Citation: WEI Zhen, ZHU Peng-Fei, ZHANG Ya-Qin, GUO Feng-Wan, QI Xiao-Ting, WANG Juan. Complex (HP₂W₁₈O₆₂)(C₆H₆NO₂)₅·2H₂O via in-situ Decarboxylation: Crystal Structure, Spectroscopy and Electrochemistry[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1089-1095. doi: 10.3969/j.issn.1001-4861.2013.00.182 shu

Complex (HP₂W₁₈O₆₂)(C₆H₆NO₂)₅·2H₂O via in-situ Decarboxylation: Crystal Structure, Spectroscopy and Electrochemistry

1.
1. College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;

Corresponding author: WANG Juan,
Received Date: 17 January 2013
Available Online: 15 March 2013
Fund Project: 国家自然科学基金(No.21201061) (No.21201061)湖北省自然科学基金(No.2012FFB00205)资助项目。 (No.2012FFB00205)

Heteropolyacid complex (HP₂W₁₈O₆₂)(C₆H₆NO₂)₅·2H₂O (1) with 2-picolinic acid in deionized water has been synthesized and characterized by IR, UV, cyclic voltammetry (CV) and X-ray single-crystal diffraction methods. The 2-picolinic acid was obtained by decarboxylation of pyridine-2,6-dicarboxylicacid(H₂PDA). The results show that the crystal of the complex 1 belongs to monoclinic system, space group P2₁/n with: a=1.553 3(2)nm, b=2.006 3(3) nm, c=2.759 9(4) nm, β=103.981(2)°, Z=4, F(000)=8 816. Intermolecular hydrogen-bond and weak interactions from polyanions and 2-picolinic acid lead the complex to a 3D supramolecular architecture. CV study reveals that compound 1 exhibits four chemical processes. CCDC: 905785.
- polyoxometallate;pyridine-2,6-dicarboxylic;2-picolinic acid;electrochemistry;crystal structure
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Complex (HP2W18O62)(C6H6NO2)5·2H2O via in-situ Decarboxylation: Crystal Structure, Spectroscopy and Electrochemistry

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通讯作者: 陈斌, bchen63@163.com

Complex (HP₂W₁₈O₆₂)(C₆H₆NO₂)₅·2H₂O via in-situ Decarboxylation: Crystal Structure, Spectroscopy and Electrochemistry