Citation: ZHANG Mei-Li, ZHANG Gang-Qiang, WANG Ji-Jiang, REN Yi-Xia, CHEN Xiao-Li, LÜ Lei. Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 671-676. doi: 10.3969/j.issn.1001-4861.2013.00.146 shu

Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand

1.
1 College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, Shaanxi 716000, China;

Received Date: 7 September 2012
Available Online: 17 January 2013
Fund Project: 陕西省教育厅科研基金(No.11JK0567, 11JK0565, 12JK0636) (No.11JK0567, 11JK0565, 12JK0636)延安大学自然基金(No.YDZD2011-07)资助项目。 (No.YDZD2011-07)

A coordination polymer of Mn^Ⅱ with flexible ligands, namely [Mn(pda)(bpp)] (1) (H₂pda=1,3-phenyl-enediacetic acid, bpp=1,3-bi(4-pyridyl)propane), was synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. The results of structure characterization indicate that the complex crystallizes in the orthorhombic space group Pnna with a=1.965 2(6) nm, b=1.103 3(4) nm, c=0.963 9(3) nm, α=β=γ=90.0°, V=2.089 8(12) nm³, Z=4, D_c=1.416 Mg·m^-3, μ=0.664 mm^-1, F(000)=924, and final R₁=0.040 2, wR₂=0.133 2. The crystal structure of complex 1 consists of one Mn^Ⅱ, one 1,3-pda ligand and one bpp ligand. The bpp ligands bridge the Mn^Ⅱ ions to form a one-dimensional(1D) right-handed helical chain along the crystallographic b direction. Moreover, these helical chains are united together through the 1,3-pda ligands to afford a two-dimensional(2D) helical layer. Further investigation of this 2D structure suggests that the Mn^Ⅱ centers are connected to each other by bpp to afford a 1D zigzag chain along the crystallographic c direction. The 1D zigzag chains are interlinked by the 1,3-pda anions, constituting step-shaped 2D (4,4) network. In addition, thermal stability and electrochemistry of 1 have also been studied. CCDC: 885051.
- complex;synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142