Citation: JIANG Jing, WANG Dong-Jie, LIU Zhi-Peng, WANG Jun-Long, LI Xing. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Complex with 1, 3-Di(4-pyridy)propane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1952-1956. doi: 10.3969/j.issn.1001-4861.2013.00.260 shu

Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Complex with 1, 3-Di(4-pyridy)propane

1.
Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

Received Date: 30 December 2012
Available Online: 7 April 2013
Fund Project: 浙江省自然科学基金(No.LY12B01005) (No.LY12B01005)上海市分子催化和功能材料重点实验室开放课题(No.2012MCIF02) (No.2012MCIF02)

A new Cd(Ⅱ) complex {[CdL₂(H₂O)₂]·2(C₇H₆N₅)}_n(C₇H₆N₅=5-(3-aminophenyl)tetrazole ion) based on a ligand L (L=1,3-di(4-pyridy)propane) has been synthesized and structurally characterized by X-ray single crystal diffraction analysis. Structural analysis reveals that the complex is a one-dimensional complex. The Cd(Ⅱ) ion adopts a distorted octahedral coordinated geometry formed by four N atoms and two O atoms, of which four N atoms from different L ligands, two O atoms from different H₂O. In the crystal, adjacent Cd(Ⅱ) centers are bridged by L ligands to generate a one-dimensional chain structure. The one-dimensional chains are further connected into a three-dimensional supramolecular network by O-H…N, N-H…N hydrogen bonding contacts. CCDC: 908806.
- 1, 3-di(4-pyridy)propane;Cd(Ⅱ) complex;crystal structure;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142