Citation: HAO Peng-Fei, YANG Zhi, MA Xiao-Li, LI Jia-Rong. Synthesis, Characterization and Thermal Stability of the Aluminum Boroxine-Linked Compound with N-aryl Substituted β-Diketiminato Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1909-1913. doi: 10.3969/j.issn.1001-4861.2013.00.296 shu

Synthesis, Characterization and Thermal Stability of the Aluminum Boroxine-Linked Compound with N-aryl Substituted β-Diketiminato Ligand

1.
School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China

Received Date: 16 February 2013
Available Online: 15 May 2013
Fund Project: 国家自然科学基金(No.21001016) (No.21001016)北京市自然科学基金(No.2132044) (No.2132044)

The reaction of LAlH₂ (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAl[OB(2-CF₃C₆H₄)]2(μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic AlO₃B₂ ring fused to the organic C₃N₂ part. Compound was characterized by ¹H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis. CCDC: 918118.
- β-diketiminato ligand;six-membered ring, aluminum boroxine;thermal stability
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沈阳化工大学材料科学与工程学院沈阳 110142