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Citation: FENG Hao, DU Jing, HAN Xiao-Peng, CHENG Fang-Yi, CHEN Jun. Sol-Gel Synthesis of Perovskite La1-xCaxMnO3(x=0~0.4) Nanoparticles for Electrocatalytic Oxygen Reduction[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1617-1625. doi: 10.3969/j.issn.1001-4861.2013.00.286 shu

Sol-Gel Synthesis of Perovskite La1-xCaxMnO3(x=0~0.4) Nanoparticles for Electrocatalytic Oxygen Reduction

  • 1.

    Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

  • Received Date: 3 April 2013
    Available Online: 10 May 2013

    Fund Project: 国家自然科学基金(No.21231005) (No.21231005)863课题(2011AA050704) (2011AA050704)973项目(2011CB935900) (2011CB935900)

  • In this work, a series of La1-xCaxMnO3 perovskite nanoparticles were prepared through a sol-gel method and investigated as catalysts for the oxygen reduction reaction (ORR). The XRD, SEM and TEM characterization demonstrated high crystallinity of the synthesized particles having diameters of about 40 nm. The crystal structure was determined by Rietveld refinement, indicating variation of the lattice parameters with the amount of substituted Ca. The electrocatalytic properties of the samples were studied using rotating-disk and rotating ring-disk electrode techniques in KOH aqueous solution. Investigations on the composition-performance relationship of La1-xCaxMnO3 perovskites revealed that mixed Mn valence and medium Mn-O bond length favored the ORR electrocatalysis. Among the La1-xCaxMnO3 series, La0.7Ca0.3MnO3 exhibited outstanding ORR activity, enabled an apparent 4-electron pathway and showed superior durability compared to the benchmark carbon-supported Pt nanoparticles. Furthermore, metal-air cells assembled with La0.7Ca0.3MnO3 could deliver high charge and discharge capacity with flat plateaus. The considerable catalytic performances of La1-xCaxMnO3 nanoparticles indicate their promising application as low-cost and high-abundance catalysts in alkaline fuel cells and metal-air batteries.
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    1. [1]

      [1] Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012,11:19-29

    2. [2]

      [2] Suntivich J, Gasteiger H A, Yabuuchi N, et al. Nat. Chem., 2011,3:546-550

    3. [3]

      [3] Cheng F Y, Chen J. Chem. Soc. Rev., 2012,41:2172-2192

    4. [4]

      [4] Zhao Y L, Xu L, Mai L Q, et al. Proc. Natl. Acad. Sci. U.S. A, 2012,109:19569-19574

    5. [5]

      [5] Neburchilov V, Wang H J, Martin J J, et al. J. Power Sources, 2010,195:1271-1291

    6. [6]

      [6] CHENG Fang-Yi(程方益), CHEN Jun(陈军). Acta Chim. Sin. (Huaxue Xuebao), 2013,71:473-477

    7. [7]

      [7] HAN Hong-Tao(韩红涛), TANG You-Gen(唐有根). Chin. J. Power Sources (Dianyuan Jishu), 2006,30:454-457

    8. [8]

      [8] Sunarso J, Torriero A A, Zhou W, et al. J. Phys. Chem. C, 2012,116:5827-5834

    9. [9]

      [9] ZHANG Zhong-Lin(张忠林), YUAN Juan-Ning(员娟宁), SUN Yan-Ping(孙彦平), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,27(12):2413-2418

    10. [10]

      [10] Liang Y Y, Wang H L, Zhou J G, e al. J. Am. Chem. Soc., 2012,134:3517-3523

    11. [11]

      [11] Benbow E M, Kelly S P, Zhao L, et al. J. Phys. Chem. C, 2011,115:22009-22017

    12. [12]

      [12] Cheng F Y, Shen J, Peng B, et al. Nat. Chem., 2011,3:79-84

    13. [13]

      [13] Oh S H, Nazar L F. Adv. Energy Mater., 2012,2:903-910

    14. [14]

      [14] Winther-Jensen B, Winther-Jensen O, Forsyth M, et al. Science, 2008,321(5889):671-674

    15. [15]

      [15] Suntivich J, Gasteiger H A, Yabuuchi N, et al. J. Electrochem. Soc., 2010,157:B1263-B1268

    16. [16]

      [16] Débart A, Paterson A J, Bao J, et al. Angew. Chem. Int. Ed., 2008,47:4521-4524

    17. [17]

      [17] Cheng F Y, Chen J. Nat. Chem., 2012,4:962-963

    18. [18]

      [18] LI Dan-Lin(李丹林), LI Shang(李赏), PAN Mu(潘牧). J. Hubei Univ. (Hubei Daxue Xuebao), 2011,33:98-102

    19. [19]

      [19] LIN Sheng-Ling(林生岭), XU Shao-Fen(徐绍芬), CHENG Ye(成烨), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(11):1637-1642

    20. [20]

      [20] HU He-He(胡合合), LUO Yong-Chun(罗永春), KANG Long (康龙), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(10):2130-2138

    21. [21]

      [21] Hyodo T, Hayashi M, Miura N, et al. J. Electrochem. Soc., 1996,143:L266-L267

    22. [22]

      [22] Niu Y J, Zhou W, Sunarso J, et al. J. Mater. Chem., 2010, 20:9619-9622

    23. [23]

      [23] MIAO Jian-Wen(缪建文), FAN Yi-Ning(范以宁), JIN Yong-Shu(金永漱), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(12):1361-1365

    24. [24]

      [24] Han X P, Zhang T R, Du J, et al. Chem. Sci., 2013,4:368-376

    25. [25]

      [25] Du J, Pan Y D, Zhang T R, et al. J. Mater. Chem., 2012,22: 15812-15818

    26. [26]

      [26] Zhu J, Su Y, Cheng F Y, et al. J. Power Sources, 2007,166: 331-336 [27] Toby B H. J. Appl. Cryst., 2001,34:210-213

    27. [27]

      [28] Bard A J, Faulkner L R. Electrochemical Methods: Fundamentals and Applications. New York: Wiley, 2000

    28. [28]

      [29] El-Deab M S, Ohsaka T. Angew Chem Int Ed, 2006,45: 5963-5966

    29. [29]

      [30] Li X X, Qu W, Zhang, J J, et al. J. Electrochem. Soc., 2011, 158:A597-A604

    30. [30]

      [31] Cheng F Y, Shen J, Ji W Q, et al. ACS Appl. Mater. Interfaces, 2009,1:460-466

    31. [31]

      [32] ZHANG Huan(章欢), DAI Yu(戴煜), HU Xiao-Hong(胡晓宏), et al. Sci. Sin. Chim. (Zhongguo Kexue: Huaxue), 2011,41 (12):1784-1790

    32. [32]

      [33] Xu J J, Xu D, Wang Z L, et al. Angew. Chem. Int. Ed., 2013,52:3887-3890

    33. [33]

      [34] DiCastro V, Polzonetti G, Contini G, et al. Surf. Interface. Anal., 1990,16:571-574

    34. [34]

      [35] Oku M, Hirokawa K. J. Electron. Spectrosc. Relat. Phenom., 1976,8:475-481

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