Citation: LI Jun-Hua, ZHANG Dan, LI Xue. Synthesis of Hollow Mesoporous Aluminosilicate Spheres and Its Catalytic Cracking Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2049-2056. doi: 10.3969/j.issn.1001-4861.2013.00.287 shu

Synthesis of Hollow Mesoporous Aluminosilicate Spheres and Its Catalytic Cracking Properties

1.
School of Chemistry and Environmental Engineering, Liaoning University of Technology, Jinzhou, Liaoning 121001, China

Received Date: 26 March 2013
Available Online: 7 May 2013
Fund Project: 辽宁省教育厅项目(No.L2012222) (No.L2012222)辽宁工业大学教师科研基金(No.X201115)资助项目 (No.X201115)

Hollow mesoporous aluminosilicate spheres (HMAS) with middle strong acidity have been successfully synthesized by a facile hydrothermal treatment on mesoporous silica spheres (MSS) in zeolite precursor solution. The as-prepared materials were characterized by TEM, SEM, XRD, N₂ adsorption-desorption, ²⁷Al NMR and NH₃-TPD. The results showed that the hollowing process was associated with a progressive mass redistribution and changes of pores structures. The surfactant cetyltrimethylammonium bromide (CTAB) located in the pores of MSS protected the mesoporous silica spheres from dissolving into strongly basic zeolite precursor solution and acted as the template for mesoporous shell. Under the templating function of CTAB, primary zeolite units were introduced into the mesopore walls of HMAS. The obtained material HMAS had moderate acid strength. Catalytic tests showed that the catalysts exhibited high catalytic activity compared with the MSS and Hβ zeolite for catalytic cracking of 1, 3, 5-triisopropylbenzene.
- hollow; mesoporous silica; zeolite precursors; catalytic cracking
1. [1]
  [1] Liu S, Rao H, Sui X, et al. J. Non-Cryst. Solids, 2008,354: 826-830 [2] Zou H, Wu S S, Ran Q P, et al. J. Phys. Chem. C, 2008, 112:11623-11629 [3] Yeh Y Q, Chen B C, Lin H P, et al. Langmuir, 2006,22:6-9 [4] Wan Y, Yu S H. J. Phys. Chem. C, 2008,112,3641-3647 [5] Fujita S, Nakano H, Ishii M, et al. Micropor. Mesopor. Mater., 2006,96:205-209 [6] Li Y S, Shi J L, Hua Z L, et al. Nano Lett., 2003,3:609-612 [7] Arruebo M, Galan M, Navascues N, et al. Chem. Mater., 2006,18:1911-1919 [8] Martin T, Galarneau A, Renzo F Di, et al. Chem. Mater., 2004,16:1725-1731 [9] Lin H P, Mou C Y, Liu S B, et al. Chem. Commun., 2001,19:1970-1971 [10]Zhang H J, Wu J, Zhou L P, et al. Langmuir, 2007,23:1107- 1113 [11]Fowler C E, Khushalani D, Mann S. Chem. Commun., 2001, 19:2028-2029 [12]Yu C Z, Tian B H, Fan J, et al. Chem. Lett., 2002,31:62-63 [13]Zhu Y F, Shi J L, Shen W H, et al. Nanotechnology, 2005,16:2633-2638 [14]Zhu Y F, Shi J L, Chen H R, et al. Micropor. Mesopor. Mater., 2005,84:218-222 [15]Han S H, Hou W G, Xu J, et al. Colloid Polym. Sci., 2004,282:1286-1291 [16]Yoon S B, Kim J Y, Kim J H, et al. Curr. Appl. Phys., 2006,6:1059-1063 [17]Zhu G S, Qiu S L, Terasaki O, et al. J. Am. Chem. Soc., 2001,123:7723-7724 [18]Le Y, Chen J F, Wang J X, et al. Mater. Lett., 2004,58: 2105-2108 [19]Zhao M W, Zheng L Q, Li N, et al. Mater. Lett., 2008,62 (30):4591-4593 [20]Liu S Q, Wei M Y, Rao J C, et al. Mater. Lett., 2011,65 (13):2083-2085 [21]Wu S H, Hung Y, Mou C Y. Chem. Mater., 2013,25(3):352- 364 [22]Yang W L, Li B S. J. Mater. Chem. B, 2013,1:2525-2532 [23]WU Hong-Yu(伍宏玉), LAI Cai-Lang(赖彩浪), LI Hai-Tao (李海涛), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(2):257-262 [24]Sun B, Guo C Y, Yao Y, et al. J. Mater. Sci., 2013,48,(5): 1890-1898 [25]XIE Lin-Yan(解林艳), LI Qun-Yan(李群艳), WANG Zhi- Hong(王志宏), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(10):1756-1760 [26]MA Xue-Hui(马雪慧), WANG Le-Shan(王乐善), ZHAO Yan-Bao(赵彦保). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(6):1091-1096 [27]Teng Z G, Su X D, Zheng Y Y, et al. Chem. Mater., 2013, 25(1):98-105 [28]Sadasivan S, Sukhorukov G B. J. Colloid Interf. Sci., 2006,304:437-441 [29]Wang J G, Li F, Zhou H J, et al. Chem. Mater., 2009,21: 612-620 [30]Xu W J, Xu Y, Wu D, et al. Stud. Surf. Sci. Catal., 2007, 170:861-865 [31]Han Y, Xiao F S, Wu S, et al. J. Phys. Chem. B, 2001,105: 7963-7966 [32]Camblor M A, Mifsud A, Perezpariente J. Zeolites, 1991,11: 792-797 [33]Mies M M, Rebrov E V, Jansen J C, et al. Micropor. Mesopor. Mater., 2007,106:95-106 [34]Sing K S W, Everett D H, Haul R A W, et al. Pure Appl. Chem., 1985,57:603-619 [35]Zhai S R, Zheng J L, Li J P, et al. Micropor. Mesopor. Mater., 2005,83:10-18 [36]Zheng Y H, Cheng Y, Wang Y S, et al. J. Phys. Chem. B, 2006,110:8284-8288 [37]Qiao R, Zhang X L, Qiu R, et al. Chem. Mater., 2007,19: 6485-6491 [38]Doyle A, Hodnett B K. Micropor. Mesopor. Mater., 2003,63: 53-57 [39]Park S J, Kim Y J, Park S J, Langmuir, 2008,24:12134- 12137 [40]Zhao D Y, Zhou Y M, Xia S J, et al. Catal. Today, 2001,68: 11-20 [41]Bergadà O, Boíx E, Salagre P, et al. Appl. Catal. A: Gen., 2009,368:163-169 [42]ZHAI Shang-Ru(翟尚如), ZHENG Jun-Lin(郑均林), WU Dong(吴东), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20(9):1093-1096 [43]LI Sha(李莎), ZHOU Hui(周慧), FAN Jie(范杰), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013,29(5): 896-902 [44]Zhu L, Xiao F S, Zhang Z T, et al. Catal. Today, 2001,68: 209-216
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