Advanced Search

Citation: DU Ke, YANG Fei, HU Guo-Rong, PENG Zhong-Dong, CAO Yan-Bing. Studies on the Effects from Citric Acid and Ammonium Citrate Tribasic Treatment on Electrochemical Performance of Li[Li0.2Mn0.54Ni0.13 Co0.13]O2[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 786-792. doi: 10.3969/j.issn.1001-4861.2013.00.139 shu

Studies on the Effects from Citric Acid and Ammonium Citrate Tribasic Treatment on Electrochemical Performance of Li[Li0.2Mn0.54Ni0.13 Co0.13]O2

  • 1.

    College of Metallurgical Science and Engineering, Central South University, Changsha 410083, China

  • Received Date: 1 November 2012
    Available Online: 27 December 2012

  • In order to improve the initial charge/discharge efficiency and rate performance of Li[Li0.2Co0.13Ni0.13Mn0.54]O2, we used citric acid and ammonium citrate tribasic to treat the materiel Li[Li0.2Co0.13Ni0.13Mn0.54]O2, which was synthesized by carbonation co-precipitated method. After surface modification, Emission Spectrometer (ICP-AES) analysis showed that lithium is the major element of the filtrate, 16.37wt% and 13.14wt% of lithium elements dissolved out during the pretreatment stage respectively, and a small amount of transition metals desorpted in this process. The charging/discharging test revealed that the materials treated by 20% of citric acid and ammonium citrate tribasic performed higher initial efficiency (80.2% and 80.7%), After 40 cycles with 0.2C cycle, the capacity retention rate increased to 97.42% and 92.70% from 91.43%, and the capacity at 1C increased to 179.5 mAh·g-1, 181.5 mAh·g-1, respectively. The results showed that after the treatment of citric acid and ammonium citrate tribasic, material properties and the rate performance were both improved.
  • 加载中
    1. [1]

      [1] Thackeray M M, Kang S H, Johnson, C S, et al. J. Mater. Chem., 2007,17:3112-3125

    2. [2]

      [2] Lim J H, Bang H, Lee K S, et al. J. Power Sources, 2009, 189:571-575

    3. [3]

      [3] Johnson C S, Li N, Lefief C, et al. Electrochem. Commun., 2007,9:787-795

    4. [4]

      [4] Lu Z, Dahn J R. J. Electrochem. Soc., 2002,149(7):A815-A822

    5. [5]

      [5] Armstrong A R, Holzapfel M, Novak P, et al. J. Am. Chem. Soc., 2006,128:8694-8698

    6. [6]

      [6] Liu J, Reeja J B, Manthiram A. J. Phys. Chem. C, 2010,114: 9528-9533

    7. [7]

      [7] Wu Y, Manthiram A. Electrochem. Solid-State Lett., 2006,9 (5):A221-A224

    8. [8]

      [8] Jung Y S, Cavanagh A S, Yan Y, et al. J. Electrochem. Soc., 2011,158(12):A1298-A1302

    9. [9]

      [9] Zhao Y, Zhao C, Feng H, et al. Electrochem. Solid-State Lett., 2011,14(1):A1-A5

    10. [10]

      [10] Zheng J M, Li J, Zhang Z R, et al. Solid State Ionics, 2008, 179:1794-1799

    11. [11]

      [11] ZHENG Jian-Ming(郑建明), YANG Yong(杨勇). Proceedings of The 14th National Conference on Solid State Ionics(第十 四届全国固态离子学学术会议), Xiamen:[s.n.], 2008:B38

    12. [12]

      [12] Wu Y, Murugan A V, Manthiram A. J. Electrochem., Soc., 2008,155(9):A635-A641

    13. [13]

      [13] Wang Q Y, Liu J, Murugan A V. J. Mater Chem., 2009,19: 4965-4972

    14. [14]

      [14] Kang S H, Thackeray M M. Electrochem. Commun., 2009, 11:748-751

    15. [15]

      [15] Lee S H, Koo B K, Kim J C, et al. J. Power Sources, 2008, 184:276-283

    16. [16]

      [16] Liu J, Wang Q, Reeja J B, et al. Electrochem. Commun., 2010,12:750-753

    17. [17]

      [17] WU Xiao-Biao(吴晓彪), DONG Zhi-Xin(董志鑫), ZHEN Jian-Ming(郑建明), et al. J. Xiamen Univ.: Nat. Sci.(Xiamen Daxue Xuebao: Ziran Kexueban), 2008,47(2):224-227

    18. [18]

