Citation: JIA Xiao-Yan, CHENG Mei-Ling, LIU Qi, HONG Jian, CHEN Lin-Ti, BAO Jin-Ting, LI Zhan-Feng, JI Yun-Zhou. Synthesis, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Complexes Based on Tetrafluoroterephthalate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1999-2006. doi: 10.3969/j.issn.1001-4861.2013.00.268 shu

Synthesis, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Complexes Based on Tetrafluoroterephthalate Ligand

1.
1 School of Petrochemical Engineering and Jiangsu Province Key Laboratory of Fine Petro-chemical Technology, Changzhou University, Changzhou, Jiangsu 213164, China;

Received Date: 16 November 2012
Available Online: 3 March 2013
Fund Project:

Two new Zinc(Ⅱ) complexes,[Zn₂(bpy)₄(Htfbdc)₂(tfbdc)] (1) and[Zn(bpy)(H₂O)₂(tfbdc)] (2) (2,2'-bpy=2,2'-bipyridine, tfbdc=tetrafluoroterephthalate) have been synthesized and characterized by elemental analysis, IR spectra, thermogravimetric and X-ray single crystal structure analyses. Structure analysis reveals that 1 and 2 possess same crystal system and space group: triclinic,P1. In 1, Zn(Ⅱ) ion has distorted octahedral geometry, while in 2, Zn(Ⅱ) ion has geometry of distorted trigonal bipyramid. Complex 1 is a dinucleate structure, which is further assembled to a 2D supramolecular network through intermolecular hydrogen bonds. Complex 2 is a mononucleate zwitterion, which is further assembled to a 3D supramolecular network via hydrogen bonds interactions. Photoluminescent properties of complexes 1 and 2 in the solid state have also been investigated. CCDC: 900443, 1; 900444, 2.
- zinc(Ⅱ);2,3,5,6-tetrafluoroterephthalic acid;crystal structure;photoluminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142