Citation: NIU Wen-Jun, SHEN Ya-Le, XU Jing, MA Liu-Lei, ZHAO Yu-Hua, SHEN Ming. Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2110-2118. doi: 10.3969/j.issn.1001-4861.2013.00.267 shu

Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange

1.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Received Date: 16 March 2013
Available Online: 13 April 2013
Fund Project: 国家自然科学基金(No.21273194) (No.21273194)江苏科技支撑计划－社会发展基金(No.BE2012705) (No.BE2012705)江苏省大学生实践创新训练计划基金(No.2012JSSPITP1372)资助项目。 (No.2012JSSPITP1372)

This paper reports a facile one-pot solvothermal approach for the preparation of 200nm-size Fe₃O₄ nanospheres with uniform morphology and monodispersity at 160 ℃. During this preparation process, FeCl₃·6H₂O was used as a single iron source, 1, 2-propylene glycol as solvent and reducing agent, urea as a homogeneous precipitant and maleic acid as an additive. The as-prepared Fe₃O₄ nanospheres not only had high magnetization saturation value and but also displayed high catalytic activity during the process of xylenol orange (XO) being oxidized degradation by hydrogen peroxide (H₂O₂). The measurement of UV-Vis spectra indicated that the decolorization rate of xylenol orange was only 6.2% with the oxidation of hydrogen peroxide without Fe₃O₄ catalyst. However, when Fe₃O₄ nanospheres were added to the solution, they showed excellent catalytic activity and the decolorization rate of XOcould be increased to 100% within 1h. The experiment also revealed that Fe₃O₄ nanospheres remained high catalytic activity and stability of material structure after recycling catalyzing of 10 times.
- Fe₃O₄ nanospheres; solvothermal method; catalytic degradation; xylenol orange
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Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange