Citation: LIANG Han, KANG Jing-Jing, GUO Qiong, ZHANG Qi, FEI Ri-Ling, GUO Zi-Dong, LI Lian-Zhi. Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)][J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1819-1824. doi: 10.3969/j.issn.1001-4861.2013.00.264 shu

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)]

1.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China

Received Date: 15 January 2013
Available Online: 29 March 2013
Fund Project: 聊城大学大学生科技文化创新基金(No.SF2012048和SRT11043HX2) (No.SF2012048和SRT11043HX2)山东省自然科学基金(No.Y2004B02)资助项目。 (No.Y2004B02)

Two new chiral oxovanadium complexes,[VO(Naph-Leu)(OMe)(CH₃OH)] (1) and[VO(Naph-Phe)(OMe)(CH₃OH)] (2), (Naph-Leu=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-leucine, Naph-Phe=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-phenylalanine), have been synthesized. Single crystal X-ray diffraction analysis showed that complex 1 crystallized in the orthorhombic crystal system, space group P2₁2₁2 with the cell parameters: a=0.946 80(8) nm, b=3.246 3(3) nm, c=0.662 37(5) nm, V=2.035 9(3) nm³, Z=4, F(000)=864, R₁=0.046 3, wR₂=0.112 7, S=1.076; and complex 2, crystallized in the monoclinic crystal system, space group P2₁ with the cell parameters: a=1.113 41(11) nm, b=0.724 09(6) nm, c=1.342 99(12) nm, V=1.047 95(16) nm³, Z=2, F(000)=464, R₁=0.035 8, wR₂=0.088 8, S=1.024. The IR, UV-Vis and circular dichroism (CD) spectra of the two complexes were measured and discussed. CCDC: 885240, 1; 897188, 2.
- chirality;oxovanadium complex;crystal structure;CD spectra
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH3OH)] and[VO(Naph-Phe)(OMe)(CH3OH)]

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)]