Citation: WANG Xiu-Li, ZHAO Dan, TIAN Ai-Xiang, LIU Guo-Cheng. Synthesis, Crystal Structure and Property of a 3D Octamolybdate Coordination Polymer Based on Nickel(Ⅱ)-bis(triazole) System[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1668-1674. doi: 10.3969/j.issn.1001-4861.2013.00.256 shu

Synthesis, Crystal Structure and Property of a 3D Octamolybdate Coordination Polymer Based on Nickel(Ⅱ)-bis(triazole) System

1.
Department of Chemistry, Bohai University, Jinzhou, Liaoning 121000, China

Received Date: 11 August 2012
Available Online: 1 March 2013
Fund Project: 国家自然科学基金(No.21171025,21101015)资助项目。 (No.21171025,21101015)

A new 3D coordination polymer [Ni₂(bte)₅(γ-Mo₈O₂₆)]·5H₂O(1) (bte=1, 2-bis(1, 2, 4-triazol-1-y1)ethane), has been synthesized under hydrothermal conditions and characterized by elemental analyses, thermogravimetric analysis (TGA) and single crystal X-ray diffraction. The crystal structure analysis indicates that in compound 1, the bte ligands link the Ni(Ⅱ) ions and construct a unique 2D metal-organic layer. The γ-[Mo₈O₂₆]^4- anions show two different functions: (i) it acts as a structural directing agent embeding in the 2D metal-organic layer; (ii) it is functionalized by the bte ligands through Mo-N bonds for bridging this 2D metal-organic layer and finally inducing a 3D framework of 1 with the Schläfli symbol of {3²·4⁴·5⁴·6²·7³}{3²·4⁶·5⁶·6}₂. In addition, the electrochemical and fluorescence properties of the title compound have been studied. CCDC: 881771.
- γ-octamolybdate;metal-organic layer;fluorescence property;bis(triazole)-based ligand
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沈阳化工大学材料科学与工程学院沈阳 110142