Citation: SONG Ji-Mei, ZHAO Shao-Juan, WANG Yong, HU Hai-Qin, SHI Ya-Li, REN Ming-Song. ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1813-1818. doi: 10.3969/j.issn.1001-4861.2013.00.258 shu

ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity

1.
1 College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China;

Received Date: 29 January 2013
Available Online: 23 April 2013
Fund Project: 国家自然科学基金(No.21171002) (No.21171002)安徽省自然科学基金(No.11040606M55) (No.11040606M55)安徽省教育厅自然科学基金(No.KJ2010A015)资助项目。 (No.KJ2010A015)

ZnWO₄ nanoparticles were synthesized by a facile solvothermal method. ZnWO₄ nanoparticles were utilized as the catalyst for the formation of 5-phenyl-1H-tetrazoles from cyclo-addition reaction. The results show that the yield reaches 81% when 0.2 mmol catalyst is used at 110℃ for 10 h. However, the yield only reaches 43% and 65% for amorphous and nanorods ZnWO₄, respectively. Clearly, ZnWO₄ nanoparticles display superior catalytic performance. This high activity might be attributed to the larger surface area and more active sites that originate from the small size and good dispersibility of ZnWO₄ nanoparticles. The unsaturated W atoms on the surface of ZnWO₄ nanoparticles can activate the nitriles and enhance the reactivity for azides.
- nanoparticles;ZnWO₄;catalysis;5-phenyl-1H-tetrazoles
1. [1]
  [1] Tsarevsky N V, Bernaerts K V, Dufour B, et al. Macromole-cules., 2004,37:9308-9313
2. [2]
  [2] Herr R J. Bioorg. Med. Chem., 2002,10:3379-3393
3. [3]
  [3] Bavetsias V, Marriott J H, Melin C, et al. J. Med. Chem., 2000,43:1910-1926
4. [4]
  [4] Wittenberger S. J. Org. Prep. Proced. Int., 1994,26:499-531
5. [5]
  [5] Ostrovskii V A, Pevzner M S, Kofmna T P, et al. Targets Heterocycl. Syst., 1999,3:467
6. [6]
  [6] Hiskey M, Chavez D E, Naud D L, et al. Proc. Int. Pyrotech. Semin., 2000,27:3-14
7. [7]
  [7] Koldobskii G I, Ostrovskii V A. Usp. Khim., 1994,63:847-865
8. [8]
  [8] Huisgen R, Sauer J, Sturn H J. Chem. Ber., 1960,93:2106-2124
9. [9]
  [9] Abu-Eittah R H, El-Kelany. Spectrochim. Acta. Part A, 2012, 99:316-328
10. [10]
  [10] Terrence R B J, Yao Z J, Gao Y, et al. Bioorg. Med. Chem., 2001,9:1439-1445
11. [11]
  [11] Herandez A S, Cheng P T W, Musial C M, et al. Bioorg. Med. Chem., Lett., 2007,17:5928-5933
12. [12]
  [12] Wang L Z, Qu Z R, Zhao H. Inorg. Chem.,2003,42:3969-3971
13. [13]
  [13] Amantini D, Beleggia R, Fringuelli F, et al. J. Org. Chem., 2004,69:2896-2898
14. [14]
  [14] Aridoss G, Zhao C Q, Borosky G L, et al. J. Org. Chem., 2012,77:4152-4155
15. [15]
  [15] Ostrovskii V A, Koren A O. Heterocycles., 2000,53:1421-1448
16. [16]
  [16] Harding M M, Mokdsi G. Curr. Med. Chem., 2000,7(12): 1289-1303
17. [17]
  [17] Demko Z P, Sharpless K B. J. Org. Chem., 2001,66:7945-7950
18. [18]
  [18] Zhou Y, Yao C, Ni R J, et al. Synth. Commun., 2010,40: 2624-2632
19. [19]
  [19] He J H, Li B J, Chen F S, et al. J. Mol. Catal. A, 2009,304: 135-138
20. [20]
  [20] Aridoss G, Laali K K. Eur. J. Org. Chem., 2011:6343-6355
21. [21]
  [21] Lang L M, Li B J, Liu W, et al. Chem. Comm., 2010,46:448-450
22. [22]
  [22] Liu Y X, Song H, Zhang Q H, et al. Ind. Eng. Chem. Res., 2012,51:4779-4893
23. [23]
  [23] Zhu L P, Zhang W D, Xiao H M, et al. J. Phys. Chem. C., 2008,112:10073-10078
24. [24]
  [24] Zhong L S, Hu J S, Liang H P, et al. J. Adv. Mater., 2006, 18:2426-2431
25. [25]
  [25] Yu D B, Sun X Q, Zou J W, et al. J. Phys. Chem. B, 2006, 110:21667-21671
26. [26]
  [26] LI Lei(李蕾), ZENG Shu-yuan(曾涑源), MI Yu-wei(米玉伟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 8(28):1643-1650
27. [27]
  [27] Lin J, Lin J, Zhu Y F. Inorg. Chem., 2007,46(20):8372-8378
28. [28]
  [28] Gillet M, Lemire C, Gillet E, et al. Surf. Sci., 2003,532:519-526
29. [29]
  [29] Nagornaya L, Burachas S, Vostretsov Y, et al. J. Cryst. Growth., 1999,877:199-199
30. [30]
  [30] Wahl D, Mykhaylyk M S, Mikhailik V B et al. J. Appl. Phys., 2005,97:083523-083523
31. [31]
  [31] Song J M, Wang H, Li Y P, et al. Mater. Res. Bull., 2012, 47:315-320
32. [32]
  [32] Dambournet D, Leclerc H, Vimont A, et al. Phys. Chem. Chem. Phys., 2009,11:1369-1379
33. [33]
  [33] ZENG Yu-Feng(曾玉凤), LIU Zi-Li(刘自力), QIN Zu-Zeng (秦祖赠), et al. Chinese J. Mole. Catal.(Fenzi Cuihua), 2009,23(1):53-56
1. [1]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-0. doi: 10.3866/PKU.WHXB202408002
2. [2]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . Catalytic Effect of H₃PW₁₂O₄₀ on Hydrogen Storage of MgH₂. Acta Physico-Chimica Sinica, 2025, 41(1): 100001-0. doi: 10.3866/PKU.WHXB202308032
3. [3]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
4. [4]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
5. [5]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . Construction of 4-Amino-1H-imidazole-5-carbonitrile Modified Carbon Nitride-Based Donor-Acceptor Photocatalyst for Efficient Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-0. doi: 10.3866/PKU.WHXB202406026
6. [6]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
7. [7]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
8. [8]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
9. [9]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
10. [10]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
11. [11]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
14. [14]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
15. [15]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
16. [16]
  Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007
17. [17]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
18. [18]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
19. [19]
  Rui LIU , Xinjun ZHOU , Tao WANG . Photocatalytic degradation performance of tetracycline by MOF-74-Mn/g-C₃N₄ Z-type heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1796-1804. doi: 10.11862/CJIC.20250033
20. [20]
  Gaopeng Liu , Lina Li , Bin Wang , Ningjie Shan , Jintao Dong , Mengxia Ji , Wenshuai Zhu , Paul K. Chu , Jiexiang Xia , Huaming Li . Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(7): 2306041-0. doi: 10.3866/PKU.WHXB202306041

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(375)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

ZnWO4 Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity

Metrics

通讯作者: 陈斌, bchen63@163.com

ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity