Citation: XU Yang, FU Rao, LIU Yang, ZHANG Hai-Yang, WANG Zhao. One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2126-2132. doi: 10.3969/j.issn.1001-4861.2013.00.251 shu

One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂

XU Yang ¹ ,
FU Rao ¹ ,
LIU Yang ¹ ,
ZHANG Hai-Yang ¹ ,
WANG Zhao ²

1.
1 Development Department of Chang Chun Ju Ming Optoelectronic Materials Company, Changchun 130103, China;

Received Date: 6 January 2013
Available Online: 21 March 2013
Fund Project: 国家自然科学基金(No.51173038) (No.51173038)科技型中小企业技术创新基金(No.12C26212201382)资助项目 (No.12C26212201382)

TiO₂ nanorod arrays were synthesized through the one-step hydrothermal process. The influence of deionized water to the morphology of nanorod arrays instead of absolute ethyl alcohol as precursor was also investigated. The results showed that a layer of TiO₂ microsphere can be synthesized on the top of the nanorod arrays, which serve as the basic unit for the growth of microsphere and finally result in complex TiO₂ nanorod arrays film. The XRDand TEMresults suggeste that the nanorod arrays film is consisted of single-crystalline TiO₂with tetragonal rutile phase structures. After the assembling of dye sensitized solar cells with the as-synthesized samples, the open-circuit voltage and short-circuit current density and fill factor were measured out as V_oc=0.63 V, J_sc=10.9 mA·cm^-2 and FF=56.3%, respectively. The energy conversion efficiency (η) is approximately 4.1%.
- Ti₀₂ nanorod; complex structure; hydrothermal; DSSC; conversion efficiency
1. [1]
  [1] CUI Rong-Qiang(崔容强), HUANG Yan(黄燕), SUN Tie-Guo (孙铁国). Energy Eng.(Nengyuan Gongcheng), 1999,1:1-3 [2] O'Regan B, Gratzel M. Nature, 1991,24:353-737 [3] Hegfleldt A, Gratzel M. Chem. Rev., 1995,95:49-68 [4] Meng Q B, Lin Y, Dai S. Y. Physics, 2004,3:177-180 [5] Desilvestro J, Graetzel M, Kavan L, et al. J. Am. Chem. Soc., 1985,10:2988-2990 [6] Seigo L, Murakami T N, Comte P, et al. Thin Solid Films, 2008,30:4613-4619 [7] Daeneke T, Kwon T H, Holmes A B, et al. Nature Chem., 2011,3:211-215 [8] Dai S Y, Kong F T, Hu L H, et al. Acta Phys. Sin., 2005,4: 1919-1926 [9] Kong F T, Dai S Y. Prog. Chem., 2004,18:1410-1422 [10]Hu L H, Dai S Y. Chin. Phys. Lett., 2005,22:493-499 [11]Oskam G, Meyer G J. J. Phys. Chem., 1996,100:17021-17027 [12]Hao Y Z, Yang M Z, Cai S M. Acta Phys.-Chim. Sin., 1998, 14:309-314 [13]Vlachopoulos N, Liska P, Augustynski. J. Am. Chem. Soc., 1988,4:1216-1220 [14]Gopal K M, Karthik S, Maggie P, et al. Nano Lett., 2006,2: 215-218 [15]Ferber J, Luther J. Solar Energy Mater. Solar Cells., 1998, 54:265-275 [16]Barbe C, Arendse F, Comte P, et al. J. Am. Ceram. Soc., 1997,80:3157-3171 [17]Koo B, Park J, Kim Y, et al. J. Phys. Chem., 2006,110: 24318-24323 [18]Adachi M, Murata Y, Takao J, et al. J. Am. Chem. Soc., 2004,126:14943-14949 [19]Liu B, Aydil E S. J. Am. Chem. Soc., 2009,11:3985-3990 [20]Kang S H, Choi S H, Kang M S, et al. Adv. Mater., 2008, 20:54-58 [21]Law M, Greene L E, Johnson J C, et al. Nat. Mater., 2005, 4:455-459 [22]Tan B, Wu Y Y. J. Phys. Chem., 2006,110:15932-19538 [23]Karthik S, Gopal K M, Haripriya E P, et al. Iopsci. Nano- technol., 2007,18:707-714 [24]Liu B, Aydil E S. J. Am. Chem. Soc., 2009,11:3985-3990 [25]Marco L D, Manca M, Giannuzzi R, et al. J. Phys. Chem., 2010,114:4228-4236 [26]Manuela J, Haim L. Nano Lett., 2003,3:353-358 [27]Jong H P, Sungwook K, Allen J. E. Nano Lett., 2006,1:24- 28 [28]Marian N, Joop S, Albert G. Nano Lett., 2005,9:1716-1719 [29]ZHONG Wei-Zhuo(仲维卓), HUA Su-Kun(华素坤). Shanghai Chem. Ind.(Shanghai Huagong), 1998,11:25-27 [30]LI Jing-Xian(李竟先), WU Jin-Qiu(吴基球). China Ceram. (Zhongguo Taoci), 2002,38:72-76 [31]Huang X P, Pan C X. J. Cryst. Growth, 2007,306:117-122 [32]LI Jing-Xian(李竟先), WU Jin-Qiu(吴基球). China Ceram. Ind.(Zhongguo Taoci Gongye), 2001,8:29-33
1. [1]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
2. [2]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
3. [3]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
4. [4]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
5. [5]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
6. [6]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
7. [7]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
8. [8]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
9. [9]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
10. [10]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
11. [11]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
12. [12]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
13. [13]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
14. [14]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
15. [15]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
16. [16]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
17. [17]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
18. [18]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
19. [19]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
20. [20]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(336)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO2

Metrics

通讯作者: 陈斌, bchen63@163.com

One-Step Hydrothermal Synthesis and Research on the Photovoltaic Properties of the Complex TiO₂