Citation: LIU Liang-Liang, XIA Dan, LIU Wei-Sheng, TANG Yu. Facile Fabrication of Layered-Rare-Earth-Hydroxide/Polymethyl-Methacrylate Multi-color Luminescent Films[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1663-1667. doi: 10.3969/j.issn.1001-4861.2013.00.293 shu

Facile Fabrication of Layered-Rare-Earth-Hydroxide/Polymethyl-Methacrylate Multi-color Luminescent Films

1.
Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Received Date: 28 April 2013
Available Online: 5 June 2013
Fund Project: 国家自然科学基金(No.20931003,21071068) (No.20931003,21071068)国家自然科学基金委员会人才培养基金(No.J1103307)资助项目。 (No.J1103307)

Herein, the organic-inorganic hybrid phosphors has been designed and assembled by the intercalation of salicylic acid (HSA), as sensitizer, into the layered rare-earth hydroxides (LRHs) with the compositions of (Gd_0.5Tb_0.5-xEu_x)₂(OH)₅NO₃·nH₂O, through ion-exchange reaction under hydrothermal condition. More interestingly, the luminescence color of the SA^--LRHs:xEu can be easily tuned from green to red due to the energy transfer from the Tb³⁺ to Eu³⁺ ions by changing the doping concentration of activator ions. In addition, the transparent and color-tunable luminescent film devices can be fabricated facilely with the use of SA^--LRHs:xEu hybrids and polymethyl methacrylate (PMMA).
- layered rare earth hydroxide;organic sensitizer;intercalation and assembly;luminescent films
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沈阳化工大学材料科学与工程学院沈阳 110142