Citation: ZUO Luo, FENG Jian-Hua, GUO Li, LI Hui-Hui, WU Gang. Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1979-1984. doi: 10.3969/j.issn.1001-4861.2013.00.291 shu

Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex

ZUO Luo ¹ ,
FENG Jian-Hua ¹ ,
GUO Li ¹ ,
LI Hui-Hui ¹ ,
WU Gang ^1,2

1.
1 College of Material and Chemical Engineering, Chu Zhou University, Chuzhou, Anhui 239012, China;

Received Date: 23 July 2012
Available Online: 4 May 2013
Fund Project: 安徽省自然科学基金(No.1208085MB31) (No.1208085MB31)安徽省应用化学重点建设学科基金(No.200802187C) (No.200802187C)安徽省化学工程与工艺教学团队 (No.20101035) (No.20101035)滁州学院大学生科研项目(No.2012XS18,2012XS19)资助项目。 (No.2012XS18,2012XS19)

Solvothermal reaction of BaCl₂·2H₂O with 3,4-pyridinedicarboxylic acid afforded a new inorganic-organic hybrid framework,[Ba₂(pdc)₂(H₂O)₃]_n (1) (H₂pdc=3,4-pyridinedicarboxylic acid). This complex has been fully characterized by single crystal X-ray diffraction, elemental analysis, and IR spectrum. X-ray analysis shows that complex 1 features a two-dimensional network (2D). Ba1 takes eight-coordinated distorted square antiprism geometry. Ba₂ takes ten-coordinate distorted dicapped square prism coordination geometry. The whole pdc^2- anion connects four different Ba(Ⅱ) atoms, giving rise to a 2D network structure. The three-dimensional structure is formed by O-H…N hydrogen bonding interactions. Thermal stability and luminescent property of compound 1 have also been investigated. CCDC: 887479.
- Ba(Ⅱ) complex;carboxylate group;luminescent property;thermogravimetry
1. [1]
  [1] LI Jing(李静), JI Chang-Chun(季长春), WANG Zuo-Wei(王作为), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:2083-2089
2. [2]
  [2] ZHU Ying-Gui(朱英贵), JU Xue-Hai(居学海), SONG Ying-Lin(宋瑛林), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(12):2029-2034
3. [3]
  [3] Kong C Y. J. Inorg. Organomet. Polym., 2011,21:189-194
4. [4]
  [4] Niu C Y, Pan Z L, Dang Y L, et al. J. Inorg. Organomet. Polym., 2011,21:611-618
5. [5]
  [5] Baxter P N W, Khoury R G, Lehn J M, et al. Chem. Eur. J., 2000,6:4140-4148
6. [6]
  [6] Long D L, Blake A J, Champness N R, et al, Chem. Eur. J., 2002,8:2026-2033
7. [7]
  [7] Su C Y, Cai Y P, Chen C L, et al. J. Am. Chem. Soc., 2003, 125:8595-8613
8. [8]
  [8] Ciurtin D M, Pschirer N G, Smith M D, et al. Chem. Mater., 2001,13:2743-2745
9. [9]
  [9] Baxter P N W, Lehn J M, Baum G, et al. Chem. Eur. J., 2000,6:4510-4517
10. [10]
  [10] Pan L, Huang X Y, Li J, et al. Angew. Chem., Int. Ed., 2000,39:527-530
11. [11]
  [11] Abuhmaiera R, Lan Y, Ako A M, et al. CrystEngComm, 2009,11:1089-1096
12. [12]
  [12] Motreff A, da Costa R C, Allouchi H, et al. Inorg. Chem., 2009,48:5623-5625
13. [13]
  [13] Berggren G, Anderlund M F, Styring S, et al. Inorg. Chem., 2012,51:2332-2337
14. [14]
  [14] Bo Q B, Sun Z X, Song G L, et al. J. Inorg. Organomet. Polym., 2007,17:615-622
15. [15]
  [15] Wang F, Liu Z S, Yang H, et al. Angew. Chem., Int. Ed., 2011,50:450-453
16. [16]
  [16] Cao R, Lu J, Batten S R, CrystEngComm, 2008,10:784-789
17. [17]
  [17] Zhang X, Huang Y Y, Zhang M J, et al. Cryst. Growth Des., 2012,12:3231-3238
18. [18]
  [18] Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
19. [19]
  [19] Sheldrick G M. SHELXL 97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
20. [20]
  [20] Fromma K M, Goesmann H. Acta Cryst. C56, 2000:1179-1180
21. [21]
  [21] Yu J O, Cté A P, Enright G D, et al. Inorg. Chem., 2001,40: 582-583
22. [22]
  [22] Zhu H F, Zhang Z H, Sun W Y, et al. Cryst. Growth Des., 2005,5:177-182
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
5. [5]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
9. [9]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
12. [12]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
15. [15]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
16. [16]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
19. [19]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
20. [20]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(197)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142