Citation: HE Rong, ZHU Xiao-Yan, SONG Hui-Hua, YU Hai-Tao. Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2085-2090. doi: 10.3969/j.issn.1001-4861.2013.00.298 shu

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand

1.
1 College of Chemistry and Material Sciences, Hebei Normal University, Shijiazhuang 050024, China;

Received Date: 19 July 2012
Available Online: 8 May 2013
Fund Project: 国家自然科学基金(No.20601007,21141002,20772022和20971035) (No.20601007,21141002,20772022和20971035)河北省教育厅自然科学基金(ZH2006002) (ZH2006002)河北省自然科学基金(B2012205040)河北师范大学博士基金(No.130374)资助项目。 (B2012205040)河北师范大学博士基金(No.130374)

Reaction of L-O-Phosphoserine (H₂OPSer) and 1,10-phenanthroline (phen) and Cu(CH₃COO)₂·H₂Oin water-ethanol at ambient temperature afforded the remarkably copper complex [Cu(OPSer)(phen)(H₂O)]·3H₂O(1). The structure has been determined by single-crystal X-ray diffraction analysis and further characterized by infrared spectra (IR), elemental analysis, thermal analysis and magnetic measurements. The chiral copper(Ⅱ) mononuclear complex self-assembled via intermolecular hydrogen bonding interactions into 3Dsupramolecular network and was further consolidated by the π-π stacking interactions. The magnetic susceptibilities (1.8～300 K) indicated that the monnuclear(Ⅱ) cores were ferromanetic coupling (g=2.07,zJ'=0.044). CCDC: 760116.
- chiral copper(Ⅱ) complex; L-O-Phosphoserine; 1,10-phenanthroline; crystal structure; magnetism
1. [1]
  [1] Ma L, Abney C, Lin W. Chem. Soc. Rev., 2009,38:1248- 1256 [2] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982- 986 [3] Zhang Y, Saha M K, Bernal I. CrystEngComm, 2003,5:34- 37 [4] Xiong R G, You X Z, Abrahams B F, et al. Angew. Chem. Int. Ed., 2001,40:4422-4425 [5] Huang Q, Yu J, Gao J, et al. Cryst. Growth Des., 2010,10: 5291-5296 [6] Valente C, Choi E, Belowich M E, et al. Chem. Commun., 2010,46:4911-4913 [7] Ryoo J J, Shin J W, Dho H S, et al. Inorg. Chem., 2010,49: 7232-7234 [8] Dybtsev D N, Yutkin M P, Peresypkina E V, et al. Inorg. Chem., 2007,46:6843-6845 [9] An H Y, Wang E B, Xiao D R, et al. Angew. Chem. Int. Ed., 2006,45:904-908 [10]Liu Q Y, Wang Y L, Zhang N, et al. Cryst.Growth Des., 2011,11:3717-3720 [11]Gao E Q, Yue Y F, Bai S Q, et al. J. Am. Chem. Soc., 2004,126:1419-1429 [12]Dong L, Chu W, Zhu Q, et al. Cryst. Growth Des., 2011,11: 93-99 [13]Su Z, Chen M S, Fan J, et al. CrystEngComm, 2010,12: 2040-2043 [14]He R, Song H H, Wei Z. Inorg. Chim. Acta, 2010,363(11): 2631-2636 [15]He R, Song H H, Wei Z, et al. J. Solid State Chem., 2010, 183(9):2021-2026 [16]HE Rong(何蓉), SONG Hui-Hua(宋会花), WEI Zhen(魏珍). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26: 1715-1718 [17]HE Rong(何蓉), SONG Hui-Hua(宋会花), WEI Zhen(魏珍). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,29: 898-904 [18]Wu L L, He R, Song H H, et al. Chem. Res. Chinese U., 2011,27(5):724-729 [19]ZHU Xiao-Yan(朱小燕), SONG Hui-Hua(宋会花), HE Rong (何蓉). Chinese J. Inorg. Chem, (Wuji Huaxue Xuebao), 2012,28(9):2011-2016 [20]Sheldrick G M. SHELXS-97, Program for X-Ray Crystal Structure Solution, and SHELXL-97, Program for X-ray Structure Refinement. University of G?觟ttingen, Germany. 1997. [21]Noro S I, Horike S, Nakamura T. Inorg. Chem., 2006,45(13): 9290-9300 [22]Subramanian P S, Suresh E, Casella L. Eur. J. Inorg. Chem., 2007:1654-1660 [23]Biswas C, Drew M G B, Estrader M, et al. Dalton Trans., 2009:5015-5022 [24]QU Zhi-Bin(区志镔), HUANG Shan-Hua(黄山华), LE Xue- Yi(乐学义). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:1580-1586 [25]Kruszynski R, Machura B, Wolff M, et al. Inorg. Chim. Acta, 2009,362:1369-1373 [26]Ginsberg A P, Lines M E. Inorg. Chem., 1972,11:2289-2290
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
11. [11]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
12. [12]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
13. [13]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
17. [17]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
18. [18]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
19. [19]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
20. [20]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(408)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H2O)] 3H2O Based on L-O-Phosphoserine Ligand

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand