Citation: JIANG Qi-Bai, JI Yi-Fei, SHEN Xu-Jie, YAN Hong. Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 910-914. doi: 10.3969/j.issn.1001-4861.2013.00.168 shu

Synthesis and Characterization of Ni(Ⅱ) and Ir(Ⅰ) Complex with o-Carborane [O,P] or [O,O] Ligand

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering Nanjing University, Nanjing 210093, China

Corresponding author: YAN Hong,
Received Date: 4 January 2013
Available Online: 12 March 2013
Fund Project: 国家自然科学基金(No.20925104,21271102,21021062)资助项目。 (No.20925104,21271102,21021062)

The reactions of o-carborane [P,P] ligand L1 with NiCl₂(PPh₃)₂ and [IrCl(COD)]₂ under an open atmosphere lead to two nido-carborane species 1 and 2 containing [O,P] or [O,O] ligands. All these complexes have been characterized by NMR, MS, IR and X-ray diffraction analyses. Complex 1 with solvent CHCl₃ formed the normal Cl…H interaction and novel CH…π interaction. Complex 2 is the first Ir(Ⅰ) compound containing [O,P] o-carborane ligand. However, due to the difference of metal (Ni and Ir), the [P,P] ligand L1 was oxizided to novel [P,O] ligand and [O,O] ligand, respectively. CCDC: 927419, 1; 927420, 2.
- carborane;nickel;iridium;[P,O] ligands
1. [1]
  [1] Pleek J. Chem. Rev., 1992,92(2):269-278
2. [2]
  [2] Grimes R N. Coord. Chem. Rev., 2000,200-202:773-811
3. [3]
  [3] ZHOU Quan(周权), MAO Zu-Ju(茅祖菊), NI Li-Zhong(倪礼忠), et al. Chinese Plast.(Zhongguo Suliao), 2006,20(7):6-13
4. [4]
  [4] Russell N. Appl. Organomet. Chem., 1996,10:209-225
5. [5]
  [5] TANG Jin-Song(唐松青), DINH Hong-Xun(丁宏勋). Chem. Propell. Poly. Mater(Huaxue Tuijinji Yu Gaofenzi Cailiao), 2004,2(1):8-11
6. [6]
  [6] Cigler P, Kozisek M, Rezacova P. et al. P. Natl. Acad. Sci. USA, 2005,102(43):15394-15396
7. [7]
  [7] Zhang R, Zhu L, Liu G, et al. J. Am. Chem. Soc., 2012,134 (25):10341-10344
8. [8]
  [8] Zhong W, Xie M, Jiang Q, et al. Chem. Commun., 2012,48: 2152-2154
9. [9]
  [9] Xu Z, Han L, Ji C, et al. Dalton Trans., 2011,40:6992-6997
10. [10]
  [10] Liu G, Hu J, Wen J, et al. Inorg. Chem., 2011,50:4187-4194
11. [11]
  [11] Jin G. Coord. Chem. Rev., 2004,248:587-602
12. [12]
  [12] Wang J, Weng L, Jin G. Rev. Inorg. Chem., 2005,25:55-56
13. [13]
  [13] Liu S, Han Y, Jin G. Chem. Soc. Rev., 2007,36:1543-1560
14. [14]
  [14] Tutusaus O, Nunez R, Vias C, et al. Inorg. Chem., 2004,43: 6067-6074
15. [15]
  [15] Hampton D. J. Am. Chem. Soc., 1965,87:1817-1818
16. [16]
  [16] Dou J, Zhang D, Zhu Y, et al. Polyhedron, 2007,26:4216- 4222
17. [17]
  [17] Teixidor F, Benakki R, Vias C, et al. Organometallics, 1998,17:4630-4633
18. [18]
  [18] Garton G, Henn D, Powell H, et al. J. Am. Soc., 1963:3625- 3633
19. [19]
  [19] Tabrizi D, Manoli J, Dereigne A. J. Less-Common Met., 1970,21:337-341
20. [20]
  [20] Alexander R, Schroeder H. Inorg. Chem., 1963,22:1107-1110
21. [21]
  [21] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1990.
22. [22]
  [22] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
23. [23]
  [23] Sun K, Wang L, Wang Z. Organmetallics, 2008,27:5649-5656
24. [24]
  [24] Fey N, Harris S, Harvey J, et al. J. Chem. Inf. Model, 2006,46:912-916
25. [25]
  [25] Tsuzuki S, Honda K, Uchimaru T, et al. J. Phys. Chem., 2002,106(17):4423-4428
26. [26]
  [26] Takahashi O, Kohno Y, Nishio M. Chem. Rev., 2010,110 (10):6049-6076
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