Citation: LI Shu-Jing, ZHANG Xiao-Peng, LIU Jian, ZHENG Wei, LI Cheng-Hui. Synthesis and Characterization of Chiral 2,5-Bis(4,5-pinene-2-pyridyl) Pyrazine and Its Rhenium(Ⅰ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1745-1752. doi: 10.3969/j.issn.1001-4861.2013.00.295 shu

Synthesis and Characterization of Chiral 2,5-Bis(4,5-pinene-2-pyridyl) Pyrazine and Its Rhenium(Ⅰ) Complex

1.
1 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China;

Received Date: 31 January 2013
Available Online: 25 May 2013
Fund Project: 国家自然科学基金(No.21001063,91022031) (No.21001063,91022031)河南省科技厅科技攻关(No.122102210250)资助项目。 (No.122102210250)

The chiral ligand 2,5-bis(4,5-pinene-2-pyridyl) pyrazine (L) and its rhenium(Ⅰ) complex [Re(CO)₃Cl(L)]·DMF were synthesized. X-ray crystallographic analysis show that L crystallizes in monoclinic P2₁ space group while [Re(CO)₃Cl(L)]·DMF crystallizes in orthorhombic P2₁2₁2₁ space group. The Re(Ⅰ) atom is six-coordinated by two nitrogen atoms (N1, N2) from the chiral ligand, three carbon atoms (C1, C2 and C3) from CO, and one chlorine atom (Cl1). Both ligand and [Re(CO)₃Cl(L)]·DMF show optical activity as manifested by the CD and VCD spectra. Upon excitation, the ligand and Re(Ⅰ) complex emit at 420 and 650 nm, respectively. Both the ligand and Re(Ⅰ) complex show second-order non-linear optic (NLO) properties, and the second harmonic generation (SHG) responses are ~0.4 and ~0.3 times that of urea, respectively. CCDC: 921976, complex; 921977, ligand.
- pinene;rhenium(Ⅰ) complex;luminescence;chiral;circular dichlorism
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