Citation: ZHUANG Jia, QIN Hai-Yang, LI Lin-Feng, ZHOU Ying, JIA Chun-Yang, WAN Zhong-Quan, ZENG Xian-Guang. Hydrothermal Synthesis of a Dysmorphic Double Layer Structure TiO₂ Nanorod Films and Its Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1057-1064. doi: 10.3969/j.issn.1001-4861.2013.00.179 shu

Hydrothermal Synthesis of a Dysmorphic Double Layer Structure TiO₂ Nanorod Films and Its Properties

1.
1. School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China;

Corresponding author: QIN Hai-Yang,
Received Date: 13 December 2012
Available Online: 16 February 2013
Fund Project: 国家自然科学基金(No.51102245) (No.51102245)四川省材料腐蚀与防护重点实验室课题(No.2012CL04)资助项目。 (No.2012CL04)

A type of double layer(array-cluster)TiO₂ films were prepared with mixed solution of hydrochloric acid and tetrabutyl titanate (TBOT) by a hydrothermal method at specific reaction condition. It was found that the TiO₂ films on the substrate has a two-layer structure and has the tetragonal rutile phase observed from the field emission scaning electron microscopy (FESEM) and the X-ray diffraction (XRD). Moreover, the subjacent layer of the two-layer structure were TiO₂ rods array, while the supernatant layer was TiO₂ rods clusters, and microscopic structure of these rods all are made of smaller TiO₂ nanorods(25～65 nm). This two-layer structure of TiO₂ films can favors to acquiring more light and adsorbing more dye, and could provide a fast circulation channel for photon-generated electrons. The thickness of this type of TiO₂ films in supernatant layer can be varied by changing initial reactant concentration, growth time or substrate placed angles. And without any modification treatment, a light-to- electricity conversion effciency of DSSC with TiO₂ nanorod array-cluster films can enhance 2.6 time in comparison with only TiO₂ nanorod array films.
- hydrothermal method;nanorod films;TiO₂;array-clusters structure;light-to-electricity conversion efficiency
1. [1]
  [1] ORegan B, Grätzel M. Nature, 1991,353:737-740
2. [2]
  [2] Zhang Y B, Feng X J, Jiang L. Sci. Chin. Ser. B: Chem. 2007,50:175-178
3. [3]
  [3] Zhou Z J, Fan J Q, Wang X, et al. ACS Appl. Mater. & Interf., 2011,3:2189-2194
4. [4]
  [4] Kondo Y, Yoshikawa H, Awaga K, et al. Langm., 2008,24: 547-550
5. [5]
  [5] Gopal K M, Oomman K V, et al. Sol. Ene. Mate. & Sol. Cel., 2006,90:2011-2075
6. [6]
  [6] Shin J H, Moon J H. Langm., 2011,27:6311-6315
7. [7]
  [7] Agarwala S, Kevin M, Wong A S W, et al. Appl. Mater. & interf., 2010,7:1844-1850
8. [8]
  [8] Li D D, Chang P C, Chien C J, et al. Chem. Mater., 2010, 22:5707-5711
9. [9]
  [9] Chen X B, Mao S S. Chem. Rev., 2007,107:2891-2959
10. [10]
  [10] Yang M J, Ding B. J. Phys. Chem. C, 2011,115:14534- 14541
11. [11]
  [11] Cho I S, Chen Z B, Forman A J. Nano Letters, 2011,11: 4978-4984
12. [12]
  [12] Kandiel T A, Dillert R, Feldhoff A, et al. J. Phys. Chem. C 2010,114:4909-4915
13. [13]
  [13] Kim S, Sohn K S, Pyo M. Combin. Sci., 2010, doi: org/ 10.1021/co1000025
14. [14]
  [14] Mahajan L H, Mhaske S T, Mater. Lett., 2012,68:183-186
15. [15]
  [15] Lia Q, Satura D J G, Kima H, et al. Mater. Lett., 2012,76: 169-172
16. [16]
  [16] You M K, Kim T G, Sung Y M. Cryst. Grow. & Des., 2010, 10:983-987
17. [17]
  [17] Long Y Z, Lu Y, Huang Y, et al. J. Phys. Chem. C, 2009, 113:13899-13905
18. [18]
  [18] Acharya K P, Alabi T R, Schmall N, et al. J. Phys. Chem. C, 2009,113:19531-19535
19. [19]
  [19] Zhu H, Tao Jie, Dong X. J. Phys. Chem. C, 2010,114:2873- 2879
20. [20]
  [20] Liu B, Aydil E S. J. Am.Chem. Soc., 2009,131:3985-3990
21. [21]
  [21] LI Ping(李平), LU Hai-Xia(路海霞), QIN Li-Zhao(覃礼钊), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(9):1855-1860
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis of a Dysmorphic Double Layer Structure TiO2 Nanorod Films and Its Properties

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis of a Dysmorphic Double Layer Structure TiO₂ Nanorod Films and Its Properties