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Citation: GUO Li-Fang, WANG Zhao-Xi, LI Ming-Xing. A Two-Dimensional Manganese(Ⅲ) Coordination Polymer Constructed from[Mn3O] Units：Synthesis, Crystal Structure and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1921-1927. doi: 10.3969/j.issn.1001-4861.2013.00.274 shu

A Two-Dimensional Manganese(Ⅲ) Coordination Polymer Constructed from[Mn3O] Units：Synthesis, Crystal Structure and Magnetic Properties

  • 1.

    1 Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China;

  • Received Date: 1 February 2013
    Available Online: 1 May 2013

    Fund Project: 国家自然科学基金(No.20901049, 21171115) (No.20901049, 21171115)浙江省有机化学与皮革化工重中之重学科开放基金(No.100061200130)资助项目。 (No.100061200130)

  • A 2D coordination polymer, namely {[NaMn3ⅢO(sao)3(tfbdc)(H2O)4]·0.5H2O·2CH3CH2OH}n(1) (H2tfbdc=2, 3, 5, 6-tetrafluoroterephthalic acid, H2sao=salicylaldoxime), was synthesized and structurally characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. This complex crystallizes in triclinic space group P1, and exhibits a two-dimensional polymeric structure constructing from[Mn3O] units bridged by sodium cations and tetrafluoroterephthalate. Variable-temperature magnetic susceptibility analysis indicates that antiferromagnetic interaction exists between the manganese(Ⅲ)ions in the[Mn3O] unit. CCDC: 934761.
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    1. [1]

      [1] Cheetham A K, Férey G, Loiseau T. Angew. Chem. Int. Ed., 1999,38:3268-3292

    2. [2]

      [2] Rao C N R, Natarajan S, Vaidhyanathan R. Angew. Chem. Int. Ed., 2004,43:1466-1496

    3. [3]

      [3] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004,43:2334-2375

    4. [4]

      [4] Pan L, Olson D H, Ciemnolonski L R, et al. Angew. Chem. Int. Ed., 2006,45:616-619

    5. [5]

      [5] Mueller U, Schubert M, Teich F, et al. J. Mater. Chem., 2006,16:626-636

    6. [6]

      [6] Rosseinsky M J. Microporous Mesoporous Mater., 2004,73: 15-30

    7. [7]

      [7] Maspoch D, Ruiz-Molina D, Veciana J. J. Mater. Chem., 2004,14:2713-2723

    8. [8]

      [8] Collins D J, Zhou H C. J. Mater. Chem., 2007,17:3154-3160

    9. [9]

      [9] Morris R E, Wheatley P S. Angew. Chem. Int. Ed., 2008,47: 4966-4981

    10. [10]

      [10] Ma S, Zhou H C. Chem. Commun., 2010,46:44-53

    11. [11]

      [11] Braun M E, Steffek C D, Kim J, et al. Chem. Commun., 2001:2532-2533

    12. [12]

      [12] Chen S C, Zhang Z H, Huang K L, et al. Cryst. Growth Des., 2008,8:3437-3445

    13. [13]

      [13] Li C P, Tian Y L, Guo Y M. Inorg. Chem. Commun., 2008,11:1405-1408

    14. [14]

      [14] Vela J, Smith J M, Yu Y, et al. J. Am. Chem. Soc., 2005, 127:7857-7870

    15. [15]

      [15] Ohashi M, Kambara T, Hatanaka T, et al. J. Am. Chem. Soc., 2011,133:3256-3259

    16. [16]

      [16] Chan P W Y, Yakunin A F, Edwards E A, et al. J. Am. Chem. Soc., 2011,133:7461-7468

    17. [17]

      [17] Ge C, Zhang X, Yin J, et al. Chin. J. Chem., 2010,28:2083-2088

    18. [18]

      [18] Jana A, Roesky H W, Schulzke C, et al. Organometallics, 2010,29:4837-4841

    19. [19]

