Citation: SONG Ji-Mei, ZHAO Shao-Juan, WANG Yong, HU Hai-Qin, SHI Ya-Li, REN Ming-Song. ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1813-1818. doi: 10.3969/j.issn.1001-4861.2013.00.258 shu

ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity

1.
1 College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China;

Received Date: 29 January 2013
Available Online: 23 April 2013
Fund Project: 国家自然科学基金(No.21171002) (No.21171002)安徽省自然科学基金(No.11040606M55) (No.11040606M55)安徽省教育厅自然科学基金(No.KJ2010A015)资助项目。 (No.KJ2010A015)

ZnWO₄ nanoparticles were synthesized by a facile solvothermal method. ZnWO₄ nanoparticles were utilized as the catalyst for the formation of 5-phenyl-1H-tetrazoles from cyclo-addition reaction. The results show that the yield reaches 81% when 0.2 mmol catalyst is used at 110℃ for 10 h. However, the yield only reaches 43% and 65% for amorphous and nanorods ZnWO₄, respectively. Clearly, ZnWO₄ nanoparticles display superior catalytic performance. This high activity might be attributed to the larger surface area and more active sites that originate from the small size and good dispersibility of ZnWO₄ nanoparticles. The unsaturated W atoms on the surface of ZnWO₄ nanoparticles can activate the nitriles and enhance the reactivity for azides.
- nanoparticles;ZnWO₄;catalysis;5-phenyl-1H-tetrazoles
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沈阳化工大学材料科学与工程学院沈阳 110142

ZnWO4 Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity

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通讯作者: 陈斌, bchen63@163.com

ZnWO₄ Nanoparticles as Catalyst for Synthesis of 5-Phenyl-1H-tetrazoles with High Activity