Citation: JI Ning-Ning, ZHANG Ya-Nan, SHI Zhi-Qiang, HE Guo-Fang. Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1957-1961. doi: 10.3969/j.issn.1001-4861.2013.00.230 shu

Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine

1.
College of Chemistry and Chemical Engineering, Taishan University, Taian, Shandong 271021, China

Received Date: 5 October 2012
Available Online: 21 March 2013
Fund Project: 泰安市科技发展计划(No.20081009)资助项目。 (No.20081009)

The title complex[Zn(PCPA)₂(4,4'-bipy)(H₂O)]_n with p-chlorophenoxyacetic acid (PCPA), 4,4'-bipyridine (4,4'-bipy) has been hydrothermally synthesized and characterized by elemental analysis, IR spectra, UV spectra, thermal analyses, powder X-ray diffraction and single crystal X-ray diffraction. The zinc(Ⅱ) ion is six-coordinated with two nitrogen atoms from two 4,4'-bipy, three oxygen atoms from three PCPA and one water oxygen atom, forming a slightly distorted octahedral configuration. The complex molecules form a 2D layer structure through bridged PCPA and 4,4'-bipy which is consolidated by O-H…O hydrogen bonds. CCDC: 850113.
- p-chlorophenoxyacetic acid;4,4’-bipyridine;Zinc(Ⅱ) complex;crystal structure
1. [1]
  [1] Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc. Rev., 2007,36:770-818
2. [2]
  [2] Nouar F, Eubank J F, Bousquet T, et al. J. Am. Chem. Soc., 2008,130:1833-1835
3. [3]
  [3] Chun H P, Jung H J. Inorg. Chem., 2009,48:417-419
4. [4]
  [4] Ono K, Yoshizawa M, Akita M, et al. J. Am. Chem. Soc., 2009,131:2782-2783
5. [5]
  [5] XU Gui-Ji(徐贵基), PAN Zhao-Rui(潘兆瑞), ZHENG He-Gen(郑和根), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(9):1551-1556
6. [6]
  [6] SHI Zhi-Qiang(石智强), JI Ning-Ning(季宁宁), ZHAO Xue (赵雪), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(2):251-256
7. [7]
  [7] JI Ning-Ning(季宁宁), SHI Zhi-Qiang(石智强), ZHAO Ren-Gao(赵仁高). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(6):1025-1030
8. [8]
  [8] LIU Tong-Fei(刘同飞), ZNI Guang-Hua(崔广华), JIAO Zni-Huan(焦翠欢), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1417-1422
9. [9]
  [9] SHI Zhi-Qiang(石智强), JI Ning-Ning(季宁宁), HE Guo-Fang(何国芳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):1507-1512
10. [10]
  [11] LIU Jia-Lu(刘家禄), ZHAO Guo-Liang(赵国良). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(8):2021-2026
11. [11]
  [12] Shi Z Q, Ji N Ning, Zhao R G, et al. Struct. Chem., 2011, 22:225-233
12. [12]
  [13] Zhang S S, Niu S Y, Wang L, et al. Asian J. Chem., 2006, 18:1885-1887
13. [13]
  [14] Miyazawa M, Irie Y, Kashimoto K, et al. Inorg. Chem. Commun., 2009,12:336-339
14. [14]
  [15] YANG Ying-Qun(杨颖群), LI Chang-Hong(李昶红), LI Wei (李薇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(10):1890-1894
15. [15]
  [16] Sun Y X, Wang Z, Zhang H H, et al. Inorg. Chim. Acta, 2007,360:2565-2572
16. [16]
  [17] Sheldrick G M. SHELXL 97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
17. [17]
  [18] Sheldrick G M. SHELXL 97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
18. [18]
  [19] Nakamota K, Translated by HUANG De-Ru(黄德如), WANG Ren-Qing(汪仁庆). Infrand and Raman Spectra of Inorganic and Coordination Compounds, 3rd Ed.(无机和配位化合物的红外和拉曼光谱.3版). Beijing: Chemical Industry Press, 1986.
19. [19]
  [20] Wang Z, Zhang H H, Chen Y P, et al. J. Solid. State. Chem, 2006,179:1536-1544
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
7. [7]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
17. [17]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
18. [18]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
19. [19]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
20. [20]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(403)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142