Citation: JIA Hong-Liang, HOU Li-Fen, ZHANG Yu, YUAN Peng-Fei, LI Gang. Synthesis, Structure and Properties of a 2-(p-Bromophenyl)-Imidazole Dicarboxylate-Based Ni(Ⅱ) Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1897-1902. doi: 10.3969/j.issn.1001-4861.2013.00.285 shu

Synthesis, Structure and Properties of a 2-(p-Bromophenyl)-Imidazole Dicarboxylate-Based Ni(Ⅱ) Coordination Polymer

1.
1 College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China;

Received Date: 17 December 2012
Available Online: 30 April 2013
Fund Project: 国家自然科学基金(No.21071127) (No.21071127)教育部新世纪优秀人才项目(No.NCET-10-0139)资助项目。 (No.NCET-10-0139)

By the reaction of 2-(p-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid (p-BrPhH₃IDC) with Ni(Ⅱ) ion, one coordination polymer, namely,[Ni(p-BrPhH₂IDC)₂]·2H₂O}_n (1) has been synthesized under solvothermal condition. Its molecular structure has been characterized by single-crystal X-ray diffraction, elemental analysis and IR spectrum. The results reveal that it is a two-dimensional polymer, and the ligand p-BrPhH₃IDC shows strong coordination ability. Furthermore, the existence of intermolecular hydrogen bonds and π…π stacking interactions between the aromatic groups supplies the additional stabilization for the solid-state supramolecular structure of polymer 1. The thermal properties of 1 and its magnetic behaviors have been studied in the temperature range of 2.0~300 K. Magnetic measurement shows that the antiferromagnetic coupling between the Ni(Ⅱ) ions in complex 1 can be observed. CCDC: 913845.
- coordination polymer;imidazole dicarboxylate;synthesis;crystal structure;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142