Citation: MA Zhi-Hong, WANG Na, GUO Kai-Ming, LIN Jin, ZHENG Xue-Zhong. Synthesis and Structures of Substituted Tetramethylcyclopentadienyl Diruthenium Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1882-1886. doi: 10.3969/j.issn.1001-4861.2013.00.237 shu

Synthesis and Structures of Substituted Tetramethylcyclopentadienyl Diruthenium Complexes

1.
1 College of Chemistry & Material Science,Hebei Normal University,Shijiazhuang 050024, China;

Received Date: 11 September 2012
Available Online: 26 February 2013
Fund Project: 河北省自然科学基金(No.B2008000150) (No.B2008000150)河北师范大学重点基金(No.L2009Z06)资助项目。 (No.L2009Z06)

The ligands[C₅Me₄HR] (R=cyclopentyl,cyclohexyl,ⁿPr) reacted with Ru₃(CO)₁₂ in refluxing xylene to give three new substituted tetramethylcyclopentadienyl diruthenium metal carbonyl complexes[(η⁵-C₅Me₄R)Ru(CO)(μ-CO)]₂ (R=cyclopentyl (1),cyclohexyl (2),ⁿPr (3)),respectively. The three new complexes were characterized by IR,elemental analysis and ¹H NMR spectra. The crystal structure of complexes 1 and 2 was determined by X-ray single crystal diffraction. CCDC: 891140, 1; 837727, 2.
- ruthenium carbonyl;cyclopentadienyl;structure;X-ray single crystal diffraction
1. [1]
  [1] Lin M, Kang G Y, Guo Y A, et al. J. Am. Chem. Soc., 2012, 134:398-405
2. [2]
  [2] Liu G, Huang K, Cao B, et al. Org. Lett., 2012,14:102-105
3. [3]
  [3] Stanowski S, Nicholas K M, Srivastava R S. Organometallics, 2012,31:515-518
4. [4]
  [4] Do Y, Han J, Rhee Y H, et al. Adv. Synth. Catal., 2011,35: 3363-3366
5. [5]
  [5] Kuninobu Y, Uesugi T, Kawata A, et al. Angew. Chem. Int. Ed., 2011,50:10406-10408
6. [6]
  [6] Zhang M, Imm S, Bähn S, et al. Angew. Chem. Int. Ed., 2011,50:11197-11201
7. [7]
  [7] Wang B, Yin Z, Li Y, et al. J. Org. Chem., 2011,76:9531-9535
8. [8]
  [8] Liu W, Liu J, Ogawa D, et al. Org. Lett., 2011,13:6272-6275-
9. [9]
  [9] Serra D, Correia M C, McElwee-White L. Organometallics, 2011,30:5568-5577
10. [10]
  [10] OConnor J M, Casey C P. Chem. Rev., 1987,87:307-318
11. [11]
  [11] Möhring P C, Coville N J. Coord. Chem. Rev., 2006,250: 18-35
12. [12]
  [12] Möhring P C, Coville N J. J. Organomet. Chem., 1994,79: 1-29
13. [13]
  [13] Bensley D M, Mintz E A, Sussangkarn S J. J. Org. Chem., 1988,53:4417-4419
14. [14]
  [14] Mills O S, Nice N P. J. Organomet. Chem., 1967,9:339-344
15. [15]
  [15] Nataro C, Angelici R. J. Inorg. Chem., 1998,37:2975-2983
16. [16]
  [16] Schumann H, Stenz S, Girgsdies F, et al. Z. Naturforsch., 2002,57b:1017-1026
17. [17]
  [17] MA Zhi-Hong(马志宏), ZHAO Ming-Xia(赵明霞), LIN Jin (林进). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25:377-380
18. [18]
  [18] Lin J, Gao P, Li B, et al. Inorg. Chim. Acta, 2006,359:4503-4510
1. [1]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
2. [2]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
3. [3]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
4. [4]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
5. [5]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
6. [6]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
7. [7]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
12. [12]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
13. [13]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
14. [14]
  Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
15. [15]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
16. [16]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
17. [17]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
18. [18]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
19. [19]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
20. [20]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(685)
HTML views(106)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142