Citation: MAO Yan, ZHANG Chuan-Hui, ZHANG Yang, WANG Qi, XU Gui-Liang, HUANG Ling, LI Jun-Tao, SUN Shi-Gang. Synthesis and Electrochemical Performance of Novel Expanded Graphite Oxide/Sulfur Composite Cathodes for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 889-895. doi: 10.3969/j.issn.1001-4861.2013.00.141 shu

Synthesis and Electrochemical Performance of Novel Expanded Graphite Oxide/Sulfur Composite Cathodes for Lithium-Sulfur Batteries

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China

Corresponding author: HUANG Ling,
Received Date: 1 December 2012
Available Online: 6 January 2013
Fund Project: 国家“973”计划(No.2009CB220102) (No.2009CB220102)国家基础科学人才培养计划(No.J1210014)资助项目。 (No.J1210014)

The expanded graphite oxides were prepared by modified Hummers method. The expanded graphite oxide/sulfur (E-GO/S) composites have been successfully prepared by a new chemical reaction method based on comproportionation in the acidic aqueous solution. FT-IR, XPS were characterized the existence of functional groups on the surface of expanded graphite oxide. XRD results showed that the as-prepared sulfur belongs to orthorhombic system. SEM and TEM results indicated the uniform distribution of the sulfur in the composite. The electrochemical test showed that the expanded graphite oxide/sulfur (E-GO/S) composites can deliver the highest discharge capacity of 1 020 mAh·g^-1 at the first cycle, after 100 cycles of charge-discharge, the discharge capacity of the composites keep the capacity of ca. 650 mAh·g^-1, and have the excellent rate performance and coulombic efficiency that may be attributed to the homogeneous distribution of sulfur in the composites and the chemical approach to fix sulfur and the lithium polysulfides via the chemical bonds with the functional groups on the surface of expanded graphite oxide.
- elemental sulfur;comproportionation;lithium-sulfur battery;expanded graphite oxide
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沈阳化工大学材料科学与工程学院沈阳 110142