Citation: HUANG De-Qian, ZHANG Hong, SHENG Liang-Quan, LIU Zhao-Di, XU Hua-Jie, FAN Su-Hua. A Neodymium(Ⅲ) Coordination Polymer Based on Oxalate and Carbonate Ligands： Synthesis, Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2497-2502. doi: 10.3969/j.issn.1001-4861.2013.00.283 shu

A Neodymium(Ⅲ) Coordination Polymer Based on Oxalate and Carbonate Ligands： Synthesis, Structure and Luminescence

1.
School of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236037, China

Received Date: 7 January 2013
Available Online: 25 April 2013
Fund Project: 国家自然科学基金(No.21201037) (No.21201037)安徽高校省级自然科学研究项目(No.KJ2012Z310,KJ2011A210)资助项目 (No.KJ2012Z310,KJ2011A210)

Aneodymium(Ⅲ) coordination polymer, namely, {[Nd2(ox)(cb)₂(H₂O)₂]·3H₂O}_n (1) (ox=oxalate, cb=carbonate) (1), has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, and single-crystal X-ray diffraction. Structural determination reveals that the neodymium ions are bridged by μ₂-ox and μ₄-cb ligands to give a 3D framework including 2D channels of 0.53 nm×0.41 nm along the b axis and 0.59 nm×0.84 nm along the c axis, respectively. It can also be described as a (4,5)-connected {4⁴.6²}{4⁴.6⁶} topological 3D framework. Solid-state 1 emits the intensely NIR characteristic luminescence of Nd³⁺ ion at room temperature. CCDC: 917863.
- neodymium(Ⅲ) coordination polymer;crystal structure;oxalate;carbonate;luminescent
1. [1]
  [1] Ma D, Wang W, Li Y, et al. CrystEngComm, 2010,12:4372-4377
2. [2]
  [2] Campos R A, Kovalev I P, Guo Y, et al. J. Appl. Phys., 1996, 80:7144-7150
3. [3]
  [3] Tsukube H, Shinoda S. Chem. Rev., 2002,102:2389-2404
4. [4]
  [4] Bünzli J C G. Chem. Rev., 2010,110:2729-2755
5. [5]
  [5] Smith P H, Brainard J R, Morris D E, et al. J. Am. Chem. Soc., 1989,111:7437-7443
6. [6]
  [6] Romèro S, Mosset A, Trombe J C. Eur. J. Solid State Inorg. Chem., 1997,34:209-219
7. [7]
  [7] Bruker. APEXII Software, Version 6.3.1. Bruker AXS Inc, Madison, Wisconsin, USA, 2004.
8. [8]
  [8] Sheldrick G M. Acta Cryst., 2008,A64:112-122
9. [9]
  [9] Lees A M J, Platt A W G. Inorg. Chem., 2003,42:4673-4679
10. [10]
  [10]Evans W J, Giarikos D G, Ziller J W. Organometallics., 2001,20:5751-5758
11. [11]
  [11]Spek A L. Platon: A Multipurpose Crystallographic Tool, Utrecht University, The Netherlands, 2005.
12. [12]
  [12]Veith M, Belot C, Huch V, et al. Eur. J. Inorg. Chem., 2010,636:2262-2275
13. [13]
  [13]Bünzli J C G. J. Alloys Compd., 2006,408:934-944
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沈阳化工大学材料科学与工程学院沈阳 110142