      [19] Beltrán T F, Feliz M, Llusar R, et al. Organometallics, 2011,30:290-297

    20. [20]

      [20] Lemal D M. J. Org. Chem., 2004,69:1-11

    21. [21]

      [21] Sandford G. Tetrahedron, 2003,59:437-454

    22. [22]

      [22] Zhang L, Wang Q, Liu Y C. J. Phys. Chem. B, 2007,111: 4291-4295

    23. [23]

      [23] Hübner O, Glöss A, Fichtner M, et al. J. Phys. Chem. A, 2004,108:3019-3023

    24. [24]

      [24] Yang C, Wang X, Omary M A. J. Am. Chem. Soc., 2007, 129:15454-15455

    25. [25]

      [25] Cotton F A, Lin C, Murillo C A. J. Chem. Soc., Dalton Trans., 1998:3151-3154

    26. [26]

      [26] Chisholm M H, Wilson P J, Woodward P M. Chem. Commun., 2002:566-567

    27. [27]

      [27] Rau S, Böttcher L, Schebesta S, et al. Eur. J. Inorg. Chem., 2002:2800-2809

    28. [28]

      [28] Kitaura R, Iwahori F, Matsuda R, et al. Inorg. Chem., 2004,43:6522-6524

    29. [29]

      [29] Ito M, Onaka S. Inorg. Chim. Acta, 2004,357:1039-1046

    30. [30]

      [30] Chun H, Dybtsev D N, Kim H, et al. Chem. Eur. J., 2005,11:3521-3529

    31. [31]

      [31] Chen B, Yang Y, Zapata F, et al. Inorg. Chem., 2006,45: 8882-8886

    32. [32]

      [32] Yoon J H, Choi S B, Oh Y J, et al. Catal. Today, 2007,120: 324-329

    33. [33]

      [33] ZHU En-Jing(朱恩静), LIU Qi(刘琦), CHEN Qun(陈群), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2008, 24(9):1428-1433

    34. [34]

      [34] YU Li-Li(于丽丽), LIU Qi(刘琦), XI Hai-Tao(席海涛), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(4): 621-626

    35. [35]

      [35] Hulvey Z, Falcao E H L, Eckert J, et al. J. Mater. Chem., 2009,19:4307-4309

    36. [36]

      [36] Hulvey Z, Ayala E, Furman J D, et al. Cryst. Growth Des., 2009,9:4759-4765

    37. [37]

      [37] Hulvey Z, Ayala E, Cheetham A K. Z. Anorg. Allg. Chem., 2009,635:1753-1757

    38. [38]

      [38] Bruker 2000, SMART (Version 5.0), SAINT-plus (Version 6), SHELXTL (Version 6.1)

    39. [39]

      [39] Miyasaka H, Takayama K, Saitoh A, et al. Chem. Eur. J., 2010,16:3656-3662

    40. [40]

      [40] Geng J P, Wang Z X, He X, et al. Inorg. Chem. Commun., 2011,14:997-1000

    41. [41]

      [41] Biswas B, Khanra S, Weyhermüller T, et al. Chem. Commun., 2007:1059-1061

    42. [42]

      [42] Hulvey Z, Furman J D, Turner S A, et al. Cryst. Growth Des., 2010,10:2041-2043

    43. [43]

      [43] Wang Z, Kravtsov V C, Walsh R B, et al. Cryst. Growth Des., 2007,7:1154-1162

    44. [44]

      [44] Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33:227-250

    45. [45]

      [45] Wu Y, Yu L, Cheng M, et al. Chin. J. Chem. 2012,30:1045-1051

    46. [46]

      [46] Wang X Y, Sevov S C. Chem. Mater., 2007,19:3763-3766

    47. [47]

      [47] Coronado E, Galán-Mascarós J R, Marti-Gastaldo C, et al. Inorg. Chem., 2008,47:6829-6839

    48. [48]

      [48] Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007,129:12505-12511

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