Citation: JI Ning-Ning, ZHANG Ya-Nan, SHI Zhi-Qiang, HE Guo-Fang. Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1957-1961. doi: 10.3969/j.issn.1001-4861.2013.00.230 shu

Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine

1.
College of Chemistry and Chemical Engineering, Taishan University, Taian, Shandong 271021, China

Received Date: 5 October 2012
Available Online: 21 March 2013
Fund Project: 泰安市科技发展计划(No.20081009)资助项目。 (No.20081009)

The title complex[Zn(PCPA)₂(4,4'-bipy)(H₂O)]_n with p-chlorophenoxyacetic acid (PCPA), 4,4'-bipyridine (4,4'-bipy) has been hydrothermally synthesized and characterized by elemental analysis, IR spectra, UV spectra, thermal analyses, powder X-ray diffraction and single crystal X-ray diffraction. The zinc(Ⅱ) ion is six-coordinated with two nitrogen atoms from two 4,4'-bipy, three oxygen atoms from three PCPA and one water oxygen atom, forming a slightly distorted octahedral configuration. The complex molecules form a 2D layer structure through bridged PCPA and 4,4'-bipy which is consolidated by O-H…O hydrogen bonds. CCDC: 850113.
- p-chlorophenoxyacetic acid;4,4’-bipyridine;Zinc(Ⅱ) complex;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142