Citation: HOU Xiang-Yang, WANG Xiao, FU Feng, WANG Ji-Jiang, TANG Long. Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2245-2250. doi: 10.3969/j.issn.1001-4861.2013.00.300 shu

Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Received Date: 29 January 2013
Available Online: 30 April 2013
Fund Project: 陕西省教育厅科研计划项目(No.11JK0583) (No.11JK0583)陕西省科学技术研究发展计划(No.2013JM2015)资助项目 (No.2013JM2015)

One new metal-organic framework, namely, [Co(pqba)₂(biyb)](1) (2-phenyl-4-quinolinecarboxylic acid=Hpqba, 1,4-bis(imidazol-1-ylmethyl)benzene=biyb), has been synthesized under hydrothermal conditions. The compound 1 was characterized by elemental analysis, IRspectroscopy, and X-ray single-crystal diffraction. Complex 1 crystallizes in the Monoclinic system, C₂/c space group. In 1, the biyb act as bidentate ligands assembling with Co(Ⅱ) ions to a one-dimensional framework, which is further expanded to form a 2D supramolecular structure by π…π stacking interactions with biyb molecules between 1D chains. Thermogravimetric analyses for 1 is discussed. Furthermore, electrochemical property of the 1 shows that electron transfer of Co(Ⅱ) between Co(Ⅲ) in electrolysis is quasi-reversible process, and magnetic susceptibility measurements indicate that compound 1 has dominating antiferromagnetic couplings between metal ions. CCDC: 919474.
- cobalt complex; crystal structure; magnetic susceptibility; electrochemical property
1. [1]
  [1] Zhao T T, Jing X M, Wang J, et al. Cryst. Growth Des., 2012,12:5456-5461 [2] Yang W T, Guo M, Sun Z M, et al. Cryst. Growth Des., 2012, 12:5529-5534 [3] Zhao F H, Che Y X, Zheng J M. Inorg.Chem.Commun., 2012,16:5560 [4] Zhang Z M, Li Y G, Wang E B, et al. Angew. Chem. Int. Ed., 2009,48:1581-1584 [5] CHEN Man-Sheng(陈满生), ZENG Ju-Lan(曾巨澜), ZHANG Chun-Hua(张春华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1775-1778 [6] Wang X Y, Wang Z M, Gao S. Chem. Commun., 2008: 281294 [7] Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc., Rev., 2007, 36:770-818 [8] Ji W J, Zhai Q G, Hu M C, et al. Chem. Commun., 2011,47: 3834-3836; [9] Bu X H, Tong M L, Chang H C, et al. Inorg. Chem., 2005, 44:,9837-9846 [10]Bu X H, Tong M L, Chang H C, et al. Ange.Chem. Int. Ed. Engl., 2004,43:192-195 [11]Yuan G, Shao K Z, Wang X L, et al. Inorg. Chem. Commun., 2008,11,1246-1249 [12]Zha M Q, Li X, Bing Y. J. Coord. Chem., 2011,64:473- 482 [13]Wang J J, Chang Z, Zhang A S, et al. Inorg. Chim. Acta, 2010,363:13771385 [14]Qin Z Q, Jennings M C, Puddephatt R J, et al. Inorg. Chem., 2002,41:5174-5186. [15]Shen Y C, Li Z J, Cheng J K, et al. Inorg. Chem. Commun., 2007,10:888-890 [16]Sheldrick G M. SADABS, A Program for Empirical Absorption Correction of Area detector Data University of G?觟ttingen, Germany, 1997. [17]Sheldrick G M. SHELXS-97, Program for Crystal Structure Determination, University of G?觟ttingen, Germany, 1997. [18]Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of G?觟ttingen, Germany, 1997. [19]HAN Wei(韩伟), CHENG Mei-Lin(程美令), LIU Qi(刘琦), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:1997-2004. [20]LEI Jing-Bin(雷静彬), HUANG Fu-Ping(黄富平), YU Qing (于青), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:572-578 [21]Cheng X N, Zhang W X, Chen X M. J. Am. Chem. Soc., 2007,129:15738-15739 [22]Cui J H, Li Y Z, Guo Z J, et al. Cryst. Growth Des., 2012, 12:3610-3618
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沈阳化工大学材料科学与工程学院沈阳 110142