Citation: LI Dong-Lin, TIAN Miao, LI Qian, MA Shou-Long, XIE Rong, GOU Lei, FAN Xiao-Yong, ZHAO Peng. Nanostructure and Transparency of KTiOPO₄@SiO₂ Nanocrystalline Glass-Ceramics by Wet-Chemical Route[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1903-1908. doi: 10.3969/j.issn.1001-4861.2013.00.246 shu

Nanostructure and Transparency of KTiOPO₄@SiO₂ Nanocrystalline Glass-Ceramics by Wet-Chemical Route

1.
New Energy Materials & Devices Group, School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China

Received Date: 21 January 2013
Available Online: 18 March 2013
Fund Project: 教育部高等学校科学技术重大项目培育资金项目(No.708084) (No.708084)国家自然科学基金(No.21073021) (No.21073021)中央高校基本科研业务费专项资金(No.CHD2010ZD008,CHD2011ZD007)资助项目。 (No.CHD2010ZD008,CHD2011ZD007)

Transparent 25KTiOPO₄-75SiO₂ (KTP@SiO₂) nanocrystalline glass-ceramics were synthesized by the wet-chemical method. Morphology and nanostructure of the KTP nanocrystals embedded in the silicate glass were characterized by means of X-ray diffraction (XRD) and field emission scanning electron microscope (FESEM). The results show that, KTP nanocrystals with the size of ~30 nm are precipitated from SiO₂-based glass in the heat-treated transparent gels, forming KTiOPO₄@SiO₂ nanophase glass-ceramics. At the same time, a large amount of irregular mesopores were eliminated, but small amount of spherical nanopores with 30 nm-diameter form. This type of relatively dense glass-ceramic exhibits the optical transmittance of about 64% in the visible region. Based on nanostructure data, the effects of the nanostructure on the transparency of the glass-ceramics were analyzed according to Rayleigh model. It shows that the ratio of the refractive indices decreases the optical transmittance of the KTiOPO₄@SiO₂ nano-glass-ceramics in the visible region.
- KTiOPO₄;SiO₂;sol-gel;nano-glass-ceramics;transparency;second harmonic generation (SHG)
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沈阳化工大学材料科学与工程学院沈阳 110142

Nanostructure and Transparency of KTiOPO4@SiO2 Nanocrystalline Glass-Ceramics by Wet-Chemical Route

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通讯作者: 陈斌, bchen63@163.com

Nanostructure and Transparency of KTiOPO₄@SiO₂ Nanocrystalline Glass-Ceramics by Wet-Chemical Route