Citation: MA Jing-Liang, WANG Dian-Long, CHEN Fei, FANG Ming-Xue. Synthesis and Characterization of Lead Sulfate/Graphene Nano Sheets Composites as Anode Materials for Lead Acid Battery[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1935-1941. doi: 10.3969/j.issn.1001-4861.2013.00.252 shu

Synthesis and Characterization of Lead Sulfate/Graphene Nano Sheets Composites as Anode Materials for Lead Acid Battery

1.
1 School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China;

Received Date: 29 November 2012
Available Online: 20 March 2013
Fund Project: 国家自然科学基金(No.50974045) (No.50974045)教育部博士点基金(No.20092302110052) (No.20092302110052)黑龙江省自然科学基金(No.B200918)资助项目。 (No.B200918)

Lead sulfate/graphene nano sheets (GNS) composites were fabricated by using a simple impregnation method. The composite was used as a negative active material for lead acid battery. Compared with pure lead sulfate electrodes, the composite electrodes display higher specific capacity and rechargeable performance under high charge and discharge rates. An average discharging specific capacity of PbSO₄/GNS composites reaches 110, 94 and 69 mAh·g^-1 at current density of 100 mA·g^-1, 200 mA·g^-1 and 300 mA·g^-1, respectively. However, the average discharging capacity of PbSO₄ only reaches 49, 5 and 0.5 mAh·g^-1 at the same condition. The electrochemical characteristic of the composites electrode was studied by cyclic voltammetry (CV) and battery tests. The cyclic voltammetry results show that capacitive effect and the hydrogen evolution of graphene nano sheets become more obvious with the increase in scanning rate resulting in 20% lower charging efficiency of PbSO₄/GNS composites compared to lead sulfate. The battery charge-discharge curves confirm that graphene nano sheets improve the charging voltage about 0.1 V and can also help double the capacity of lead sulfate. The XRD and SEM results show that lead sulfate particles are well dispersed on the surface of graphene nano sheets instead of agglomerating.
- lead acid battery;impregnation method;lead sulfate;graphene nano sheet;capacitive effect
1. [1]
  [1] Lam T, Haigh P, Phyland G, et al. J. Power Sources, 2004, 133(1):126-134
2. [2]
  [2] Aidman G. J. Power Sources, 1996,59(1):25-30
3. [3]
  [3] Vermesan H, Hirai N, Shiota M, et al. J. Power Sources, 2004,133(1):52-58
4. [4]
  [4] Petkova G, Nikolov P, Pavlov D. J. Power Sources, 2006,158 (2):841-845
5. [5]
  [5] Pavlov D, Nikolov P, Rogachev T. J. Power Sources, 2011, 196(11):5155-5167
6. [6]
  [6] Lam T, Louey R. J. Power Sources, 2006,158(2):1140-1148
7. [7]
  [7] Lam T, Louey R, Haigh P, et al. J. Power Sources, 2007,174 (1):16-29
8. [8]
  [8] Cooper A, Furakawa J, Lam T, et al. J. Power Sources, 2009, 188(2):642-649
9. [9]
  [9] Furukawa J, Takada T, Monma D, et al J. Power Sources, 2010,195(4):1241-1245
10. [10]
  [10] Novoselov S, Geim K, Morozov V, et al. Science, 2004,306 (5696):666-669
11. [11]
  [11] Chou S L, Wang J Z, Choucair M, et al. Electrochem. Commun., 2010,12(2):303-306
12. [12]
  [12] Zhu N, Liu W, Xue M, et al. Electrochim. Acta, 2010,55 (20):5813-5818
13. [13]
  [13] Li Y, Lü X, Lu J, et al. J. Phys. Chem. C, 2010,114(49): 21770-21774
14. [14]
  [14] Yan Z, Hu X. Mater. Chem. Phys., 2003,77(2):402-405
15. [15]
  [15] Zhang B, Zhong J, Li W, et al. J. Power Sources, 2010,195 (13):4338-4343
16. [16]
  [16] Chen F, Hu X, Ren A, et al. CN Patent, 102201575. 2011-9-28.
17. [17]
  [17] Hummers S, Offeman E. J. Am. Chem. Soc., 1958,80(6): 1339-1339
18. [18]
  [18] Du Q, Zheng M, Zhang L, et al. Electrochim. Acta, 2010,55 (12):3897-3903
19. [19]
  [19] Moseley T. J. Power Sources, 2009,191(1):134-138
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
3. [3]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
4. [4]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
5. [5]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
8. [8]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
9. [9]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
10. [10]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
11. [11]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
12. [12]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
13. [13]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
14. [14]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
15. [15]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
16. [16]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
17. [17]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
18. [18]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
19. [19]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
20. [20]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(330)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142