      [18] Gao J, Manthiram A. J. Power Sources, 2009,191:644-647

    19. [19]

      [19] Gao J, Kim J, Manthiram A. Electrochem. Commun., 2009, 11:84-86

    20. [20]

      [20] Lee E S, Manthiram A. J. Electrochem. Soc., 2011,158(1): A47-A50

    21. [21]

      [21] Kang S H, Johnson C S, Vaughey J T, et al. J. Electrochem. Soc., 2006,153(6):A1186-A1192

    22. [22]

      [22] Kang S H, Thackeray M M. J. Electrochem. Soc., 2008,155 (4):A269-A275

    23. [23]

      [23] Denis Y W Y, Katsunori Y, Hiroshi N. J. Electrochem. Soc., 2010,157(11):A1177-A1182

    24. [24]

      [24] DU Ke(杜柯),HUANG Xia(黄霞),YANG Fei(杨菲), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(5): 983-988

    25. [25]

      [25] Gao Y, Yakovleva M V, Ebner W B. Electrochem. Solid-State Lett., 1998,1(3):117-119

    26. [26]

      [26] Lu C H, Wang H C. J. Electrochem. Soc., 2005,152(6):C341 -C347

    27. [27]

      [27] Breger J, Jiang M, Dupré N, et al. J. Solid State Chem., 2005,178:2575-2585

    28. [28]

      [28] Lu Z, Beaulieu L Y, Donaberger R A, et al. J. Electrochem. Soc., 2002,149(6):A778-A791

    29. [29]

      [29] Park Y J, Hong Y S, Wu X, et al. J. Power Sources, 2004, 129:288-295

    30. [30]

      [30] Thackeray M M, Johnson C S, Li N, et al. US Patent, 7303840 B2. 2007-12-4.

    31. [31]

      [31] Yu L, Qiu W, Lian F, et al. J. Alloys Compd., 2009,471:317 -321

  • 加载中
    1. [1]

      Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189

    2. [2]

      Jiajia Li ,  Xiangyu Zhang ,  Zhihan Yuan ,  Zhengyang Qian ,  Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073

    3. [3]

      Yangrui Xu ,  Yewei Ren ,  Xinlin Liu ,  Hongping Li ,  Ziyang Lu . 具有高传质和亲和表面的NH2-UIO-66基疏水多孔液体用于增强CO2光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032

    4. [4]

      Doudou Qin ,  Junyang Ding ,  Chu Liang ,  Qian Liu ,  Ligang Feng ,  Yang Luo ,  Guangzhi Hu ,  Jun Luo ,  Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    5. [5]

      Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

    6. [6]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

    7. [7]

      Xuejiao Wang ,  Suiying Dong ,  Kezhen Qi ,  Vadim Popkov ,  Xianglin Xiang . Photocatalytic CO2 Reduction by Modified g-C3N4. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

    8. [8]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    9. [9]

      Bao Jia ,  Yunzhe Ke ,  Shiyue Sun ,  Dongxue Yu ,  Ying Liu ,  Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121

    10. [10]

      Honglian Liang ,  Xiaozhe Kuang ,  Fuping Wang ,  Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073

    11. [11]

      Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

    12. [12]

      Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225

    13. [13]

      Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO2 by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259

    14. [14]

      Weihan Zhang ,  Menglu Wang ,  Ankang Jia ,  Wei Deng ,  Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043

    15. [15]

      Zhuomin Zhang ,  Hanbing Huang ,  Liangqiu Lin ,  Jingsong Liu ,  Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034

    16. [16]

      Yukai Jiang ,  Yihan Wang ,  Yunkai Zhang ,  Yunping Wei ,  Ying Ma ,  Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033

    17. [17]

      Lan Ma ,  Cailu He ,  Ziqi Liu ,  Yaohan Yang ,  Qingxia Ming ,  Xue Luo ,  Tianfeng He ,  Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046

    18. [18]

      Ruilin Han ,  Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023

    19. [19]

      Hongyi Zhang ,  Zhihong Shi ,  Zhijun Zhang . A New Strategy for “De-formulized” Calculation of Dynamic Buffer Capacity in Analytical Chemistry Education. University Chemistry, 2024, 39(3): 390-394. doi: 10.3866/PKU.DXHX202309030

    20. [20]

      Ji Qi ,  Jianan Zhu ,  Yanxu Zhang ,  Jiahao Yang ,  Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050

Get Citation
PDF
XML
Metrics
  • PDF Downloads(359)
  • Abstract views(980)
  • HTML views(100)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return