Citation: WU Zhen-Yu, LI Feng-Jie, LI Cun, ZHU Wei-Ju, FANG Min. Preparation and Photocatalytic Properties of Different Morphological ZnO@ PANI Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2091-2098. doi: 10.3969/j.issn.1001-4861.2013.00.245 shu

Preparation and Photocatalytic Properties of Different Morphological ZnO@ PANI Nanocomposites

1.
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China

Received Date: 20 January 2013
Available Online: 8 April 2013
Fund Project: 安徽省自然科学基金(No.11040606M33) (No.11040606M33)安徽大学博士启动基金(No.02303319)资助项目 (No.02303319)

The particle, rod, and spherical flower-like nano-ZnO with the uniform morphology and size were prepared through a simple direct precipitation method and hydrothermal method. Then nano-ZnO was modified by the silane coupling agent anilino-methyl-triethoxysilane (KH-42) (m-ZnO), and the nanocomposites consisted of m-ZnOand polyaniline (m-ZnO@PANI) were synthesized by Pickering emulsion polymerization method. XRD, SEM, HRTEM, FTIR, UV-Vis, TGwere used to characterize the shape, composition and structure of the nano-ZnO and m-ZnO@PANI nanocomposite. The photocatalytic activity of m-ZnO@PANI nanocomposites under UV-vis and visible light irradiation was evaluated by using nanocomposites as photocatalysts to degrade methylene blue (MB) dye molecules in aqueous solution. The results indicate that the nanocomposites have strong absorption of UVand visible light and good photocatalytic efficiency under UV-Vis and visible light irradiation. The photocatalytic efficiency of the rod nanocomposite is the best among them. The photodegradation rates under UV-Vis irradiation and visible light irradiation are 98.2% and 97.1% respectively. Furthermore, the recycled photodegradation efficiency of nanocomposite is stable and the second cycle photodegradation rate under UV-Vis irradiation was 96.0%.
- nano-ZnO; PANI; composite; photocatalyst
1. [1]
  [1] Guo M Y, Fung M K, Fang F, et al. J. Alloys Compd. 2011, 509:1328-1332 [2] Faisal M, Khan S B, Rahman M M, et al. Appl. Surf. Sci., 2011,258:672-677 [3] SONG Ji-Zhong(宋继中), HE Ying(贺英), PAN Zhao-Dong (潘照东), et al. Acta Chim. Sin.(Huaxue Xuebao), 2011,69: 1582-1588 [4] WANG Hu(王虎), XIE Juan(谢娟), DUAN Ming(段明). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27: 193-198 [5] WANG Hu(王虎), XIE Juan(谢娟), DUAN Ming(段明). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:321- 326 [6] WANG Zhi-Fang(王志芳), LI Mi(李密), ZHANG Hong-Xia (张红霞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:715-720 [7] GAO Hai-Xia(高海霞), CHENG Guo-Feng(程国峰), CHENG Rong-Ming(成荣明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22:872-876 [8] LI Yun-Jun(李跃军), YIN Zhong-Hong(尹忠红), CAO Tie- Ping(曹铁平),et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebaoe), 2011,27:1348-1352 [9] TENG Hong-Hui(滕洪辉), XU Shu-Kun(徐淑坤), WANG Meng(王猛). J. Inorg. Mater. Sin. (Wuji Cailiao Xuebao), 2010,25:1034 -1040 [10]LI Chang-Quan(李长全), LUO Lai-Tao(罗来涛), XIONG Guang-Wei(熊光伟). Chin. J. Catal. (Cuihua Xuebao). 2009, 30:1058-1062 [11]YU Chang-Lin(余长林), YANG Kai(杨凯), YU Ji-Mei (余济美), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27,505-512 [12]Wang H H, Xie C S, Zhang W, et al. J. Hazard. Mater. 2007,141:645-652 [13]Ma S S, Li R, Lü C P, et al. J. Hazard. Mater. 2011,192:730- 740 [14]Mahmood M A, Baruah S, Dutta J. Mater. Chem. Phys., 2011, 130:531-535 [15]Patil A B, Patil K R, Pardeshi S K. J. Hazard. Mater. 2010, 183:315-323 [16]Fu D Y, Han G Y, Chang Y Z, et al. Mater. Chem. Phys. 2012,132:673-681 [17]Zhang H, Zong R L, Zhu Y F. J. Phys. Chem. C, 2009, 113,4605-4611 [18]Eskizeybek V, Sar F, Gülce H, et al. Appl. Cataly. B: Environ, 2012,119-120:197-206 [19]Li Y H, Gong J, McCune M, et al. Synth. Metal, 2010,160: 499-503 [20]Sharma B K, Kharea N, Dhawan S K, et al. J. Alloy. Compd, 2009,477:370-373 [21]Huang G W, Xiao H M, Shi H Q, et al. J. Poly. Sci. Part A: Poly. Chem, 2012,50:2794-2801 [22]Alves K G B, Felix J F, Melo E F D, et al. J. Appl. Poly. Sci., 2012,125:E141-E147 [23]Sharma S P, Suryanarayana M V S, Nigam A K, et al. Cataly. Comm., 2009,10:905-912 [24]Huang J, Yang T L, Kang Y F. et al. Natural. Gas. Chem. 2011,20:515-519 [25]Ahmed F, Kumar S, Arshi N. et al. Thin Solid Films, 2011, 519:8375-8378 [26]Ameen S, Akhtar M S, Kim Y S, et al. Colloid. Polym. Sci., 2011,289:415-421 [27]Olad A, Nosrati R. Res. Chem. Intermed., 2012,38:323-326 [28]LI Feng-Jie(李奉杰), LI Cun(李村), ZHANG Xian-Li (张现利), et al. Bull. Chin. Ceram. Soc.(Guisuanyan Tongbao), 2012,31:145-149 [29]He Y J. Appl. Surf. Sci., 2005,249:1-6 [30]Zhu S, Wei W, Chen X, et al. J Solid State Chem., 2012, 190:174-179
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
3. [3]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
4. [4]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
5. [5]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
6. [6]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
7. [7]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
12. [12]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
13. [13]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
14. [14]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
15. [15]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
16. [16]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
17. [17]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
20. [20]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(227)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142