Citation: LI Jun-Hua, ZHANG Dan, LI Xue. Synthesis of Hollow Mesoporous Aluminosilicate Spheres and Its Catalytic Cracking Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2049-2056. doi: 10.3969/j.issn.1001-4861.2013.00.287 shu

Synthesis of Hollow Mesoporous Aluminosilicate Spheres and Its Catalytic Cracking Properties

1.
School of Chemistry and Environmental Engineering, Liaoning University of Technology, Jinzhou, Liaoning 121001, China

Received Date: 26 March 2013
Available Online: 7 May 2013
Fund Project: 辽宁省教育厅项目(No.L2012222) (No.L2012222)辽宁工业大学教师科研基金(No.X201115)资助项目 (No.X201115)

Hollow mesoporous aluminosilicate spheres (HMAS) with middle strong acidity have been successfully synthesized by a facile hydrothermal treatment on mesoporous silica spheres (MSS) in zeolite precursor solution. The as-prepared materials were characterized by TEM, SEM, XRD, N₂ adsorption-desorption, ²⁷Al NMR and NH₃-TPD. The results showed that the hollowing process was associated with a progressive mass redistribution and changes of pores structures. The surfactant cetyltrimethylammonium bromide (CTAB) located in the pores of MSS protected the mesoporous silica spheres from dissolving into strongly basic zeolite precursor solution and acted as the template for mesoporous shell. Under the templating function of CTAB, primary zeolite units were introduced into the mesopore walls of HMAS. The obtained material HMAS had moderate acid strength. Catalytic tests showed that the catalysts exhibited high catalytic activity compared with the MSS and Hβ zeolite for catalytic cracking of 1, 3, 5-triisopropylbenzene.
- hollow; mesoporous silica; zeolite precursors; catalytic cracking
1. [1]
  [1] Liu S, Rao H, Sui X, et al. J. Non-Cryst. Solids, 2008,354: 826-830 [2] Zou H, Wu S S, Ran Q P, et al. J. Phys. Chem. C, 2008, 112:11623-11629 [3] Yeh Y Q, Chen B C, Lin H P, et al. Langmuir, 2006,22:6-9 [4] Wan Y, Yu S H. J. Phys. Chem. C, 2008,112,3641-3647 [5] Fujita S, Nakano H, Ishii M, et al. Micropor. Mesopor. Mater., 2006,96:205-209 [6] Li Y S, Shi J L, Hua Z L, et al. Nano Lett., 2003,3:609-612 [7] Arruebo M, Galan M, Navascues N, et al. Chem. Mater., 2006,18:1911-1919 [8] Martin T, Galarneau A, Renzo F Di, et al. Chem. Mater., 2004,16:1725-1731 [9] Lin H P, Mou C Y, Liu S B, et al. Chem. Commun., 2001,19:1970-1971 [10]Zhang H J, Wu J, Zhou L P, et al. Langmuir, 2007,23:1107- 1113 [11]Fowler C E, Khushalani D, Mann S. Chem. Commun., 2001, 19:2028-2029 [12]Yu C Z, Tian B H, Fan J, et al. Chem. Lett., 2002,31:62-63 [13]Zhu Y F, Shi J L, Shen W H, et al. Nanotechnology, 2005,16:2633-2638 [14]Zhu Y F, Shi J L, Chen H R, et al. Micropor. Mesopor. Mater., 2005,84:218-222 [15]Han S H, Hou W G, Xu J, et al. Colloid Polym. Sci., 2004,282:1286-1291 [16]Yoon S B, Kim J Y, Kim J H, et al. Curr. Appl. Phys., 2006,6:1059-1063 [17]Zhu G S, Qiu S L, Terasaki O, et al. J. Am. Chem. Soc., 2001,123:7723-7724 [18]Le Y, Chen J F, Wang J X, et al. Mater. Lett., 2004,58: 2105-2108 [19]Zhao M W, Zheng L Q, Li N, et al. Mater. Lett., 2008,62 (30):4591-4593 [20]Liu S Q, Wei M Y, Rao J C, et al. Mater. Lett., 2011,65 (13):2083-2085 [21]Wu S H, Hung Y, Mou C Y. Chem. Mater., 2013,25(3):352- 364 [22]Yang W L, Li B S. J. Mater. Chem. B, 2013,1:2525-2532 [23]WU Hong-Yu(伍宏玉), LAI Cai-Lang(赖彩浪), LI Hai-Tao (李海涛), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(2):257-262 [24]Sun B, Guo C Y, Yao Y, et al. J. Mater. Sci., 2013,48,(5): 1890-1898 [25]XIE Lin-Yan(解林艳), LI Qun-Yan(李群艳), WANG Zhi- Hong(王志宏), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(10):1756-1760 [26]MA Xue-Hui(马雪慧), WANG Le-Shan(王乐善), ZHAO Yan-Bao(赵彦保). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(6):1091-1096 [27]Teng Z G, Su X D, Zheng Y Y, et al. Chem. Mater., 2013, 25(1):98-105 [28]Sadasivan S, Sukhorukov G B. J. Colloid Interf. Sci., 2006,304:437-441 [29]Wang J G, Li F, Zhou H J, et al. Chem. Mater., 2009,21: 612-620 [30]Xu W J, Xu Y, Wu D, et al. Stud. Surf. Sci. Catal., 2007, 170:861-865 [31]Han Y, Xiao F S, Wu S, et al. J. Phys. Chem. B, 2001,105: 7963-7966 [32]Camblor M A, Mifsud A, Perezpariente J. Zeolites, 1991,11: 792-797 [33]Mies M M, Rebrov E V, Jansen J C, et al. Micropor. Mesopor. Mater., 2007,106:95-106 [34]Sing K S W, Everett D H, Haul R A W, et al. Pure Appl. Chem., 1985,57:603-619 [35]Zhai S R, Zheng J L, Li J P, et al. Micropor. Mesopor. Mater., 2005,83:10-18 [36]Zheng Y H, Cheng Y, Wang Y S, et al. J. Phys. Chem. B, 2006,110:8284-8288 [37]Qiao R, Zhang X L, Qiu R, et al. Chem. Mater., 2007,19: 6485-6491 [38]Doyle A, Hodnett B K. Micropor. Mesopor. Mater., 2003,63: 53-57 [39]Park S J, Kim Y J, Park S J, Langmuir, 2008,24:12134- 12137 [40]Zhao D Y, Zhou Y M, Xia S J, et al. Catal. Today, 2001,68: 11-20 [41]Bergadà O, Boíx E, Salagre P, et al. Appl. Catal. A: Gen., 2009,368:163-169 [42]ZHAI Shang-Ru(翟尚如), ZHENG Jun-Lin(郑均林), WU Dong(吴东), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20(9):1093-1096 [43]LI Sha(李莎), ZHOU Hui(周慧), FAN Jie(范杰), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2013,29(5): 896-902 [44]Zhu L, Xiao F S, Zhang Z T, et al. Catal. Today, 2001,68: 209-216
1. [1]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
2. [2]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
5. [5]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
8. [8]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
9. [9]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
10. [10]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
11. [11]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
12. [12]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
13. [13]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
14. [14]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
15. [15]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
16. [16]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
17. [17]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
18. [18]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
19. [19]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
20. [20]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(248)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142