Citation:
HE Rong, ZHU Xiao-Yan, SONG Hui-Hua, YU Hai-Tao. Synthesis, Structural Characterization, and Properties of Complex [Cu(OPSer)(phen)(H2O)] 3H2O Based on L-O-Phosphoserine Ligand[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(10): 2085-2090.
doi:
10.3969/j.issn.1001-4861.2013.00.298
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Reaction of L-O-Phosphoserine (H2OPSer) and 1,10-phenanthroline (phen) and Cu(CH3COO)2·H2Oin water-ethanol at ambient temperature afforded the remarkably copper complex [Cu(OPSer)(phen)(H2O)]·3H2O(1). The structure has been determined by single-crystal X-ray diffraction analysis and further characterized by infrared spectra (IR), elemental analysis, thermal analysis and magnetic measurements. The chiral copper(Ⅱ) mononuclear complex self-assembled via intermolecular hydrogen bonding interactions into 3Dsupramolecular network and was further consolidated by the π-π stacking interactions. The magnetic susceptibilities (1.8~300 K) indicated that the monnuclear(Ⅱ) cores were ferromanetic coupling (g=2.07,zJ'=0.044). CCDC: 760116.
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