Citation: WANG Dong-Ni, XU Duo-Hui, DING Liu-Liu, CHEN Qi, LU Chang-Sheng. Synthesis and Crystal Structure of a Dicuclear Cobalt Complex Consisting of 2, 2’-Bipyrimidyl and Dithiolene[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1724-1732. doi: 10.3969/j.issn.1001-4861.2013.00.289 shu

Synthesis and Crystal Structure of a Dicuclear Cobalt Complex Consisting of 2, 2’-Bipyrimidyl and Dithiolene

1.
1 Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;

Received Date: 23 January 2013
Available Online: 27 April 2013
Fund Project: 国家自然科学基金(No.21021062 和91122031)江苏省自然科学基金(No.BK2011550)资助项目。 (No.21021062 和91122031)江苏省自然科学基金(No.BK2011550)

A new dinuclear cobalt complex with mixed ligands, (C₄H₉)₄N₂(Co(mnt)₂)₂(bpy) (1) (C₅₆H₇₈Co₂N₁₄S₈)((C₄H₉)₄N=tetrabutylammonium, mnt=maleonitriledithiolate and bpy=2,2'-bipyrimidyl) has been synthesized and characterized by single-crystal X-ray structure determination. Complex 1 is of monoclinic system, space group P2₁/c, with a=2.368 2(2) nm, b=1.582 11(13) nm, c=1.873 85(16) nm, β=105.834(2)°. Each cobalt center was coordinated with two mnt groups and bridged by 2,2'-bipyrimidyl ligand in complex 1. It was then investigated by thermogravimetric analysis (TGA), UV, IR, X-ray photoelectron spectroscopy (XPS), and cyclic voltammograms (CVs). Magnetic susceptibilities measurements of complex 1 revealed weak antiferromagnetic exchange interactions between the adjacent Co(Ⅱ) ions. CCDC: 919857.
- mixed ligand;dinuclear cobalt complex;crystal structure
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