Citation: WANG Peng, XUE Zhao-Teng, MA Jing-Hong, KANG Yu-Hong, LI Rui-Feng. Zeolite LTA with Intracrystal Mesopores Constructed by Bond-Blocking Principle[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1777-1786. doi: 10.3969/j.issn.1001-4861.2013.00.269 shu

Zeolite LTA with Intracrystal Mesopores Constructed by Bond-Blocking Principle

1.
Key Laboratory of Coal Science and Technology, Ministry of Education, School of Chemistry and Chemical Engineering, Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Received Date: 22 March 2013
Available Online: 21 April 2013
Fund Project: 国家自然科学基金(No.50872087)资助项目。 (No.50872087)

Zeolite LTA with intracrystal mesopores was built using four different organic functionized SiO₂ as configuration units. The effects of the synthesis conditions, including that of the alkalinity, the Si/Al molar ratio of synthesis mixture and crystallization time, on the growth process of the mesostructured zeolite crystals were investigated. Phenylaminopropyl-trimethoxysilane is the best candidate to create intracrystal mesopores in zeolite LTA crystals. The growth process of the mesostructured zeolite crystals was studied. Mesoporous size of the zeolite LTA can be modulated by selecting different kinds of organosilanes. Within a certain range, the external surface area and the mesoporous volume increase with the increasing organic function degree of the silica source. The results confirm that the synthesis method by the bond-blocking principle is an effective route to prepare zeolite LTA with tunable intracrystalline mesopores.
- catalysis;bond-blocking principle;zeolite LTA;intracrystalline mesopores;organosilane;functionized SiO₂
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沈阳化工大学材料科学与工程学院沈阳 110142