Citation: XU Yan, XING Li-Shu, LI Xiang-Ping, SHI Lei, LI Xue-Bing, LIN Sen, LI Ming-Shi. Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1849-1855. doi: 10.3969/j.issn.1001-4861.2013.00.248 shu

Direct Synthesis of Al-SBA-15 at High Aging Temperature without Mineral Acid

XU Yan ^1,2 ,
XING Li-Shu ^1,2 ,
LI Xiang-Ping ² ,
SHI Lei ³ ,
LI Xue-Bing ² ,
LIN Sen ² ,
LI Ming-Shi ¹

1.
1 Institute of Petrochemical Technology, Changzhou University, Gehu Road, Changzhou, Jiangsu 213164, China;

Received Date: 8 October 2012
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(20976076) (20976076)中科院百人项目(Y11202220T) (Y11202220T)山东省高等学校科技计划项目(J12LA02)资助项目。 (J12LA02)

Al-SBA-15 with a rod-like morphology and well-ordered mesostructure was hydrothermally synthesized through a one-step approach in an environmentally friendly medium by using triblock copolymer Pluronic P123 as a structure-directing agent. The influence of aging temperature and silica-alumina species co-hydrolysis on the morphologies and structural properties of the resultant materials were investigated by XRD, IR, SEM, TEM and nitrogen adsorption-desorption techniques at 77 K. Compared to silica-alumina co-hydrolysis, the aging temperature plays an important role in the formation of the ordered mesostructure. The mesopores are widened and the wall thickness becomes thinner when the aging temperature is increased. The particles have well-defined rod-like morphology with the uniform particle size from 2 to 4 μm and the diameter in the range of 400~600 nm. The Si/Al molar ratio of the final Al-SBA-15 samples will be obviously higher if the time for silica-alumina co-hydrolysis is longer than 20 h.
- Al-SBA-15;acid-free hydrothermal synthesis;mesoporous materials;morphology;pore structure
1. [1]
  [1] Kresge C T, Leonowicz M E, Roth W J, et al. Nature, 1992,352:710-712
2. [2]
  [2] Corma A. Chem. Rev., 1997,97:2373-2419
3. [3]
  [3] Zhao D, Feng J, Huo Q, et al. Science, 1998,279:548-552
4. [4]
  [4] Vinu A, Murugesan V, Bhlmann W, et al. J. Phys. Chem. B, 2004,108:11496-11505
5. [5]
  [5] Wu S, Han Y, Zou Y C, et al. Chem. Mater., 2004,16:486-492
6. [6]
  [6] Yue Y, Gédéon A, Bonardet J L. Chem. Commun., 1999, 1967-1968
7. [7]
  [7] Zhang Z, Han Y, Zhu L. Angew. Chem. Int. Ed., 2001,40: 1258-1262
8. [8]
  [8] Luan Z, Maes E M, Heide P A W, et al. Chem. Mater., 1999,11:3680-3686
9. [9]
  [9] SUN Jin-Yu(孙锦玉), Zhao Dong-Yuan(赵东元). Chem. J. Chin. Univ.(Gaodeng Xuexiao Huaxue Xuebao), 2000,21(1): 21-23
10. [10]
  [10] YU Hui(于辉), ZHAI Qing-Zhou(翟庆洲). Bulletin Chin. Ceramic Soc. (Guisuanyan Tongbao), 2006,25(6):123-128
11. [11]
  [11] Pitchumani R, Li W, Coppens M O. Catal. Today, 2005,105: 618-622
12. [12]
  [12] Vinu A, Murugesan V, Hartmann M, et al. J. Phys. Chem. B, 2004,108:11496-11505
13. [13]
  [13] Han Y, Li D, Zhao L, et al. Angew. Chem. Int. Ed., 2003, 42:3633-3637
14. [14]
  [14] Li D, Han Y, Xiao F S, et al. Chem. Eur. J., 2004,10:5911-5922
15. [15]
  [15] Chen S Y, Jang L Y, Cheng S. Chem. Mater., 2004,16: 4174-4180
16. [16]
  [16] Chen S Y, Tsai H D, Chuang W T. J. Phys. Chem. C, 2009, 113:15226-15238
17. [17]
  [17] Wu Z, Wang H, Zhuang T. Adv. Funct. Mater., 2008,18:82-94
18. [18]
  [18] Lin N, Yang J, Wu Z. Microporous Mesoporous Mater., 2011, 139:130-137
19. [19]
  [19] Lin S, Shi L, Ribeiro Carrott M M L. Microporous Mesoporous Mater., 2011,142:526-534
20. [20]
  [20] Bennadja Y, Beaunier P, Margolese D. Microporous Mesoporous Mater., 2001,44:147-152
21. [21]
  [21] Feuston B P, Higgins J B. J. Phys. Chem., 1994,98:4459-4462
22. [22]
  [22] Ryoo R, Ko C H, Kruk M. J. Phys. Chem. B, 2000,104: 11465-11471
23. [23]
  [23] YU Shan-Qing(于善青),ZHAO Rui-Yu(赵瑞玉),LIU Chen-Guang(刘晨光). Acta Petrolei Sinica(Petroleum Processing) (Shiyou Xuebao (Shiyou Jiagong)), 2004,20(4):79-83
24. [24]
  [24] ZHOU Li-Hui(周丽绘), ZHANG Li-Zhong(张利中), LIU Hong-Lai(刘洪来). Chinese J.Process Engineering (Guocheng Gongcheng Xuebao), 2006,6(3):499-502
25. [25]
  [25] Mokaya R, Jones W. Chem. Commun., 1997,22:2185-2186
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