Citation:
WANG Xiu-Li, ZHAO Dan, TIAN Ai-Xiang, LIU Guo-Cheng. Synthesis, Crystal Structure and Property of a 3D Octamolybdate Coordination Polymer Based on Nickel(Ⅱ)-bis(triazole) System[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(8): 1668-1674.
doi:
10.3969/j.issn.1001-4861.2013.00.256
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A new 3D coordination polymer [Ni2(bte)5(γ-Mo8O26)]·5H2O(1) (bte=1, 2-bis(1, 2, 4-triazol-1-y1)ethane), has been synthesized under hydrothermal conditions and characterized by elemental analyses, thermogravimetric analysis (TGA) and single crystal X-ray diffraction. The crystal structure analysis indicates that in compound 1, the bte ligands link the Ni(Ⅱ) ions and construct a unique 2D metal-organic layer. The γ-[Mo8O26]4- anions show two different functions: (i) it acts as a structural directing agent embeding in the 2D metal-organic layer; (ii) it is functionalized by the bte ligands through Mo-N bonds for bridging this 2D metal-organic layer and finally inducing a 3D framework of 1 with the Schläfli symbol of {32·44·54·62·73}{32·46·56·6}2. In addition, the electrochemical and fluorescence properties of the title compound have been studied. CCDC: 881771.
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-
-
[1]
[1] Zhong Y L, Ng W W, Zhang J X, et al. J. Am. Chem. Soc., 2009,131:18293-18298
-
[2]
[2] Yamase T. Chem. Rev., 1998,98:307-325
-
[3]
[3] Qi W, Wang Y Z, Lin W, et al. Chem. Eur. J., 2010,16: 1068-1070
-
[4]
[4] Yan X H, Zhu P L, Fei J B, et al. Adv. Mater., 2010,22: 1283-1287
-
[5]
[5] Ritchie C, Ferguson A, Nojiri H, et al. Angew. Chem. Int. Ed., 2008,47:5609-5612
-
[6]
[6] Xi Z W, Zhou N, Sun Y, et al. Science, 2001,292:1139-1141
-
[7]
[7] Botar B, Geletili Y V, Kgerler P, et al. J. Am Chem. Soc., 2006,128:11268-11277
-
[8]
[8] Kamata K, Yonehara K, Sumida Y, et al. Science, 2003, 300:964-966
-
[9]
[9] Liu H Y, Wu H, Ma J F, et al. Dalton Trans., 2011,40:602-613
-
[10]
[10] Liu H Y, Bo L, Yang J, et al. Dalton Trans., 2011,40:9782-9788
-
[11]
[11] Zhang C J, Pang H J, Tang Q, et al. New J. Chem., 2011, 35:190-196
-
[12]
[12] Lan Y Q, Li S L, Wang X L, et al. Inorg. Chem., 2008,47: 8179-8187
-
[13]
[13] Li S L, Lan Y Q, Ma J F, et al. Inorg. Chem., 2007,46: 8283-8290
-
[14]
[14] Bridgeman A J. J. Phys. Chem., A, 2002,106:12151-12160
-
[15]
[15] Wu C D, Lu C Z, Zhuang H H, et al. Inorg. Chem., 2002, 41:5636-5637
-
[16]
[16] Hageman D, Zapf P J, Zubieta J. Chem. Commun., 1998, 1283-1284
-
[17]
[17] Raring R S, Zubieta J. Inorg. Chim. Acta, 2001,312:188-196
-
[18]
[18] Wang X L, Li J, Tian A X, et al. CtystEngComm, 2011,13: 2194-2196
-
[19]
[19] Wang X L, Hu H L, Liu G C, et al. Chem. Commum., 2010, 46:6485-6489
-
[20]
[20] Wang X L, Li J, Tian A X, et al. Cryst. Growth Des., 2011, 11:3456-3462
-
[21]
[21] Tian A X, Ying J, Peng J, et al. Inorg. Chem., 2008,47: 3274-3283
-
[22]
[22] WU Jing-Jing(吴晶晶), HAN Zhan-Gang(韩占刚), WANG Yan-Nan(王彦娜), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26:921-925
-
[23]
[23] WANG Xiao-Lan(王晓兰), LI Yang-Gang(李阳光), MANG Jing-Xi(孟靖昕), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26:391-397
-
[24]
[24] Wang X L, Zhao D, Tian A X, et al. Inorg. Chim. Acta, 2012,388:114-119
-
[25]
[25] Tian A X, Liu X J, Ying J, et al. CtystEngComm, 2011,13: 6680-6687
-
[26]
[26] LIU Xun-Gao(刘训高), ZHANG Yu-Mei(张玉梅), LI Bao-Long(李宝龙), J. Suzhou Univ.: Natural Sci.(Suzhou Daxue Xuebao: Ziran Kexueban), 2005,21:59-62
-
[27]
[27] Wang X L, Kang Z H, Wang E B, et al. Mater. Lett., 2002, 56:393-396
-
[28]
[28] Sheldrick G M. Acta Crystallogr. A, 2008,64:112-122
-
[29]
[29] Gao Y Z, Xu Y Q, Han Z G, et al. J. Solid State Chem., 2010,183:1000-1006
-
[30]
[30] Bi Y F, Du S C, Liao W P. Chem. Commun., 2011,47:4724-4726
-
[31]
[31] Dolomanov O V, Blake A J, Champness N R, et al. J. Appl. Crystallogr., 2003,36:1283-1284
-
[32]
[32] Keita B, Nadjo L. J. Electroanal. Chem., 1987,227:77-98
-
[33]
[33] Liu X G, Wang L Y, Zhu X, et al. Cryst. Growth Des., 2009,9:3997-4005
-
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