Citation: ZHOU Xian-Ju, ZHOU Kai-Ning, WANG Zhi-Liang, XIAO Teng-Jiao, ZHAO Xiao-Qi, LI Qing-Xu. Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1870-1876. doi: 10.3969/j.issn.1001-4861.2013.00.288 shu

Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates

1.
1 Department of Mathematics and Physics, Chongqing University of Posts and Telecommunications, Chongqing 400065, China;

Received Date: 25 September 2012
Available Online: 13 May 2013
Fund Project: 国家自然科学基金(No.20903123) (No.20903123)教育部重点项目(No.211154) (No.211154)重庆市自然科学基金(No.KJ110532,CSTC2011jjA1425) (No.KJ110532,CSTC2011jjA1425)

Europium complexes with cinnamic acid (HL) and its para-substitued derivates R-L (R=CH₃, Cl, NO₂, OCH₃, OH) have been synthesized, and their crystal structures have been determined. The results of single-crystal X-Ray diffraction have shown that {[Eu₂(CH₃-L)₆(DMF)(H₂O)]·2DMF·H₂O}_n (1) and {[Eu₂(Cl-L)6(DMF)(H₂O)]·2DMF·H₂O}_n (2) are 1D chain coordination polymers while {[Eu₂(NO₂-L)₆(DMF)(H₂O)]·2DMF·H₂O}₂ (3) is binuclear structured. The complexes have been characterized by FT-IR, UV-Vis and photoluminescence (PL) spectroscopy. The influence of substituted groups' electron-withdrawing effect has been discussed. The effect of coordinated solvent molecular on complexes' luminescent properties has been investigated. CCDC:856461, 1; 856460, 2; 856462, 3.
- Eu³⁺ complexes;cinnamic acid;crystal structure;luminescent properties
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沈阳化工大学材料科学与工程学院沈阳 110142