Citation: HE Rong, ZHU Xiao-Yan, SONG Hui-Hua, YU Hai-Tao. Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2085-2090. doi: 10.3969/j.issn.1001-4861.2013.00.298 shu

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand

1.
1 College of Chemistry and Material Sciences, Hebei Normal University, Shijiazhuang 050024, China;

Received Date: 19 July 2012
Available Online: 8 May 2013
Fund Project: 国家自然科学基金(No.20601007,21141002,20772022和20971035) (No.20601007,21141002,20772022和20971035)河北省教育厅自然科学基金(ZH2006002) (ZH2006002)河北省自然科学基金(B2012205040)河北师范大学博士基金(No.130374)资助项目。 (B2012205040)河北师范大学博士基金(No.130374)

Reaction of L-O-Phosphoserine (H₂OPSer) and 1,10-phenanthroline (phen) and Cu(CH₃COO)₂·H₂Oin water-ethanol at ambient temperature afforded the remarkably copper complex [Cu(OPSer)(phen)(H₂O)]·3H₂O(1). The structure has been determined by single-crystal X-ray diffraction analysis and further characterized by infrared spectra (IR), elemental analysis, thermal analysis and magnetic measurements. The chiral copper(Ⅱ) mononuclear complex self-assembled via intermolecular hydrogen bonding interactions into 3Dsupramolecular network and was further consolidated by the π-π stacking interactions. The magnetic susceptibilities (1.8～300 K) indicated that the monnuclear(Ⅱ) cores were ferromanetic coupling (g=2.07,zJ'=0.044). CCDC: 760116.
- chiral copper(Ⅱ) complex; L-O-Phosphoserine; 1,10-phenanthroline; crystal structure; magnetism
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H2O)] 3H2O Based on L-O-Phosphoserine Ligand

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H₂O)] 3H₂O Based on L-O-Phosphoserine Ligand