Citation:
ZHANG Fu-Xing, KUANG Dai-Zhi, FENG Yong-Lan, WANG Jian-Qiu, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Synthesis, Crystal Structure and Properties of the Tricyclohexyltin R-Mandeliate[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(10): 2099-2104.
doi:
10.3969/j.issn.1001-4861.2013.00.263
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The tricyclohexyltin R-mandeliate was synthesized by the reaction of the tricyclohexyltin hydroxide with the R-mandelic acid. Its structure has been determined by X-ray single crystal diffraction. The crystal belongs to orthorhombic with space group P21212 a=0.80641(4) nm, b=1.76868(9) nm, c=1.83479(8) nm, V=2.6169(2) nm3, Z=4, Dc=1.318 g·cm-3, μ(Mo Kα)=9.98 cm-1, F(000)=1080, R1=0.0390, wR2=0.1039. The tin atom has a distorted tetrahedral geometry.The study on title complex has been performed,with quantum chemistry calculation by means of G03Wpackage and taking Lanl2dz basis set. The stabilities of the complex,the orbital energies and composition characteristics of some frontier molecular orbitals have been investigated. The properties of thermogravimetric analysis and photoluminescent behavior and electrochemical of the complex have also been discussed.
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