Citation: WANG Zhi-Hua, WANG Xin-Peng, ZHAO Sheng-Neng, WANG Qin, MENG Xiang-Gao, JIN Su-Rong. Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2’-Bipyridine-3,3’-dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1877-1881. doi: 10.3969/j.issn.1001-4861.2013.00.271 shu

Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2’-Bipyridine-3,3’-dicarboxylic Acid Ligands

1.
1 School of Science, Wuhan University of Technology, Wuhan 430070, China;

Received Date: 21 July 2012
Available Online: 4 May 2013
Fund Project: 中央高校基本科研业务费专项资金(批准号:2012-Ia-042)资助项目。 (批准号:2012-Ia-042)

A complex {[Cu₄(PMo₁₂O₄₀)(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]·6H₂O}_n was synthesized under hydrothermal condition using H₃PMo₁₂O₄₀·xH₂O,H₂bpdc, CuSO₄·5H₂O as raw materials and characterized by elemental analysis, IR,TG and single-crystal X-ray diffraction. The title compound consists of polyoxoanion[PMo₁₂O₄₀]^3-, cations[Cu₄(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]³⁺ and lattice water molecules. The structure refinement indicates that the title compound forms a one-dimensional chain from the polyanions and[Cu₄(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]³⁺ through O bridge. The cyclic voltammogram indicates that three couples redox waves are observed on the compound modified carbon paste electrode. CCDC: 748899.
- polyoxometalate;copper coordination polymer;hydrothermal synthesis;crystal structure
1. [1]
  [1] Hill C L. Chem. Rev., 1998,98:1-2
2. [2]
  [2] Pope M T, Muller A. Angew. Chem., Int. Ed., 1991,30:34-48
3. [3]
  [3] Ren Y P, Kong X J, Hu X Y, et al. Inorg. Chem., 2006,45: 4016-4023
4. [4]
  [4] Zheng S T, Zhang J, Yang G Y. Angew. Chem., Int. Ed., 2008,47:3909-3913
5. [5]
  [5] Fu H, Wang X L, Chen W L, et al. Chem. J. Chin. Univ., 2011,32:650-654
6. [6]
  [6] Hao X L, Luo M F, Wang X, et al. Inorg. Chem. Commun., 2011,14:1698-1702
7. [7]
  [7] Brigitte Nohra, Hani El Moll, L. Marleny Rodriguez Albelo, et al. J. Am. Chem. Soc., 2011,133:13363-13374
8. [8]
  [8] Wang D D, Peng J, Zhang P P, et al. Inorg. Chem. Commun., 2011,14:1911-1914
9. [9]
  [9] JIN Su-Rong(靳素荣), ZHANG Lian-Meng(张联盟), LIU Shi-Zhong(柳士忠), et al. Acta Chim. Sinica (Huaxue Xuebao), 2008,17:2011-2016
10. [10]
  [10] ZHAO Sheng-Neng(赵胜能), SHAO Xue-Yi(邵学义), WANG Zhi-Hua(王志花), et al. Acta Chim. Sinica (Huaxue Xuebao), 2010,21:2206-2210
11. [11]
  [11] Keum Kwak, Kil Sik Min, Bong Gon Kim. Inorg. Chim. Acta, 2007,360:1678-1683
12. [12]
  [12] Chen X L, Yao Y J, Hu H M, et al. Inorg. Chim. Acta, 2009,362:2686-2697
13. [13]
  [13] Hu M, Wang Q L, Xu G F, et al. Inorg. Chim. Acta, 2007, 360:1684-1690
14. [14]
  [14] Dholakia S, Gillard R D, Wimmer F L. Polyhedron, 1985,4: 791-795
15. [15]
  [15] Tian A X, Peng J, Sha J Q, et al. Inorg. Chem., 2008,47: 3274-3283
16. [16]
  [16] Zhang W, Liu S X, Feng D, et al. J. Mol. Struct., 2009,936: 194-198
17. [17]
  [17] Sha J Q, Peng J, Liu H S, et al. J. Mol. Struct., 2007,871:85-91
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沈阳化工大学材料科学与工程学院沈阳 110142