Citation: XU Yang, FU Rao, LIU Yang, ZHANG Hai-Yang, WANG Zhao. One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2126-2132. doi: 10.3969/j.issn.1001-4861.2013.00.251 shu

One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂

XU Yang ¹ ,
FU Rao ¹ ,
LIU Yang ¹ ,
ZHANG Hai-Yang ¹ ,
WANG Zhao ²

1.
1 Development Department of Chang Chun Ju Ming Optoelectronic Materials Company, Changchun 130103, China;

Received Date: 6 January 2013
Available Online: 21 March 2013
Fund Project: 国家自然科学基金(No.51173038) (No.51173038)科技型中小企业技术创新基金(No.12C26212201382)资助项目 (No.12C26212201382)

TiO₂ nanorod arrays were synthesized through the one-step hydrothermal process. The influence of deionized water to the morphology of nanorod arrays instead of absolute ethyl alcohol as precursor was also investigated. The results showed that a layer of TiO₂ microsphere can be synthesized on the top of the nanorod arrays, which serve as the basic unit for the growth of microsphere and finally result in complex TiO₂ nanorod arrays film. The XRDand TEMresults suggeste that the nanorod arrays film is consisted of single-crystalline TiO₂with tetragonal rutile phase structures. After the assembling of dye sensitized solar cells with the as-synthesized samples, the open-circuit voltage and short-circuit current density and fill factor were measured out as V_oc=0.63 V, J_sc=10.9 mA·cm^-2 and FF=56.3%, respectively. The energy conversion efficiency (η) is approximately 4.1%.
- Ti₀₂ nanorod; complex structure; hydrothermal; DSSC; conversion efficiency
1. [1]
  [1] CUI Rong-Qiang(崔容强), HUANG Yan(黄燕), SUN Tie-Guo (孙铁国). Energy Eng.(Nengyuan Gongcheng), 1999,1:1-3 [2] O'Regan B, Gratzel M. Nature, 1991,24:353-737 [3] Hegfleldt A, Gratzel M. Chem. Rev., 1995,95:49-68 [4] Meng Q B, Lin Y, Dai S. Y. Physics, 2004,3:177-180 [5] Desilvestro J, Graetzel M, Kavan L, et al. J. Am. Chem. Soc., 1985,10:2988-2990 [6] Seigo L, Murakami T N, Comte P, et al. Thin Solid Films, 2008,30:4613-4619 [7] Daeneke T, Kwon T H, Holmes A B, et al. Nature Chem., 2011,3:211-215 [8] Dai S Y, Kong F T, Hu L H, et al. Acta Phys. Sin., 2005,4: 1919-1926 [9] Kong F T, Dai S Y. Prog. Chem., 2004,18:1410-1422 [10]Hu L H, Dai S Y. Chin. Phys. Lett., 2005,22:493-499 [11]Oskam G, Meyer G J. J. Phys. Chem., 1996,100:17021-17027 [12]Hao Y Z, Yang M Z, Cai S M. Acta Phys.-Chim. Sin., 1998, 14:309-314 [13]Vlachopoulos N, Liska P, Augustynski. J. Am. Chem. Soc., 1988,4:1216-1220 [14]Gopal K M, Karthik S, Maggie P, et al. Nano Lett., 2006,2: 215-218 [15]Ferber J, Luther J. Solar Energy Mater. Solar Cells., 1998, 54:265-275 [16]Barbe C, Arendse F, Comte P, et al. J. Am. Ceram. Soc., 1997,80:3157-3171 [17]Koo B, Park J, Kim Y, et al. J. Phys. Chem., 2006,110: 24318-24323 [18]Adachi M, Murata Y, Takao J, et al. J. Am. Chem. Soc., 2004,126:14943-14949 [19]Liu B, Aydil E S. J. Am. Chem. Soc., 2009,11:3985-3990 [20]Kang S H, Choi S H, Kang M S, et al. Adv. Mater., 2008, 20:54-58 [21]Law M, Greene L E, Johnson J C, et al. Nat. Mater., 2005, 4:455-459 [22]Tan B, Wu Y Y. J. Phys. Chem., 2006,110:15932-19538 [23]Karthik S, Gopal K M, Haripriya E P, et al. Iopsci. Nano- technol., 2007,18:707-714 [24]Liu B, Aydil E S. J. Am. Chem. Soc., 2009,11:3985-3990 [25]Marco L D, Manca M, Giannuzzi R, et al. J. Phys. Chem., 2010,114:4228-4236 [26]Manuela J, Haim L. Nano Lett., 2003,3:353-358 [27]Jong H P, Sungwook K, Allen J. E. Nano Lett., 2006,1:24- 28 [28]Marian N, Joop S, Albert G. Nano Lett., 2005,9:1716-1719 [29]ZHONG Wei-Zhuo(仲维卓), HUA Su-Kun(华素坤). Shanghai Chem. Ind.(Shanghai Huagong), 1998,11:25-27 [30]LI Jing-Xian(李竟先), WU Jin-Qiu(吴基球). China Ceram. (Zhongguo Taoci), 2002,38:72-76 [31]Huang X P, Pan C X. J. Cryst. Growth, 2007,306:117-122 [32]LI Jing-Xian(李竟先), WU Jin-Qiu(吴基球). China Ceram. Ind.(Zhongguo Taoci Gongye), 2001,8:29-33
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One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO2

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通讯作者: 陈斌, bchen63@163.com

One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