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Citation: NIU Wen-Jun, SHEN Ya-Le, XU Jing, MA Liu-Lei, ZHAO Yu-Hua, SHEN Ming. Solvothermal Synthesis of Fe3O4 Nanospheres and Study on the Catalytic Degradation of Xylenol Orange[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2110-2118. doi: 10.3969/j.issn.1001-4861.2013.00.267 shu

Solvothermal Synthesis of Fe3O4 Nanospheres and Study on the Catalytic Degradation of Xylenol Orange

  • 1.

    School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

  • Received Date: 16 March 2013
    Available Online: 13 April 2013

    Fund Project: 国家自然科学基金(No.21273194) (No.21273194)江苏科技支撑计划－社会发展基金(No.BE2012705) (No.BE2012705)江苏省大学生实践创新训练计划基金(No.2012JSSPITP1372)资助项目。 (No.2012JSSPITP1372)

  • This paper reports a facile one-pot solvothermal approach for the preparation of 200nm-size Fe3O4 nanospheres with uniform morphology and monodispersity at 160 ℃. During this preparation process, FeCl3·6H2O was used as a single iron source, 1, 2-propylene glycol as solvent and reducing agent, urea as a homogeneous precipitant and maleic acid as an additive. The as-prepared Fe3O4 nanospheres not only had high magnetization saturation value and but also displayed high catalytic activity during the process of xylenol orange (XO) being oxidized degradation by hydrogen peroxide (H2O2). The measurement of UV-Vis spectra indicated that the decolorization rate of xylenol orange was only 6.2% with the oxidation of hydrogen peroxide without Fe3O4 catalyst. However, when Fe3O4 nanospheres were added to the solution, they showed excellent catalytic activity and the decolorization rate of XOcould be increased to 100% within 1h. The experiment also revealed that Fe3O4 nanospheres remained high catalytic activity and stability of material structure after recycling catalyzing of 10 times.
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