Citation: NIU Wen-Jun, SHEN Ya-Le, XU Jing, MA Liu-Lei, ZHAO Yu-Hua, SHEN Ming. Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2110-2118. doi: 10.3969/j.issn.1001-4861.2013.00.267 shu

Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange

1.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Received Date: 16 March 2013
Available Online: 13 April 2013
Fund Project: 国家自然科学基金(No.21273194) (No.21273194)江苏科技支撑计划－社会发展基金(No.BE2012705) (No.BE2012705)江苏省大学生实践创新训练计划基金(No.2012JSSPITP1372)资助项目。 (No.2012JSSPITP1372)

This paper reports a facile one-pot solvothermal approach for the preparation of 200nm-size Fe₃O₄ nanospheres with uniform morphology and monodispersity at 160 ℃. During this preparation process, FeCl₃·6H₂O was used as a single iron source, 1, 2-propylene glycol as solvent and reducing agent, urea as a homogeneous precipitant and maleic acid as an additive. The as-prepared Fe₃O₄ nanospheres not only had high magnetization saturation value and but also displayed high catalytic activity during the process of xylenol orange (XO) being oxidized degradation by hydrogen peroxide (H₂O₂). The measurement of UV-Vis spectra indicated that the decolorization rate of xylenol orange was only 6.2% with the oxidation of hydrogen peroxide without Fe₃O₄ catalyst. However, when Fe₃O₄ nanospheres were added to the solution, they showed excellent catalytic activity and the decolorization rate of XOcould be increased to 100% within 1h. The experiment also revealed that Fe₃O₄ nanospheres remained high catalytic activity and stability of material structure after recycling catalyzing of 10 times.
- Fe₃O₄ nanospheres; solvothermal method; catalytic degradation; xylenol orange
1. [1]
  [1] HONG Ruo-Yu(洪若瑜). Magnetic Nanoparticles and Magnetic Fluid(磁性纳米粒和磁性流体). Bejing: Chemical Industry Press, 2009. [2] Laurent S, Forge D, Port M, et al. Chem. Rev., 2008,108(6): 2064-2110 [3] Lu A H, Salabas E L, Schuth F. Angew. Chem. Int. Ed., 2007,46(8):1222-1244 [4] QIAO Rui-Rui(乔瑞瑞), ZENG Jian-Feng(曾剑峰), JIA Qiao -Juan(贾巧娟), et al. Acta Phys.-Chim. Sin. (Wuli Huaxue Xuebao), 2012,28(5):993-1011 [5] Zhou J, Qiao X Y, Binks B P, et al. Langmuir, 2011,27: 3308-3316 [6] HE Guang-Yu(何光裕), ZHANG Yan(张艳), QIAN Mao- Gong(钱茂公), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(11):2306-2312 [7] Cheng W, Tang K B, Qi Y X, et al. J. Mater. Chem., 2010, 20:1799-1805 [8] JIAO Hua(焦华), YANG He-Qing(杨合情), SONG Yu-Zhe (宋玉哲), et al. Acta Chim. Sin. (Huaxue Xuebao), 2007,65 (20):2336-2342 [9] Deng H, Li X L, Peng Q, et al. Angew. Chem. Int. Ed., 2005,117:2842-2845 [10]Zhu M Y, Diao G W. J. Phys. Chem. C., 2011,115:1380-1387 [11]Xu Z C, Hou Y L, Sun S H. J. Am. Chem. Soc., 2007,129: 8698-8699 [12]LIU Bo-Jie(刘波洁), LI Xue-Yi(李学毅), CHEN Wei(陈威), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26(3):784-788 [13]Ding H L, Zhang Y X, Wang S, et al. Chem. Mater., 2012, 24:4572-4580 [14]GAO Qian(高倩), ZHANG Ji-Lin(张吉林), HONG Guang-Yan(洪广言), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2011,32(3):552-559 [15]LU Ping(路苹), ZHANG Ji-Lin(张吉林), SUN De-Hui (孙德慧), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(7):1177-1182 [16]Cao S W, Zhu Y J, Chang J. New Journal of Chemistry, 2008,32(9):1526-1530 [17]JI Jun-Hong(季俊红), JI Sheng-Fu(季生福), YANG Wei (杨伟), et al. Process. Chem. (Huaxue Jinzhan), 2010,22(8): 1566-1574 [18]McCarty P L, Bae J, Kim J. Environ. Sci. Technol., 2011,45: 7100-7106 [19]Ali I. Chem. Rev., 2012,112:5073-5091 [20]Brillas E, Sires I, Oturan M A. Chem. Rev., 2009,109(12): 6570-6631 [21]ZHANG Nai-Dong(张乃东), ZHENG Wei(郑威), Chem. Ind. Eng. Prog. (Huagong Jinzhan),2001,12:1-3 [22]Wang M Q, Wang N, Tang H Q, et al. Catal. Sci. Technol., 2012,2:187-194 [23]Wang N, Zhu L H, Wang M Q, et al. Ultrason. Sonochem., 2010(17):78-83 [24]Kaufman H S, Fankuchen I. Anal. Chem., 1949,21(1):24- 29 [25]Pinna N, Grancharov S, Beato P, et al. Chem. Mater., 2005, 17(11):3044-3049 [26]Sun G B, Dong B X, Cao M H, et al. Chem. Mater., 2011,23 (6):1587-1593
1. [1]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
2. [2]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
3. [3]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
6. [6]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
7. [7]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
8. [8]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
9. [9]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
10. [10]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
11. [11]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
12. [12]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
13. [13]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
14. [14]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
15. [15]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
16. [16]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
17. [17]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
18. [18]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
19. [19]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
20. [20]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(260)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Solvothermal Synthesis of Fe3O4 Nanospheres and Study on the Catalytic Degradation of Xylenol Orange

Metrics

通讯作者: 陈斌, bchen63@163.com

Solvothermal Synthesis of Fe₃O₄ Nanospheres and Study on the Catalytic Degradation of Xylenol Orange