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Citation: CHEN Shan-Hu, CAO Yi, LAN Li, ZHAO Ming, SHI Zhong-Hua, GONG Mao-Chu, CHEN Yao-Qiang. Preparation of Mesoporous CeO2 with High Thermal Stability by Ammonium Carbonate Hydrolysis Method[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2231-2238. doi: 10.3969/j.issn.1001-4861.2013.00.219 shu

Preparation of Mesoporous CeO2 with High Thermal Stability by Ammonium Carbonate Hydrolysis Method

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    Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

  • Received Date: 7 January 2013
    Available Online: 19 March 2013

    Fund Project: 国家自然科学基金(No.20803049,21173153)资助项目 (No.20803049,21173153)

  • Two series of CeO2 materials were prepared by two different synthetic routes, i.e. the conventional ammonia precipitation route (CR) and the ammonium carbonate hydrolysis route (HA) using (NH4)2CO3 in the presence of hydrogen peroxide. The formation process and decomposition behavior of the precipitates were investigated by FTIR, Raman, thermogravimetric and differential thermal analysis (TG/DTA) and X-ray photoelectron spectroscopy (XPS). The results show that the as-prepared precipitate obtained by HAconsists of O22-, CO32- and OH- species. However, after hydrothermal digestion at 80 ℃, the CO32- species is gradually hydrolyzed into OH- species. Although the chemical components of the digested precipitates prepared by these two routes are almost the same, the agglomeration of CeO2 particles is markedly modified. The CeO2 powder produced by HAexhibits higher thermal stability and better reduction property compared to that obtained by CR. After the heat treatment at 900 ℃ for 3 h, the CeO2 powder from HAroute still remains a surface area of 27 m2·g-1.
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