 nm, the polymer 1 shows one emission peak at 430 nm in the solid state. CCDC: 922034.
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