Citation: GANG Gang, BAIYIN Meng-He, WANG Xiao-Jing, NAREN Ji-Ru-Ga, XU Xiao-Qing, BAI Wu-Yun, SIQIN Da-Lai. Solvothermal Synthesis and Characterzation of (1,4-DABH₂)Cd₂Sb₂S₆ with Layer Structure[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 979-984. doi: 10.3969/j.issn.1001-4861.2013.00.176 shu

Solvothermal Synthesis and Characterzation of (1,4-DABH₂)Cd₂Sb₂S₆ with Layer Structure

1.
1. College of Chemistry & Environmental Science, Inner Mongolia Normal University, Huhhot 010022, China;

Corresponding author: BAIYIN Meng-He,
Received Date: 25 July 2012
Available Online: 4 February 2013
Fund Project: 教育部科学技术研究重点项目(No.210041) (No.210041)内蒙古自然科学基金(No.20080404MS021)资助项目。 (No.20080404MS021)

A multiple thioantimonate compound, (1,4-DABH₂)Cd₂Sb₂S₆ (1) (1,4-DAB=1,4-diaminobutane) , was solvothermally synthesized at 160 ℃ and characterized by IR and TGA. Its crystal structure analysis reveals the compound was determined by single crystal X-ray diffraction. The crystal structure is orthorhombic in the space group Cmca. Crystallographic data: M_r=750.77, a=0.860 3(5) nm, b=0.898 7(6) nm, c=2.273(2) nm, V=1.758(2) nm³, Z=4, λ=0.071 073 nm, R=0.032 0, wR=0.106 7. The compound features two-dimensional (2D) grid layer of [CdSbS₃]_n^n- with six-membered Cd₂SbS₃ rings and eight-membered Cd₂Sb₂S₄ rings. The doubly protonated organic cations are located at the interlayer spaces of [CdSbS₃]_n^n- and form extensive N-H…S hydrogen bonds. In addition, UV-Vis diffusion reflectance spectra suggest that the compound is semiconductor with estimated band gap 2.10 eV. CCDC: 879803.
- solvothermal synthesis;multiple thioantimonate;crystal structure;characterization
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Solvothermal Synthesis and Characterzation of (1,4-DABH2)Cd2Sb2S6 with Layer Structure

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Solvothermal Synthesis and Characterzation of (1,4-DABH₂)Cd₂Sb₂S₆ with Layer Structure